6-Methoxy-2-Acetyl Naphthalene
- Product Name
- 6-Methoxy-2-Acetyl Naphthalene
- CAS No.
- 2700-47-2
- Chemical Name
- 6-Methoxy-2-Acetyl Naphthalene
- Synonyms
- Acylcompound;Naproxen Impurity 12;LABOTEST-BB LT00452201;6-Methoxy-2-Aletyl Naphthaiene;6-Methoxy-2-propionylnaphthone;6''-Methoxy-2''-propionaphthone;2-Propinyl-6-methoxynaphthalene;6'-Methoxy-2'-propiononaphthone;62-Methoxy-22-propiononaphthone;6-Methoxy-2-Propionylnaphthalene
- CBNumber
- CB8227074
- Molecular Formula
- C14H14O2
- Formula Weight
- 214.26
- MOL File
- 2700-47-2.mol
6-Methoxy-2-Acetyl Naphthalene Property
- Melting point:
- 110-112 °C(lit.)
- Boiling point:
- 212-215 °C14 mm Hg(lit.)
- Density
- 1.0781 (rough estimate)
- refractive index
- 1.5300 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- Light brown to gray Solid
- InChI
- InChI=1S/C14H14O2/c1-3-14(15)12-5-4-11-9-13(16-2)7-6-10(11)8-12/h4-9H,3H2,1-2H3
- InChIKey
- LWOTXBQKJLOAOZ-UHFFFAOYSA-N
- SMILES
- C(C1=CC=C2C(=C1)C=CC(OC)=C2)(=O)CC
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 379360
- Product name
- 6′-Methoxy-2′-propiononaphthone
- Purity
- 98%
- Packaging
- 25g
- Price
- $261
- Updated
- 2023/01/07
- Product number
- M331988
- Product name
- 6-Methoxy-2-propiononaphthone
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- J95878
- Product name
- 6'-Methoxy-2'-propiononaphthone
- Packaging
- 1g
- Price
- $17
- Updated
- 2021/12/16
- Product number
- 3041AL
- Product name
- 6'-Methoxy-2'-propiononaphthone
- Packaging
- 1g
- Price
- $22
- Updated
- 2021/12/16
- Product number
- J95878
- Product name
- 6'-Methoxy-2'-propiononaphthone
- Packaging
- 10g
- Price
- $85
- Updated
- 2021/12/16
6-Methoxy-2-Acetyl Naphthalene Chemical Properties,Usage,Production
Chemical Properties
Light yellow crystals, melting point 101-104°C.
Synthesis Reference(s)
Synthetic Communications, 20, p. 383, 1990 DOI: 10.1080/00397919008052779
General Description
6′?Methoxy-2′?propiononaphthone is a building block useful in organic synthesis. Its density has been reported.
Synthesis
92189-66-7
2700-47-2
Example 10 Synthesis of 1-(6-methoxynaphthalen-2-yl)propan-1-one: 29.3 g of 5-bromo-6-methoxy-2-propionyl naphthalene was dissolved in 100 ml of anhydrous dichloromethane and 20.8 ml of homotrimethylbenzene. Under strong stirring, 20 g of anhydrous aluminum chloride was added in batches to the reaction mixture that was cooled to -5 °C while the temperature was controlled below 20 °C. The reaction mixture was continued to be stirred at room temperature for 3 hours. Subsequently, the reaction mixture was slowly poured under strong stirring into a mixture consisting of 110 g of ice and 35 ml of a 35% (w/v) aqueous hydrochloric acid solution. After stirring for 15 minutes, the organic and aqueous layers were separated and the aqueous layer was discarded. The organic layer was sequentially washed twice with 50 ml of aqueous 6N hydrochloric acid solution and then with 50 ml of water. Next, 50 ml of water was added to the organic solution and the pH was adjusted with 30% (w/v) aqueous sodium hydroxide to 12. After discarding the aqueous phase, the organic phase was dried with anhydrous sodium sulfate and subsequently evaporated to dryness under vacuum. The residue was crystallized by n-heptane to give 20.2 g of 1-(6-methoxynaphthalen-2-yl)propan-1-one in 94.3% yield.
References
[1] Patent: EP440930, 1991, A2
[2] Patent: US5107013, 1992, A
6-Methoxy-2-Acetyl Naphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
6-Methoxy-2-Acetyl Naphthalene Suppliers
- Tel
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- Country
- Switzerland
- ProdList
- 6896
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View Lastest Price from 6-Methoxy-2-Acetyl Naphthalene manufacturers
- Product
- 6'-Methoxy-2'-propiononaphthone 2700-47-2
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2024-12-04
- Product
- 6'-Methoxy-2'-propiononaphthone 2700-47-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2018-12-24