2,4,6-Triformylphloroglucinol
Uses- Product Name
- 2,4,6-Triformylphloroglucinol
- CAS No.
- 34374-88-4
- Chemical Name
- 2,4,6-Triformylphloroglucinol
- Synonyms
- 1,3,5-Triformylphloroglucinol;triformylPhloroglucinol;2,4,6-Triformylphloroglucinol;2,4,6-trihydroxybenzene-1,3,5-tricarbaldehyde;BZ500;1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-;2,4,6-Trihydroxy-1,3,5-benzenetricarbaldehyde, 95%;DK7335;JACS-34374-88-4;Trialdehyde Resorcinol
- CBNumber
- CB82707907
- Molecular Formula
- C9H6O6
- Formula Weight
- 210.14
- MOL File
- 34374-88-4.mol
2,4,6-Triformylphloroglucinol Property
- Melting point:
- 198-200 °C
- Boiling point:
- 233.8±40.0 °C(Predicted)
- Density
- 1.755±0.06 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- solubility
- DMSO (Slightly, Heated)
- form
- Solid
- pka
- 3.32±0.33(Predicted)
- color
- Pale Orange
- InChI
- InChI=1S/C9H6O6/c10-1-4-7(13)5(2-11)9(15)6(3-12)8(4)14/h1-3,13-15H
- InChIKey
- KAPNIDMXEKQLMQ-UHFFFAOYSA-N
- SMILES
- C1(C=O)=C(O)C(C=O)=C(O)C(C=O)=C1O
Safety
- HS Code
- 2912.49.6000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- T3688
- Product name
- 2,4,6-Triformylphloroglucinol
- Purity
- min. 98.0 %
- Packaging
- 200MG
- Price
- $52
- Updated
- 2025/07/31
- Product number
- T3688
- Product name
- 2,4,6-Triformylphloroglucinol
- Purity
- min. 98.0 %
- Packaging
- 1G
- Price
- $156
- Updated
- 2025/07/31
- Product number
- T793650
- Product name
- 2,4,6-Triformylphloroglucinol
- Packaging
- 100mg
- Price
- $105
- Updated
- 2021/12/16
- Product number
- 7572CS
- Product name
- 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde
- Packaging
- 250mg
- Price
- $146
- Updated
- 2021/12/16
- Product number
- 99790
- Product name
- 2,4,6-Triformylphloroglucinol
- Packaging
- 100mg
- Price
- $390
- Updated
- 2021/12/16
2,4,6-Triformylphloroglucinol Chemical Properties,Usage,Production
Uses
MOP is a phenolic organic compound which can be used as intermediate of synthetic materials.
Description
2,4,6-Triformylphloroglucinol (MOP)is a highly functionalised and symmetrical building block.
Physical properties
Pale orange solid
Uses
2,4,6-Triformylphloroglucinol is a chemical reagent used in gelation landscape engineering with a hydrogelator system to control products. This prevents the formation of hydrogel materials with vastly different properties. In addition, it is used in the preparation of luminescent nanoporous hybrid material to be used as a drug delivery system for anti-cancer agents.
Definition
2,4,6-Triformylphloroglucinol is a highly functionalised and symmetrical building block. 2,4,6-Triformylphloroglucinol contains 3 aldehyde groups which can react with nucleophiles, such as amines or anilines, to make β-ketoenamines. When the nucleophile contains more than one amine group, microporous polymers can be formed. These microporous polymers find a wide range of applications, including carbon dioxide capture.
Synthesis
108-73-6
100-97-0
34374-88-4
In a 50 mL xylene vial, accurately weigh 2 g of hexamethylenetetramine (urotropine) and slowly add 10 mL of fresh trifluoroacetic acid. The reaction vial needs to be cooled in an ice water bath due to the exothermic nature of the reaction which may lead to loss of trifluoroacetic acid by evaporation. Under nitrogen protection, 0.67 g of resorcinol was added to the reaction system and 50 mL of glycerol was added as solvent. Subsequently, the reaction was carried out at 120°C for 1.5 h under microwave radiation conditions. Upon completion of the reaction, the reaction mixture was cooled to room temperature and extracted by adding 30 mL of dichloromethane to isolate trifluoroacetic acid. The supernatant was subjected to a simple secondary distillation (first at 40°C and atmospheric pressure, followed by raising the temperature of the distillate to 72°C) and 7 mL of the fraction was collected. The recovered concentration of trifluoroacetic acid was measured to be 98.6% and the calculated recovery was 70% by gas chromatography analysis. The solution was filtered, the filtrate was extracted with chloroform, the mixture was treated with sulfuric acid and filtered again. The filtrate was dried under vacuum to give a light pink solid. The solid was confirmed to be 1,3,5-traldehyde mesitylene trisphenol (target product) by 1H-NMR (Figure 1) analysis in a yield of 0.085 g. The solid was analyzed by 1H-NMR (Figure 1).
References
[1] Chemistry - A European Journal, 2016, vol. 22, # 47, p. 17029 - 17036
[2] Dyes and Pigments, 2016, vol. 132, p. 291 - 305
[3] Journal of Polymer Science, Part A: Polymer Chemistry, 2018, vol. 56, # 20, p. 2344 - 2353
[4] Journal of Organic Chemistry, 2009, vol. 74, # 8, p. 3168 - 3171
[5] Journal of the American Chemical Society, 2015, vol. 137, # 45, p. 14236 - 14239
2,4,6-Triformylphloroglucinol Preparation Products And Raw materials
Raw materials
Preparation Products
2,4,6-Triformylphloroglucinol Suppliers
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View Lastest Price from 2,4,6-Triformylphloroglucinol manufacturers
- Product
- 2,4,6-Triformylphloroglucinol 34374-88-4
- Price
- US $30.00-0.80/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g，kg-tons, free sample is available
- Release date
- 2024-03-26
- Product
- 2,4,6-Triformylphloroglucinol 34374-88-4
- Price
- US $30.00-0.80/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g，kg-tons, free sample is available
- Release date
- 2024-03-26
- Product
- 2,4,6-Triformylphloroglucinol 34374-88-4
- Price
- US $30.00-0.80/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g，kg-tons, free sample is available
- Release date
- 2024-03-26