11,12-Dihydroindolo[2,3-a]carbazole
- Product Name
- 11,12-Dihydroindolo[2,3-a]carbazole
- CAS No.
- 60511-85-5
- Chemical Name
- 11,12-Dihydroindolo[2,3-a]carbazole
- Synonyms
- 11,12-Dihydroindolo[2,3-a]carbazole;3-A]CARBAZOLE;11,12-Dihydroin;12-DIHYRDOINDOLO[2;indolo[2,3-α]carbazole;INDOLO[2,3-A]CARBAZOLE;ioindolo[2,3-a]carbazole;Indolo[2,3-alpha]carbazole;dihydroindolo[2,3-a]carbazole;11,12-dihydroindolo carbazole
- CBNumber
- CB8280563
- Molecular Formula
- C18H12N2
- Formula Weight
- 256.3
- MOL File
- 60511-85-5.mol
11,12-Dihydroindolo[2,3-a]carbazole Property
- Melting point:
- 371°C(lit.)
- Boiling point:
- 569.8±23.0 °C(Predicted)
- Density
- 1.404±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- pka
- 16.70±0.30(Predicted)
- color
- White to Light yellow
- λmax
- 357nm(EtOH)(lit.)
- InChI
- InChI=1S/C18H12N2/c1-3-7-15-11(5-1)13-9-10-14-12-6-2-4-8-16(12)20-18(14)17(13)19-15/h1-10,19-20H
- InChIKey
- NSNKTSSANPWFJA-UHFFFAOYSA-N
- SMILES
- N1C2=C(C=CC=C2)C2=C1C1NC3=C(C=1C=C2)C=CC=C3
Safety
- HS Code
- 2933.99.8290
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- D4803
- Product name
- 11,12-Dihydroindolo[2,3-a]carbazole
- Purity
- >98.0%(HPLC)(N)
- Packaging
- 1g
- Price
- $99
- Updated
- 2024/03/01
- Product number
- D4803
- Product name
- 11,12-Dihydroindolo[2,3-a]carbazole
- Purity
- >98.0%(HPLC)(N)
- Packaging
- 200mg
- Price
- $35
- Updated
- 2024/03/01
- Product number
- I706455
- Product name
- Indolo[2,3-a]carbazole
- Packaging
- 5mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- I706455
- Product name
- Indolo[2,3-a]carbazole
- Packaging
- 25mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FD148295
- Product name
- 11,12-Dihydroindolo[2,3-a]carbazole
- Packaging
- 25mg
- Price
- $61
- Updated
- 2021/12/16
11,12-Dihydroindolo[2,3-a]carbazole Chemical Properties,Usage,Production
Chemical Properties
Flash Point：269.9±13.9 °C
Uses
11,12-Dihydroindolo[2,3-a]carbazole is an isomer of indole[3,2-b]carbazole. 11,12-Dihydroindolo[2,3-a]carbazole derivatives have good planarity, high thermal stability, and excellent photophysical properties. As an optoelectronic material, it is often used to synthesize TADF-OLED body and emission layer materials and as a pharmaceutical intermediate to synthesize anticancer drugs[1-3]. Chemical sensors based on indole[2,3-a]carbazole can be used to detect Cu2+ and Fe3+ in environmental and biological systems simultaneously[4]. Compared to other metal ions, the sensor has specificity and high sensitivity for the detection of Cu2+ and Fe3+ ions. For Cu2+ and Fe3+ ions, detection limits are as low as 2.93×10 -7 M and 4.10×10 -7 M.
Preparation
1,2-cyclohexanedione (1 g, 8.93 mmol) and phenylhydrazine hydrochloride (3.86 g, 26.78 mmol) were added to the reactor. Nitrogen is flushed into the flask, followed by 20 mL of acetic acid. After stirring and refluxing for 24 hours, the mixture is cooled to room temperature. The reaction mixture is slowly poured into ice water and stirred to precipitate a large amount of yellow solids. It is then filtered, washed with pure water, and dried. After purification, 11,12-Dihydroindolo[2,3-a]carbazole was obtained. Yield=95.6%
benefits
11,12-Dihydroindolo[2,3-a]carbazole could used as a donor unit. The electron-rich carbazole and indole units are contained in the plane donor, which helps to increase the electron-donating ability and hole-transporting ability.
References
[1] Tian J, et al. Synthesis and thermal, electrochemical, photophysical properties of novel symmetric/asymmetric indolo[2,3-a]carbazole derivatives bearing different aryl substituents. Tetrahedron, 2016; 73: 230-238.
[2] Zenkov R, et al. Indolo[2,3- a ]carbazoles: diversity, biological properties, application in antitumor therapy. Chemistry of Heterocyclic Compounds, 2020; 56: 644–658.
