1-METHYLPHENANTHRENE
- Product Name
- 1-METHYLPHENANTHRENE
- CAS No.
- 832-69-9
- Chemical Name
- 1-METHYLPHENANTHRENE
- Synonyms
- NSC 146583;1-methyl-phenanthren;1-METHYLPHENANTHRENE;PHENANTHRENE,1-METHYL-;1-Methylphenanthrene in Cyclohexane;1-Methylphenanthrene 100mg [832-69-9];1-MethylphenanthreneSolution,50mg/L,1ml;1-Methylphenanthrene @50 μg/mL in Toluene;1-MethylphenanthreneSolution,5,000mg/L,1ml;1-MethylphenanthreneSolution,2,000mg/L,1ml
- CBNumber
- CB8339474
- Molecular Formula
- C15H12
- Formula Weight
- 192.26
- MOL File
- 832-69-9.mol
1-METHYLPHENANTHRENE Property
- Melting point:
- 123°C
- Boiling point:
- 353.25°C (rough estimate)
- Density
- 1.0561 (estimate)
- refractive index
- 1.6031 (estimate)
- storage temp.
- Room Temperature
- solubility
- Soluble in alcohol (Weast, 1986)
- form
- Solid
- color
- White powder or solid.
- Water Solubility
- 269ug/L(25 ºC)
- Henry's Law Constant
- 1.56, 2.33, 3.42, 4.93, and 6.68 x 10-5 atm?m3/mol at 4.1, 11.0, 18.0, 25.0, and 31.0 °C, respectively (Bamford et al., 1998)
- IARC
- 3 (Vol. Sup 7, 92) 2010
- EPA Substance Registry System
- 1-Methylphenanthrene (832-69-9)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H351Suspected of causing cancer
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P273Avoid release to the environment.
P281Use personal protective equipment as required.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P308+P313IF exposed or concerned: Get medical advice/attention.
P330Rinse mouth.
P391Collect spillage. Hazardous to the aquatic environment
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- M325415
- Product name
- 1-Methylphenanthrene
- Packaging
- 50mg
- Price
- $185
- Updated
- 2021/12/16
- Product number
- M325415
- Product name
- 1-Methylphenanthrene
- Packaging
- 500mg
- Price
- $1455
- Updated
- 2021/12/16
- Product number
- CHM0238012
- Product name
- 1-METHYLPHENANTHRENE
- Purity
- 98.00%
- Packaging
- 1G
- Price
- $1212.75
- Updated
- 2021/12/16
- Product number
- CHM0238012
- Product name
- 1-METHYLPHENANTHRENE
- Purity
- 98.00%
- Packaging
- 25G
- Price
- $2021.25
- Updated
- 2021/12/16
- Product number
- 52320
- Product name
- 1-Methylphenanthrene
- Packaging
- 500mg
- Price
- $2200
- Updated
- 2021/12/16
1-METHYLPHENANTHRENE Chemical Properties,Usage,Production
Uses
1-Methylphenanthrene is a polycyclic aromatic hydrocarbon that has been found in particulate matter from small-scale biomass combustion from old and modern technologies and that has caused acute systemic and lung inflammation in mice after intratracheal aspiration.
Definition
ChEBI: A member of the class of phenanthrenes that is phenanthrene substituted by a methyl group at position 1.
Synthesis Reference(s)
The Journal of Organic Chemistry, 45, p. 2009, 1980 DOI: 10.1021/jo01298a054
Tetrahedron Letters, 6, p. 359, 1965
General Description
White crystalline powder.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as 1-METHYLPHENANTHRENE, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction. 1-METHYLPHENANTHRENE is sensitive to excessive heat and light.
Fire Hazard
Flash point data for 1-METHYLPHENANTHRENE are not available. 1-METHYLPHENANTHRENE is probably combustible.
Source
Detected in 8 diesel fuels at concentrations ranging from 0.10 to 210 mg/L with a mean
value of 44.33 mg/L (Westerholm and Li, 1994). Identified in a South Louisiana crude oil at a
concentration of 111 ppm (Pancirov and Brown, 1975). Schauer et al. (1999) reported 1-
methylphenanthrene in diesel fuel at a concentration of 28 μg/g and in a diesel-powered mediumduty
truck exhaust at an emission rate of 17.0 μg/km.
California Phase II reformulated gasoline contained 1-methylphenathrene at a concentration of
3.91 g/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without
catalytic converters were approximately 1.63 and 122 μg/km, respectively (Schauer et al., 2002).
Schauer et al. (2001) measured organic compound emission rates for volatile organic
compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds
from the residential (fireplace) combustion of pine, oak, and eucalyptus. The respective gas-phase
and particle-phase emission rates of 1-methylphenanthrene were 2.22 and 0.579 mg/kg of pine
burned and 1.04 and 0.050 mg/kg of oak burned. The gas-phase emission rate was 0.720 mg/kg of
eucalyptus burned.
1-METHYLPHENANTHRENE Preparation Products And Raw materials
Raw materials
Preparation Products
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