ChemicalBook > CAS DataBase List > 4-Methylthiazole-5-carboxaldehyde

4-Methylthiazole-5-carboxaldehyde

Product Name
4-Methylthiazole-5-carboxaldehyde
CAS No.
82294-70-0
Chemical Name
4-Methylthiazole-5-carboxaldehyde
Synonyms
MFTA;FMT;F2124-0219;IFLAB-BB F2124-0219;4-METHYL-5-FORMYLTHIAZOLE;5-FORMYL-4-METHYLTHIAZOLE;4-METHYLTHIAZOLE-5-ALDEHYDE;4-Methyl-5-thiazole aldehyde;4-METHYL-5-THIAZOLYL ALDEHYDE;MFTA 4-Methyl-5-formylthiazole
CBNumber
CB8162850
Molecular Formula
C5H5NOS
Formula Weight
127.16
MOL File
82294-70-0.mol
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4-Methylthiazole-5-carboxaldehyde Property

Melting point:
74-78 °C (lit.)
Boiling point:
118°C/21mmHg(lit.)
Density 
1.270±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
powder to crystal
pka
1.53±0.10(Predicted)
color 
White to Light yellow to Light orange
Water Solubility 
Slightly soluble in water.
InChI
InChI=1S/C5H5NOS/c1-4-5(2-7)8-3-6-4/h2-3H,1H3
InChIKey
JJVIEMFQPALZOZ-UHFFFAOYSA-N
SMILES
S1C(C=O)=C(C)N=C1
LogP
0.320 (est)
CAS DataBase Reference
82294-70-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
41-43
Safety Statements 
26-39
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29341000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
633208
Product name
4-Methylthiazole-5-carboxaldehyde
Purity
97%
Packaging
1g
Price
$31.6
Updated
2023/06/20
Sigma-Aldrich
Product number
633208
Product name
4-Methylthiazole-5-carboxaldehyde
Purity
97%
Packaging
5g
Price
$128
Updated
2023/06/20
TCI Chemical
Product number
M1812
Product name
4-Methylthiazole-5-carboxaldehyde
Purity
>98.0%(GC)
Packaging
1g
Price
$29
Updated
2025/07/31
TCI Chemical
Product number
M1812
Product name
4-Methylthiazole-5-carboxaldehyde
Purity
>98.0%(GC)
Packaging
5g
Price
$93
Updated
2025/07/31
TRC
Product number
M331443
Product name
4-Methylthiazole-5-carboxaldehyde
Packaging
10g
Price
$155
Updated
2021/12/16
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4-Methylthiazole-5-carboxaldehyde Chemical Properties,Usage,Production

Uses

4-Methylthiazole-5-carboxaldehyde is used as pharmaceutical intermediate.

Synthesis

89021-10-3

82294-70-0

General procedure for the synthesis of 4-methyl-5-thiazolecarboxaldehyde from 2-amino-4-methylthiazole-5-carboxaldehyde: A solution of tetrahydrofuran (THF, 3 mL) with amine 2 (5 mmol) was slowly added dropwise over a period of 20 min to a solution of tetrahydrofuran (THF, 3 mL) containing tert-butyl nitrite (t-BuONO, 7.5 mmol) and dimethylsulfoxide (DMSO, 0.5 mmol) in a solution of THF (7 mL). The reaction mixture was stirred continuously at 30°C until complete consumption of feedstock 2 was confirmed by thin layer chromatography (TLC) monitoring. Subsequently, the solvent was removed by evaporation and the yield of the low-boiling products was determined by gas chromatography (GC); the high-boiling products were separated and purified by silica gel column chromatography (eluent: hexane/ethyl acetate solvent mixture).

References

[1] Journal of Chemical Research, 2018, vol. 42, # 11, p. 579 - 583

4-Methylthiazole-5-carboxaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Methylthiazole-5-carboxaldehyde Suppliers

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View Lastest Price from 4-Methylthiazole-5-carboxaldehyde manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
4-Methylthiazole-5-carboxaldehyde 82294-70-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100
Release date
2024-11-19
Shaanxi Dideu New Materials Co. Ltd
Product
4-Methylthiazole-5-carboxaldehyde 82294-70-0
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-03-05
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-Methylthiazole-5-carboxaldehyde 82294-70-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11

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