[3] Yang S, et al. Synthesis and characterization of novel butterfly-shaped aryl-substituted indolo[2,3-a]carbazole derivatives. Tetrahedron Letters, 2015; 56: 2223-2227.
[4] Chen ;Z, et al. A simple indolo[2,3-a]carbazole based colorimetric chemosensor for simultaneous detection of Cu2+ and Fe3+ ions. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2020; 234: 118236.
11,12-Dihydroindolo[2,3-a]carbazole Preparation Products And Raw materials
Raw materials
Preparation Products
11,12-Dihydroindolo[2,3-a]carbazole Suppliers
- Tel
- 027-86697669 13986148687
- Fax
- 86-027-86697669
- sales@tcaschem.com
- Country
- China
- ProdList
- 4089
- Advantage
- 55
- Tel
- 027-61752687 15071066002
- Fax
- -
- solomlibo@163.com
- Country
- China
- ProdList
- 136
- Advantage
- 55
- Tel
- 027-81360608 13971310049
- Fax
- 027-81360608
- 109321999@qq.com
- Country
- China
- ProdList
- 52
- Advantage
- 58
- Tel
- 0576-84521666 13666863188
- huzhen777@126.com
- Country
- China
- ProdList
- 53
- Advantage
- 58
- Tel
- 18860389453
- wade@oubertec.com
- Country
- China
- ProdList
- 378
- Advantage
- 58
- Tel
- 0799-3607521 17379923216
- Fax
- 0799-3607525
- sale@guanmat.com
- Country
- China
- ProdList
- 307
- Advantage
- 55
- Tel
- 021-31115312 18217084087
- Fax
- 86 021 31115317
- mary@hohance.com
- Country
- China
- ProdList
- 139
- Advantage
- 62
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24539
- Advantage
- 81
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44751
- Advantage
- 61
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9551
- Advantage
- 66
- Tel
- 010-69706062-8030 18511583708
- Fax
- +86-10-69706062
- sunxuxia@greenguardee.com
- Country
- China
- ProdList
- 309
- Advantage
- 56
- Tel
- 021-50521775 15800962688
- Fax
- 86-21-58306291
- sales@hanshangchem.com
- Country
- China
- ProdList
- 471
- Advantage
- 57
- Tel
- +86-021-62885108 +8613917661608
- info@spring-chem.com
- Country
- China
- ProdList
- 2068
- Advantage
- 57
- Tel
- 021-61551611 13296011611
- Fax
- ＋86 21-50676805
- contact@trustwe.com
- Country
- China
- ProdList
- 9900
- Advantage
- 58
- Tel
- +86057186818502 13588463833
- Fax
- Pls mail us for more information!
- info@sagechem.com
- Country
- China
- ProdList
- 10269
- Advantage
- 58
- Tel
- 02150456736 13818239876
- Fax
- 021-50761379
- xin@riyngroup.com
- Country
- China
- ProdList
- 1136
- Advantage
- 30
- Tel
- +86 21 61551611
- Fax
- +86 21 50676805
- Country
- China
- ProdList
- 9901
- Advantage
- 58
- Tel
- 13901585132
- Fax
- +86-25-52131256
- 799750417@qq.com
- Country
- China
- ProdList
- 8888
- Advantage
- 55
- Tel
- 18521735133 18521732826;
- Fax
- 021-50323701
- market@aladdin-e.com
- Country
- China
- ProdList
- 25015
- Advantage
- 65
- Tel
- Mobile:13665161512
- Fax
- +86-510-68873513
- Country
- China
- ProdList
- 1785
- Advantage
- 58
- Tel
- 0371-67759225 13526468238
- Fax
- +86-37155919558
- sales@hqmat.com
- Country
- China
- ProdList
- 525
- Advantage
- 60
- Tel
- 400-1647117 15221909166
- Fax
- +86-21-61629029
- product02@bidepharm.com
- Country
- China
- ProdList
- 41438
- Advantage
- 60
- Tel
- 021-021-56795766
- Fax
- +86-21-56795266
- sales@worldyachem.com
- Country
- China
- ProdList
- 9352
- Advantage
- 58
- Tel
- 18040571231/1402788087
- Fax
- sales@chemduro.com
- Country
- China
- ProdList
- 1973
- Advantage
- 58
- Tel
- 027-87465837 19945049750
- Fax
- 027-8777-2287
- sales@finetechnology-ind.com
- Country
- China
- ProdList
- 9636
- Advantage
- 58
- Tel
- +86-571-87396432
- Fax
- 0571-87396431
