ChemicalBook > CAS DataBase List > (S)-(+)-Benzyl glycidyl ether

(S)-(+)-Benzyl glycidyl ether

Product Name
(S)-(+)-Benzyl glycidyl ether
CAS No.
16495-13-9
Chemical Name
(S)-(+)-Benzyl glycidyl ether
Synonyms
(S)-BENZYL GLYCIDYL ETHER;(2S)-2-[(Benzyloxy)methyl]oxirane;(s)-o-benzylglycidol;(S)-Benzylglycidyether;(S)-Glycidylbenzyl ether;(+)-Benzyl glycidyl ether;(S)-BENZYLOXYMETHYL-OXIRANE;BENZYL (S)-(+)-GLYCIDYL ETHER;(+)-BENZYL (S)-GLYCIDYL ETHER;(S)-(+)-BENZYL GLYCIDYL ETHER
CBNumber
CB8164324
Molecular Formula
C10H12O2
Formula Weight
164.2
MOL File
16495-13-9.mol
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(S)-(+)-Benzyl glycidyl ether Property

Boiling point:
130 °C (0.1 mmHg)
alpha 
5.1 º (c=5 in toluene)
Density 
1.072 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.517
Flash point:
>110°C
storage temp. 
2-8°C
solubility 
Chloroform, Ethanol
form 
Oil
color 
Colourless
Specific Gravity
1.077
optical activity
[α]20/D +5.1°, c = 5 in toluene
BRN 
5246495
InChI
InChI=1S/C10H12O2/c1-2-4-9(5-3-1)6-11-7-10-8-12-10/h1-5,10H,6-8H2/t10-/m1/s1
InChIKey
QNYBOILAKBSWFG-SNVBAGLBSA-N
SMILES
O1C[C@H]1COCC1=CC=CC=C1
CAS DataBase Reference
16495-13-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
RTECS 
TX2860030
HS Code 
29109000
Toxicity
mic-sat 660 nmol/plate MUREAV 298,197,1993
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
363537
Product name
(S)-(+)-Glycidyl benzyl ether
Purity
99%
Packaging
1g
Price
$22.82
Updated
2025/07/31
TCI Chemical
Product number
B2239
Product name
Benzyl (S)-(+)-Glycidyl Ether
Purity
>98.0%(GC)
Packaging
1g
Price
$20
Updated
2025/07/31
TCI Chemical
Product number
B2239
Product name
Benzyl (S)-(+)-Glycidyl Ether
Purity
>98.0%(GC)
Packaging
5g
Price
$28
Updated
2025/07/31
TCI Chemical
Product number
B2239
Product name
Benzyl (S)-(+)-Glycidyl Ether
Purity
>98.0%(GC)
Packaging
25g
Price
$75
Updated
2025/07/31
TRC
Product number
B278300
Product name
(S)-(+)-BenzylGlycidylEther
Packaging
25g
Price
$425
Updated
2021/12/16
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(S)-(+)-Benzyl glycidyl ether Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(S)-(+)-Benzyl Glycidyl Ether is used as a reactant in the synthesis of (+)-Discodermolide.

Uses

(S)-(+)-Glycidyl benzyl ether may be employed for the total asymmetric synthesis of (+)-gigantecin.

General Description

(S)-(+)-Glycidyl benzyl ether is aryl glycidyl ether. Enantiomerically pure aryl and benzyl glycidyl ethers have been reported to undergo stereospecific cyclizations, affording 3-chromanols or tetrahydrobenzo[c]oxepin-4-ols. (S)-benzyl glycidyl ether has been produced with 30%ee along with (R)-3-benzyloxypropane-1,2-diol with 40%ee, via its resolution using whole cells of Bacillus alcalophilus.

Safety Profile

Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.

