Bis(benzonitrile)dichloroplatinum(II)

Product Name: Bis(benzonitrile)dichloroplatinum(II)
CAS No.: 14873-63-3
Chemical Name: Bis(benzonitrile)dichloroplatinum(II)
Synonyms: bis(Benzonitrile)dichloroplatinum;Dichlorobis(benzonitrile)platinum;Dichlorobis-(benzonitrilo)-platinum;bis(benzonitrile)platinum(Ⅱ)chloride;Platinum, bis(benzonitrile)dichloro-;BIS(BENZONITRILE)DICHLOROPLATINUM(II);DICHLOROBIS(BENZONITRILE)PLATINUM(LL);BIS(BENZONITRILE)PLATINUM(II) CHLORIDE;DICHLOROBIS(BENZONITRILE)PLATINUM (II);BIS(BENZONITRILE)DICHLOROPLATINATE (II)
CBNumber: CB8287724
Molecular Formula: C14H10Cl2N2Pt
Formula Weight: 472.23
MOL File: 14873-63-3.mol

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Bis(benzonitrile)dichloroplatinum(II) Property

Melting point:: 224 °C (dec.)(lit.)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Slightly soluble in acetone, chloroform
form: crystal
color: yellow to orange
Exposure limits: ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3

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Safety

Risk Statements: 20/21/22
Safety Statements: 26-36/37/39
RIDADR: UN3439
WGK Germany: 3
RTECS: TP2185000
HazardClass: 6.1
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H311Toxic in contact with skin

H317May cause an allergic skin reaction

H331Toxic if inhaled

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P284Wear respiratory protection.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 921041
Product name: Dichlorobis(benzonitrile)platinum(II)
Purity: ≥99.9%
Packaging: 500 mg
Price: $118.75
Updated: 2025/07/31

Sigma-Aldrich

Product number: 921041
Product name: Dichlorobis(benzonitrile)platinum(II)
Purity: ≥99.9%
Packaging: 1 g
Price: $211.85
Updated: 2025/07/31

Strem Chemicals

Product number: 78-0360
Product name: Dichlorobis(benzonitrile)platinum(II), 99%
Packaging: 250mg
Price: $77
Updated: 2024/03/01

Strem Chemicals

Product number: 78-0360
Product name: Dichlorobis(benzonitrile)platinum(II), 99%
Packaging: 1g
Price: $235
Updated: 2024/03/01

Strem Chemicals

Product number: 78-0360
Product name: Dichlorobis(benzonitrile)platinum(II), 99%
Packaging: 5g
Price: $938
Updated: 2024/03/01

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Bis(benzonitrile)dichloroplatinum(II) Chemical Properties,Usage,Production

Uses

Bis(benzonitrile)dichloroplatinum(II) is used as a catalyst for asymmetric hydroformylation reactions, allylation reactions, cyclopropanation reactions, hydrosilylation reactions and carbene insertion into O-H bonds of alcohols.

Preparation

Bis(benzonitrile)dichloroplatinum(II) can be prepared as a mixture of cis and trans complexes. The reaction of Palladium(II) Chloride in benzonitrile at room temperature for 7 h yields a mixture that can be separated chromatographically to yield 26% trans- and 58% cis-PtCl2(PhCN)2. An alternate route requires stoichiometric amounts of potassium tetrachloroplatinate(II) and benzonitrile stirred at room temperature for one week. Trituration of the product with hot benzene yields pure cis-PtCl2(PhCN)2 in 60% yield; the cooled benzene solution yields pure trans-PtCl2(PhCN)2 in 20% yield.

Purification Methods

chromatography on silica gel with dichloromethane as eluant, or trituration with hot benzene.

Bis(benzonitrile)dichloroplatinum(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(benzonitrile)dichloroplatinum(II) Suppliers

China 92 Germany 2 Japan 1 United Kingdom 3 United States 11 Global 109

HBCChem, Inc.

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View Lastest Price from Bis(benzonitrile)dichloroplatinum(II) manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Bis(benzonitrile)dichloroplatinum(II) 14873-63-3
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-19

henan kanbei chemical co.,ltd

Product: HAFNIUM 14873-63-3
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-26

henan kanbei chemical co.,ltd

Product: Bis(benzonitrile)dichloroplatinum(II) 14873-63-3
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-23

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Dichlorobis(benzonitrile)platinum

14873-63-3

PtCl2C6H5CN2

C14H10Cl2N2Pt

Catalysis and Inorganic Chemistry

Pt

organometallic complexes