(S)-(+)-Benzyl glycidyl ether

Product Name: (S)-(+)-Benzyl glycidyl ether
CAS No.: 16495-13-9
Chemical Name: (S)-(+)-Benzyl glycidyl ether
Synonyms: (S)-BENZYL GLYCIDYL ETHER;(2S)-2-[(Benzyloxy)methyl]oxirane;(s)-o-benzylglycidol;(S)-Benzylglycidyether;(S)-Glycidylbenzyl ether;(+)-Benzyl glycidyl ether;(S)-BENZYLOXYMETHYL-OXIRANE;BENZYL (S)-(+)-GLYCIDYL ETHER;(+)-BENZYL (S)-GLYCIDYL ETHER;(S)-(+)-BENZYL GLYCIDYL ETHER
CBNumber: CB8164324
Molecular Formula: C10H12O2
Formula Weight: 164.2
MOL File: 16495-13-9.mol

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(S)-(+)-Benzyl glycidyl ether Property

Boiling point:: 130 °C (0.1 mmHg)
alpha: 5.1 º (c=5 in toluene)
Density: 1.072 g/mL at 20 °C(lit.)
refractive index: n20/D 1.517
Flash point:: >110°C
storage temp.: 2-8°C
solubility: Chloroform, Ethanol
form: Oil
color: Colourless
Specific Gravity: 1.077
optical activity: [α]20/D +5.1°, c = 5 in toluene
BRN: 5246495
CAS DataBase Reference: 16495-13-9(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
WGK Germany: 3
RTECS: TX2860030
HS Code: 29109000
Toxicity: mic-sat 660 nmol/plate MUREAV 298,197,1993

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 363537
Product name: (S)-(+)-Glycidyl benzyl ether
Purity: 99%
Packaging: 1g
Price: $9.64
Updated: 2024/03/01

TCI Chemical

Product number: B2239
Product name: Benzyl (S)-(+)-Glycidyl Ether
Purity: >98.0%(GC)
Packaging: 1g
Price: $16
Updated: 2024/03/01

TCI Chemical

Product number: B2239
Product name: Benzyl (S)-(+)-Glycidyl Ether
Purity: >98.0%(GC)
Packaging: 5g
Price: $25
Updated: 2024/03/01

Alfa Aesar

Product number: L14033
Product name: Benzyl (S)-(+)-glycidyl ether, 98+%
Packaging: 1g
Price: $72.65
Updated: 2024/03/01

Alfa Aesar

Product number: L14033
Product name: Benzyl (S)-(+)-glycidyl ether, 98+%
Packaging: 5g
Price: $236.65
Updated: 2024/03/01

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(S)-(+)-Benzyl glycidyl ether Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(S)-(+)-Benzyl Glycidyl Ether is used as a reactant in the synthesis of (+)-Discodermolide.

Uses

(S)-(+)-Glycidyl benzyl ether may be employed for the total asymmetric synthesis of (+)-gigantecin.

General Description

(S)-(+)-Glycidyl benzyl ether is aryl glycidyl ether. Enantiomerically pure aryl and benzyl glycidyl ethers have been reported to undergo stereospecific cyclizations, affording 3-chromanols or tetrahydrobenzo[c]oxepin-4-ols. (S)-benzyl glycidyl ether has been produced with 30%ee along with (R)-3-benzyloxypropane-1,2-diol with 40%ee, via its resolution using whole cells of Bacillus alcalophilus.

Safety Profile

Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.

Purification Methods

This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]

(S)-(+)-Benzyl glycidyl ether Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-Benzyl glycidyl ether Suppliers

Americas 1 Belgium 1 Canada 1 China 194 Europe 3 France 1 Germany 4 India 9 Japan 4 South Korea 2 Switzerland 1 United Kingdom 9 United States 38 Global 268

TOKYO CHEMICAL INDUSTRY CO., LTD.