Purification Methods

This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]

(S)-(+)-Benzyl glycidyl ether Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-Benzyl glycidyl ether Suppliers

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View Lastest Price from (S)-(+)-Benzyl glycidyl ether manufacturers

Shaanxi Didu New Materials Co. Ltd
Product
(S)-(+)-Benzyl glycidyl ether 16495-13-9
Price
US $1.50/g
Min. Order
1g
Purity
99.0% Min
Supply Ability
10 Tons
Release date
2025-06-24
Hebei Chuanghai Biotechnology Co,.LTD
Product
(S)-(+)-Benzyl glycidyl ether 16495-13-9
Price
US $10.70/KG
Min. Order
10KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-21
Career Henan Chemical Co
Product
4-a (S)-(+)-Benzyl glycidyl etherHYDROXYBENZENESULFONIC ACID SODIUM SALT DIHYDRATE 16495-13-9
Price
US $2.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100g , 1kg, 5kg , 50kg
Release date
2020-01-07

16495-13-9, (S)-(+)-Benzyl glycidyl etherRelated Search:

Isobutylene oxide Glycidyl acrylate (R)-Styrene oxide Benzyl benzoate Propylene oxide Ethylbenzene Polyethylene, Oxidized Dimethyl ether ETHYLENE OXIDE Benzyl alcohol Benzyl chloride Benzyl nicotinate Epichlorohydrin Benzyl (S)-(-)-Trityl glycidyl ether (R)-(-)-BENZYL GLYCIDYL ETHER,(R)-BENZYL GLYCIDYL ETHER,(R)-(-)-BENZYL GLYCIDYL ETHER, 98+% Diethyl ether BENZYL GLYCIDYL ETHER

  • (S)-(+)-2-(BENZYLOXYMETHYL)OXIRANE
  • (S)-(+)-1-BENZYLOXY-2,3-EPOXYPROPANE
  • (S)-1-BENZYLOXY-2,3-EPOXYPROPANE
  • (S)-(+)-BENZYL GLYCIDYL ETHER
  • (S)-BENZYL GLYCIDYL ETHER
  • (S)-BENZYLOXYMETHYL-OXIRANE
  • (s)-o-benzylglycidol
  • (S)-(+)-Glycidyl benzyl ether puriss., >=99.0% (sum of enantiomers, GC)
  • (S)-Benzyl Glycidyl Ether,99%e.e.
  • (+)-BENZYL (S)-GLYCIDYL ETHER
  • BENZYL (S)-(+)-GLYCIDYL ETHER
  • BENZYL (S)-(+)-GLYCIDYL ETHER, 99+%
  • (2S)-2-[(Benzyloxy)methyl]oxirane
  • (2S)-2β-(Benzyloxymethyl)oxirane
  • (S)-Glycidylbenzyl ether
  • (S)-(+)-GLYCIDYL BENZYL ETHER ((S)-(+)-2-(BENZYLOXYMETHYL)OXIRANE)
  • Benzyl (S)-(+)-glycidyl ether, 98+%
  • (S)-(+)-Benzyl glycidyl ether,98%
  • Benzyl (S)-(+)-2,3-Epoxypropyl Ether
  • (S)-(+)-1-Benzyloxy-2,3-epoxypropane (S)-(+)-2-(Benzyloxymethyl)oxirane
  • Benzyl (S)-(+)-glycidyl ether, ee: 99%
  • Benzyl (S)-(+)-glycidyl ether, 98%, ee: 99%
  • (S)-Benzyl glycidyl ether 97%
  • 4-a (S)-(+)-Benzyl glycidyl etherHYDROXYBENZENESULFONIC ACID SODIUM SALT DIHYDRATE
  • Benzyl (S)-(+)-Glycidyl Ether &gt
  • Oxirane, 2-[(phenylmethoxy)methyl]-, (2S)-
  • (2S)-2-(phenylmethoxymethyl)oxirane
  • (+)-Benzyl glycidyl ether
  • (S)-Benzylglycidyether
  • (<i>S</i>)-(+)-Glycidyl benzyl ether
  • Benzyl (S)-(+)-glycidyl ether, 98%min
  • 16495-13-9
  • Cd0H12O2
  • Asymmetric Synthesis
  • Epoxides
  • Organic Building Blocks
  • Oxiranes
  • Glycidyl Compounds, etc. (Chiral)
  • Simple 3-Membered Ring Compounds
  • Chiral Building Blocks
  • Chiral Building Blocks
  • Glycidyl Compounds, etc. (Chiral)
  • Oxiranes
  • Simple 3-Membered Ring Compounds
  • Synthetic Organic Chemistry
  • Chiral Compound
  • chiral
  • CHIRAL COMPOUNDS