Bis(benzonitrile)dichloroplatinum(II)
- Product Name
- Bis(benzonitrile)dichloroplatinum(II)
- CAS No.
- 14873-63-3
- Chemical Name
- Bis(benzonitrile)dichloroplatinum(II)
- Synonyms
- bis(Benzonitrile)dichloroplatinum;Dichlorobis-(benzonitrilo)-platinum;bis(benzonitrile)platinum(Ⅱ)chloride;Platinum, bis(benzonitrile)dichloro-;BIS(BENZONITRILE)DICHLOROPLATINUM(II);DICHLOROBIS(BENZONITRILE)PLATINUM(LL);BIS(BENZONITRILE)PLATINUM(II) CHLORIDE;DICHLOROBIS(BENZONITRILE)PLATINUM (II);BIS(BENZONITRILE)DICHLOROPLATINATE (II);Bis(benzonitrile)palatinum(II) chloride
- CBNumber
- CB8287724
- Molecular Formula
- C14H10Cl2N2Pt
- Formula Weight
- 472.23
- MOL File
- 14873-63-3.mol
Bis(benzonitrile)dichloroplatinum(II) Property
- Melting point:
- 224 °C (dec.)(lit.)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Slightly soluble in acetone, chloroform
- form
- crystal
- color
- yellow to orange
- Exposure limits
- ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
Safety
- Risk Statements
- 20/21/22
- Safety Statements
- 26-36/37/39
- RIDADR
- UN3439
- WGK Germany
- 3
- RTECS
- TP2185000
- HazardClass
- 6.1
- PackingGroup
- III
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H311Toxic in contact with skin
H317May cause an allergic skin reaction
H331Toxic if inhaled
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P284Wear respiratory protection.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 010004
- Product name
- Bis(benzonitrile)dichloroplatinum(II), Pt 40% min
- Packaging
- 1g
- Price
- $240
- Updated
- 2024/03/01
- Product number
- 010004
- Product name
- Bis(benzonitrile)dichloroplatinum(II), Pt 40% min
- Packaging
- 0.5g
- Price
- $127
- Updated
- 2023/06/20
- Product number
- 78-0360
- Product name
- Dichlorobis(benzonitrile)platinum(II), 99%
- Packaging
- 250mg
- Price
- $77
- Updated
- 2024/03/01
- Product number
- 78-0360
- Product name
- Dichlorobis(benzonitrile)platinum(II), 99%
- Packaging
- 1g
- Price
- $235
- Updated
- 2024/03/01
- Product number
- 010004
- Product name
- Bis(benzonitrile)dichloroplatinum(II), Pt 40% min
- Packaging
- 5g
- Price
- $1010
- Updated
- 2023/06/20
Bis(benzonitrile)dichloroplatinum(II) Chemical Properties,Usage,Production
Uses
Bis(benzonitrile)dichloroplatinum(II) is used as a catalyst for asymmetric hydroformylation reactions, allylation reactions, cyclopropanation reactions, hydrosilylation reactions and carbene insertion into O-H bonds of alcohols.
Preparation
Bis(benzonitrile)dichloroplatinum(II) can be prepared as a mixture of cis and trans complexes. The reaction of Palladium(II) Chloride in benzonitrile at room temperature for 7 h yields a mixture that can be separated chromatographically to yield 26% trans- and 58% cis-PtCl2(PhCN)2. An alternate route requires stoichiometric amounts of potassium tetrachloroplatinate(II) and benzonitrile stirred at room temperature for one week. Trituration of the product with hot benzene yields pure cis-PtCl2(PhCN)2 in 60% yield; the cooled benzene solution yields pure trans-PtCl2(PhCN)2 in 20% yield.
Purification Methods
chromatography on silica gel with dichloromethane as eluant, or trituration with hot benzene.
Bis(benzonitrile)dichloroplatinum(II) Preparation Products And Raw materials
Raw materials
Preparation Products
Bis(benzonitrile)dichloroplatinum(II) Suppliers
- Tel
- --
- Fax
- --
- sales@carbosynth.com
- Country
- United Kingdom
- ProdList
- 6005
- Advantage
- 58
- Tel
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- Fax
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- kevinbanks@molekula.com
- Country
- United Kingdom
- ProdList
- 6140
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- 66
- Tel
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- Fax
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- solutions@vwr.com
- Country
- United Kingdom
- ProdList
- 6548
- Advantage
- 82
View Lastest Price from Bis(benzonitrile)dichloroplatinum(II) manufacturers
- Product
- HAFNIUM 14873-63-3
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2022-09-26
- Product
- Bis(benzonitrile)dichloroplatinum(II) 14873-63-3
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2022-09-23
- Product
- Bis(benzonitrile)dichloroplatinum(II) 14873-63-3
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 95%-99%
- Supply Ability
- 100kg
- Release date
- 2018-12-22