Tris(hydroxymethyl)nitromethane

Product Name: Tris(hydroxymethyl)nitromethane
CAS No.: 126-11-4
Chemical Name: Tris(hydroxymethyl)nitromethane
Synonyms: 2-(Hydroxymethyl)-2-nitropropane-1,3-diol;Nitroisobutylglycerol;2-(HYDROXYMETHYL)-2-NITRO-1,3-PROPANEDIOL;AKOS 374;trisnitro;Tris Nitro;cimcoolwafers;Cimcool wafers;Trishydroxymethyl;SPECTRIS(TM) NITRO
CBNumber: CB8163079
Molecular Formula: C4H9NO5
Formula Weight: 151.12
MOL File: 126-11-4.mol

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Tris(hydroxymethyl)nitromethane Property

Melting point:: 160 °C (dec.) (lit.)
Boiling point:: 273.1°C (rough estimate)
Density: 1.5652 (rough estimate)
refractive index: 1.4183 (estimate)
solubility: H2O: soluble220g/100ml at 20°C
pka: 12.32±0.10(Predicted)
form: powder to lump
color: White to Almost white
Water Solubility: It is soluble in water.
Merck: 14,9753
BRN: 742427
LogP: 0.350 (est)
CAS DataBase Reference: 126-11-4(CAS DataBase Reference)
NIST Chemistry Reference: 1,3-Propanediol, 2-(hydroxymethyl)-2-nitro-(126-11-4)
EPA Substance Registry System: 2-(Hydroxymethyl)-2-nitro-1,3-propanediol (126-11-4)

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Safety

Hazard Codes: Xn
Risk Statements: 22-36/37/38-20/21/22
Safety Statements: 26-36
WGK Germany: 3
RTECS: TY7350000
F: 4.10
TSCA: Yes
HS Code: 29221990
Hazardous Substances Data: 126-11-4(Hazardous Substances Data)
Toxicity: mouse,LD50,intraperitoneal,4gm/kg (4000mg/kg),Khimiko-Farmatsevticheskii Zhurnal. Chemical Pharmaceutical Journal. For English translation, see PCJOAU. Vol. 11(1), Pg. 73, 1977.

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 108189
Product name: Tris(hydroxymethyl)nitromethane
Purity: 98%
Packaging: 100g
Price: $70
Updated: 2024/03/01

Sigma-Aldrich

Product number: 108189
Product name: Tris(hydroxymethyl)nitromethane
Purity: 98%
Packaging: 500g
Price: $276
Updated: 2024/03/01

TCI Chemical

Product number: H0271
Product name: 2-(Hydroxymethyl)-2-nitro-1,3-propanediol
Purity: >99.0%(GC)
Packaging: 25g
Price: $33
Updated: 2024/03/01

TCI Chemical

Product number: H0271
Product name: 2-(Hydroxymethyl)-2-nitro-1,3-propanediol
Purity: >99.0%(GC)
Packaging: 500g
Price: $163
Updated: 2024/03/01

Alfa Aesar

Product number: L13349
Product name: Tris(hydroxymethyl)nitromethane, 95%
Packaging: 100g
Price: $34.65
Updated: 2024/03/01

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Tris(hydroxymethyl)nitromethane Chemical Properties,Usage,Production

Chemical Properties

Off-white to orange solid. It crystallizes as white crystals in the mixed solution of ethyl acetate and benzene. Soluble in alcohol, slightly soluble in benzene and other hydrocarbons. Solubility in water (20°C) 220g/100ml.

Uses

Tris(hydroxymethyl)nitromethane, is used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. It is used as a primary and secondary intermediate.

Preparation

Tris(hydroxymethyl)nitromethane is prepared by the condensation of nitromethane and formaldehyde under basic conditions.

Application

Tris(hydroxymethyl)nitromethane is a bactericide and slimicide for use in cooling fluids, paper and pulp industry; as a curing agent for certain adhesives; viscositycontrolling agent in cosmetics.To inhibit bacterial growth in circulating industrial water systems, cutting oils, nonprotein glues and sizings.

General Description

Tris(hydroxymethyl)nitromethane undergoes crosslinking with hexamethylene diisocyanate to form monolithic energetic gels. It is an effective hardener for variety of tannin-based adhesives.

Hazard

Moderate fire risk. Irritant to skin and eyes.

Purification Methods

Crystallise it from CHCl3/ethyl acetate or ethyl acetate/*benzene. It is an acid and a 0.1M solution in H2O has pH 4.5. IRRITANT. [Beilstein 1 H 520.]

Tris(hydroxymethyl)nitromethane Preparation Products And Raw materials

Raw materials

Nitromethane

Preparation Products

Tris(hydroxymethyl)aminomethane

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View Lastest Price from Tris(hydroxymethyl)nitromethane manufacturers

Hebei Mujin Biotechnology Co.,Ltd

Product: Tris(hydroxymethyl)nitromethane 126-11-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-25

Hebei Zhuanglai Chemical Trading Co Ltd

Product: Tris(hydroxymethyl)nitromethane 126-11-4
Price: US $60.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2024-11-18

Apeloa production Co.,Limited

Product: 2-(Hydroxymethyl)-2-nitropropan-1,3-diol 126-11-4
Price: US $1.00/g
Min. Order: 1g
Purity: 98%
Supply Ability: 60000
Release date: 2024-06-05

126-11-4, Tris(hydroxymethyl)nitromethaneRelated Search:

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nitromethylidynetrimethanol

tris(hydroxymrthyl) nitromemethane

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TRIS(HYDROXYMETHYL)NITROMETHAN

1,1,1-Tris(hydroxymethyl)nitromethane

1,3-Dihydroxy-2-(hydroxymethyl)-2-nitropropane

Nitromethylidynetrismethanol

2-methylol-2-nitro-propane-1,3-diol

Trimethylolnitromethane Tris(hydroxymethyl)nitromethane

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2-(Hydroxymethyl)-2-nitro-1,3-propanediol&gt

tris(Hydroxymethyl)nitromethane (Tris Nitro)@100 μg/mL in Methanol

2-(Hydroxymethyl)-2-nitropropan-1,3-diol

tris(hydroxymethyl)nitromethane CAS 126-11-4

Trometamol Impurity A

Trometamol EP Impurity A

Tris(hydroxymethyl)nitoethane

2-(Hydroxymethyl)-2-nitro-1,3-propanediol, ≥ 99.0%

TRIS-NITRO (TRIS(HYDROXYMETHYL)NITROMETHANE)

126-11-4

NO2CCH2OH3

COCH33NO2

HOCH23CNO2

O2NHOCH23C

C4H9NO5

Organic Building Blocks

Oxygen Compounds