ChemicalBook > CAS DataBase List > ETHYL 1-CYANOCYCLOPROPANECARBOXYLATE
ETHYL 1-CYANOCYCLOPROPANECARBOXYLATE
- Product Name
- ETHYL 1-CYANOCYCLOPROPANECARBOXYLATE
- CAS No.
- 1558-81-2
- Chemical Name
- ETHYL 1-CYANOCYCLOPROPANECARBOXYLATE
- Synonyms
- ethyl 1-cyanocyclopropane-1-carboxylate;Ethyl 1-cyacyclopropanecarboxylate;ethyl 1-cyanocyclopropane-1-carboxyl;ETHYL 1-CYANOCYCLOPROPANECARBOXYLATE;Ethyl 1-cyanocyclopropan-carboxylate;ETHYL 1-CYANO-1-CYCLOPROPANECARBOXYLATE;Ethyl 1-cyanocyclopropanecarboxylate 96%;1-cyano-2-ethyl-1-cyclopropanecarboxylate;Ethyl 1-cyano-1-cyclopropanecarboxylate 96%;1-CYANO-CYCLOPROPANECARBOXYLIC ACIDETHYL ESTER
- CBNumber
- CB8283100
- Molecular Formula
- C7H9NO2
- Formula Weight
- 139.15
- MOL File
- 1558-81-2.mol
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ETHYL 1-CYANOCYCLOPROPANECARBOXYLATE Property
- Boiling point:
- 217 °C (lit.)
- Density
- 1.077 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.445(lit.)
- Flash point:
- 211 °F
- storage temp.
- Sealed in dry,Room Temperature
- form
- liquid
- color
- colorless
- InChI
- InChI=1S/C7H9NO2/c1-2-10-6(9)7(5-8)3-4-7/h2-4H2,1H3
- InChIKey
- FDZLCIITHLSEQK-UHFFFAOYSA-N
- SMILES
- C1(C#N)(C(OCC)=O)CC1
- CAS DataBase Reference
- 1558-81-2(CAS DataBase Reference)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 543055
- Product name
- Ethyl 1-cyano-1-cyclopropanecarboxylate
- Purity
- 96%
- Packaging
- 5g
- Price
- $35.21
- Updated
- 2025/07/31
TRC
- Product number
- E926380
- Product name
- Ethyl1-cyanocyclopropanecarboxylate
- Packaging
- 1g
- Price
- $45
- Updated
- 2021/12/16
TRC
- Product number
- E926380
- Product name
- Ethyl1-cyanocyclopropanecarboxylate
- Packaging
- 25g
- Price
- $110
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 065291
- Product name
- Ethyl 1-cyanocyclopropanecarboxylate
- Packaging
- 500mg
- Price
- $158
- Updated
- 2021/12/16
Apolloscientific
- Product number
- OR315517
- Product name
- Ethyl1-cyanocyclopropanecarboxylate
- Purity
- 96%
- Packaging
- 25g
- Price
- $186
- Updated
- 2021/12/16
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ETHYL 1-CYANOCYCLOPROPANECARBOXYLATE Chemical Properties,Usage,Production
Uses
Ethyl 1-cyano-1-cyclopropanecarboxylate may be used as a monomer in the preparation of poly(ethyl trimethylene-1-cyano-1-carboxylate)s.
General Description
Ethyl 1-cyano-1-cyclopropanecarboxylate (ethyl 1-cyanocyclopropanecarboxylate) is an alkyl 1-cyanocyclopanecarboxylate. It can be prepared by reacting ethyl cyanoacetate, 1,2-dibromoethane, potassium carbonate and DMSO.
Synthesis
106-93-4
105-56-6
1558-81-2
The general procedure for the synthesis of ethyl 1-cyanocyclopropanecarboxylate from 1,2-dibromoethane and ethyl cyanoacetate was as follows: a suspension of ethyl cyanoacetate (11.3 g, 0.1 mol), 1,2-dibromoethane, tetrabutylammonium bromide (Na 4 (n-Bu)4Br) and potassium carbonate (K 2 CO 3 ) in N,N-dimethylformamide (DMF, 100 mL) was heated to 80 °C and reacted overnight. Upon completion of the reaction, the mixture was poured into water (600 mL) and extracted with ethyl acetate (EtOAc, 3 x 50 mL). The organic layers were combined, washed with saturated saline, dried over anhydrous sodium sulfate (Na 2 SO 4 ) and concentrated under reduced pressure to give the crude product. The crude product was purified by silica gel column chromatography (eluent: petroleum ether/ethyl acetate = 10:1) to afford ethyl 1-cyanocyclopropanecarboxylate (10 g, yield: 72%).1H NMR (CDCl3, 400 MHz): δ 4.21 (q, J = 7.2 Hz, 2H), 1.65-1.61 (m, 2H), 1.58-1.55 (m, 2H) , 1.28 (t, J = 7.2 Hz, 3H).
References
[1] Journal of Organic Chemistry USSR (English Translation), 1983, vol. 19, p. 474 - 480
[2] Zhurnal Organicheskoi Khimii, 1983, vol. 19, # 3, p. 541 - 548
[3] Synthetic Communications, 1996, vol. 26, # 3, p. 525 - 530
[4] Tetrahedron Letters, 2005, vol. 46, # 4, p. 635 - 638
[5] Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2004, vol. 43, # 2, p. 420 - 422
ETHYL 1-CYANOCYCLOPROPANECARBOXYLATE Preparation Products And Raw materials
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View Lastest Price from ETHYL 1-CYANOCYCLOPROPANECARBOXYLATE manufacturers
Henan Fengda Chemical Co., Ltd
- Product
- Ethyl 1-cyanocyclopropanecarboxylate 1558-81-2
- Price
- US $200.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-30
Career Henan Chemical Co
- Product
- ETHYL 1-CYANOCYCLOPROPANECARBOXYLATE 1558-81-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20kg
- Release date
- 2018-08-13
1558-81-2, ETHYL 1-CYANOCYCLOPROPANECARBOXYLATERelated Search:
Methyl cyanoacetate
Ethyl cyanoacetate
Ethyl 2-cyanopropanoate
1-METHYLCYCLOPROPANE-1-CARBOXYLIC ACID METHYL ESTER
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Cyclopropanecarboxylic acid
3-Methoxypropionitrile
3-Ethoxypropionitrile
Trimethylacetonitrile
Cyanoacetic acid
Ethyl cyclopropanecarboxylate
ETHYL 1-METHYLCYCLOPROPANE-1-CARBOXYLATE
Methyl cyclopropane carboxylate
ETHYL 1-CYANOCYCLOPROPANECARBOXYLATE
Cyclopropanecarbonitrile
1-Cyano-1-cyclopropanecarboxylic acid
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2-cyano-2-methylpropanoic acid