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View Lastest Price from (S)-(+)-Benzyl glycidyl ether manufacturers

Hebei Chuanghai Biotechnology Co,.LTD

Product: (S)-(+)-Benzyl glycidyl ether 16495-13-9
Price: US $10.70/KG
Min. Order: 10KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-21

Career Henan Chemical Co

Product: 4-a (S)-(+)-Benzyl glycidyl etherHYDROXYBENZENESULFONIC ACID SODIUM SALT DIHYDRATE 16495-13-9
Price: US $2.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100g , 1kg, 5kg , 50kg
Release date: 2020-01-07

16495-13-9, (S)-(+)-Benzyl glycidyl etherRelated Search:

Epichlorohydrin Isobutylene oxide Glycidyl acrylate (R)-Styrene oxide Benzyl benzoate Propylene oxide Ethylbenzene Polyethylene, Oxidized Dimethyl ether ETHYLENE OXIDE Benzyl alcohol Benzyl chloride Benzyl nicotinate Diethyl ether Benzyl (S)-(-)-Trityl glycidyl ether (R)-(-)-BENZYL GLYCIDYL ETHER,(R)-BENZYL GLYCIDYL ETHER,(R)-(-)-BENZYL GLYCIDYL ETHER, 98+% BENZYL GLYCIDYL ETHER

(S)-(+)-2-(BENZYLOXYMETHYL)OXIRANE

(S)-(+)-1-BENZYLOXY-2,3-EPOXYPROPANE

(S)-1-BENZYLOXY-2,3-EPOXYPROPANE

(S)-(+)-BENZYL GLYCIDYL ETHER

(S)-BENZYL GLYCIDYL ETHER

(S)-BENZYLOXYMETHYL-OXIRANE

(s)-o-benzylglycidol

(S)-(+)-Glycidyl benzyl ether puriss., >=99.0% (sum of enantiomers, GC)

(S)-Benzyl Glycidyl Ether,99%e.e.

(+)-BENZYL (S)-GLYCIDYL ETHER

BENZYL (S)-(+)-GLYCIDYL ETHER

BENZYL (S)-(+)-GLYCIDYL ETHER, 99+%

(2S)-2-[(Benzyloxy)methyl]oxirane

(2S)-2β-(Benzyloxymethyl)oxirane

(S)-Glycidylbenzyl ether

(S)-(+)-GLYCIDYL BENZYL ETHER ((S)-(+)-2-(BENZYLOXYMETHYL)OXIRANE)

Benzyl (S)-(+)-glycidyl ether, 98+%

(S)-(+)-Benzyl glycidyl ether,98%

Benzyl (S)-(+)-2,3-Epoxypropyl Ether

(S)-(+)-1-Benzyloxy-2,3-epoxypropane (S)-(+)-2-(Benzyloxymethyl)oxirane

Benzyl (S)-(+)-glycidyl ether, ee: 99%

Benzyl (S)-(+)-glycidyl ether, 98%, ee: 99%

(S)-Benzyl glycidyl ether 97%

4-a (S)-(+)-Benzyl glycidyl etherHYDROXYBENZENESULFONIC ACID SODIUM SALT DIHYDRATE

Benzyl (S)-(+)-Glycidyl Ether &gt

Oxirane, 2-[(phenylmethoxy)methyl]-, (2S)-

(2S)-2-(phenylmethoxymethyl)oxirane

(+)-Benzyl glycidyl ether

(S)-Benzylglycidyether

16495-13-9

Cd0H12O2

Asymmetric Synthesis

Epoxides

Organic Building Blocks

Oxiranes

Glycidyl Compounds, etc. (Chiral)

Simple 3-Membered Ring Compounds

Chiral Building Blocks

Glycidyl Compounds, etc. (Chiral)

Oxiranes

Simple 3-Membered Ring Compounds

Synthetic Organic Chemistry

Chiral Compound

chiral

CHIRAL COMPOUNDS