- sales@jhechem.com
- Country
- China
- ProdList
- 10015
- Advantage
- 53
- Tel
- +86-021-58380978 +86-18017016373
- Fax
- 021-58380978
- info@systeambc.com
- Country
- China
- ProdList
- 937
- Advantage
- 50
- Tel
- +86-021-61654350
- Fax
- +86-021-61654350
- 1245958370@qq.com
- Country
- China
- ProdList
- 2984
- Advantage
- 50
- Tel
- 025-57018978 18251899859
- Fax
- 025-57018008
- sales@chalf-pharm.com
- Country
- China
- ProdList
- 5948
- Advantage
- 50
- Tel
- 17703858868
- 1819929654@qq.com
- Country
- China
- ProdList
- 288
- Advantage
- 50
- Tel
- 021-18721936-595 18721936595
- Fax
- -
- shkylpharma@126.com
- Country
- China
- ProdList
- 685
- Advantage
- 55
- Tel
- 027-59599241 18871490274
- Fax
- 027-59599241
- 1400878000@qq.com
- Country
- China
- ProdList
- 9972
- Advantage
- 58
- Tel
- 0512-62795659 15050461859;
- Fax
- 0512-6279-5659
- sales@szgeao.com
- Country
- China
- ProdList
- 509
- Advantage
- 60
- Tel
- 28-87999436 02887999436
- Fax
- QQ:2746983436
- sales@sano-chem.com
- Country
- China
- ProdList
- 3929
- Advantage
- 55
- Tel
- 15618758386 15618758386
- Fax
- QQ:3004479444
- sales3@myuchem.com
- Country
- China
- ProdList
- 2021
- Advantage
- 55
- Tel
- 021-56789108 18694901298
- Fax
- 021-56789108
- wishpharma0713@gmail.com
- Country
- China
- ProdList
- 258
- Advantage
- 56
- Tel
- 0371-53765687 18937137882
- Fax
- QQ:2885373884
- 2853979813@qq.com
- Country
- China
- ProdList
- 7998
- Advantage
- 55
- Tel
- 3429815786 13301662590
- Fax
- +86-21-51619052
- sales@atkchemical.com
- Country
- China
- ProdList
- 10006
- Advantage
- 55
- Tel
- 0311-89250318 031166536426
- Fax
- 4000311741
- master@sjzsdyn.com
- Country
- China
- ProdList
- 3496
- Advantage
- 58
- Tel
- 0632-2980981 15063270987
- Fax
- 0632-2989678
- service.china3@viwit.com
- Country
- China
- ProdList
- 117
- Advantage
- 55
- Tel
- 021-61312847; 18021002903
- Fax
- QQ:3008007432
- 3008007409@qq.com
- Country
- China
- ProdList
- 27322
- Advantage
- 60
- Tel
- 02781293128
- orders@biochemsafebuy.com
- Country
- China
- ProdList
- 9934
- Advantage
- 55
- Tel
- 021-021-20242659 18930833303
- Fax
- +86 (21) 2024-2659
- order@changyanchem.com
- Country
- China
- ProdList
- 5008
- Advantage
- 55
- Tel
- 0371-55289822 18737195735
- Fax
- QQ：2370407954
- 2370407954@qq.com
- Country
- China
- ProdList
- 2000
- Advantage
- 55
- Tel
- 400-1166-196 18502815961
- Fax
- QQ：800101999
- cdhxsj@163.com
- Country
- China
- ProdList
- 14623
- Advantage
- 60
- Tel
- Fax
- -
- 13006575422@163.com
- Country
- China
- ProdList
- 6357
- Advantage
- 58
- Tel
- 0371-0371-55629727 13323845623
- Fax
- 037155629727
- 2885676761@qq.com
- Country
- China
- ProdList
- 9859
- Advantage
- 58
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131981
- Advantage
- 58
- Tel
- 0311-68030586 18031147013
- Fax
- 0311-68030586
- yeshengchemical@163.com
- Country
- China
- ProdList
- 2977
- Advantage
- 58
- Tel
- 025-66162170
- Fax
- 025-66162170
- Country
- China
- ProdList
- 7183
- Advantage
- 55
View Lastest Price from 11,12-Dihydroindolo[2,3-a]carbazole manufacturers
- Product
- 11,12-Dihydroindolo[2,3-a]carbazole 60511-85-5
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-23
- Product
- 11,12-Dihydroindolo[2,3-a]carbazole 60511-85-5
- Price
- US $35.00-25.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 Ton
- Release date
- 2023-10-11
- Product
- 11,12-DIHYRDOINDOLO[2,3-A]CARBAZOLE 60511-85-5
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99.9%
- Supply Ability
- 30000 Kg
- Release date
- 2023-12-13