ChemicalBook > CAS DataBase List > 6-Methylquinoxaline

6-Methylquinoxaline

Product Name
6-Methylquinoxaline
CAS No.
6344-72-5
Chemical Name
6-Methylquinoxaline
Synonyms
6-METHYLQUINOXALINE;Quinoxaline, 6-methyl-;6-METHYLQUINOXALINE 99%;6-Methylquinoxaline , 97+%
CBNumber
CB8340621
Molecular Formula
C9H8N2
Formula Weight
144.17
MOL File
6344-72-5.mol
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6-Methylquinoxaline Property

Melting point:
218.5°C
Boiling point:
244-245°C
Density 
1.1164
refractive index 
1.6190
Flash point:
244-245°C
storage temp. 
Sealed in dry,Room Temperature
pka
1.40±0.30(Predicted)
Appearance
Light yellow to brown Liquid
BRN 
113371
InChI
InChI=1S/C9H8N2/c1-7-2-3-8-9(6-7)11-5-4-10-8/h2-6H,1H3
InChIKey
OSRARURJYPOUOV-UHFFFAOYSA-N
SMILES
N1C2C(=CC(C)=CC=2)N=CC=1
LogP
1.872 (est)
CAS DataBase Reference
6344-72-5(CAS DataBase Reference)
NIST Chemistry Reference
Quinoxaline, 6-methyl-(6344-72-5)
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Safety

Hazard Codes 
Xn,Xi,C,F
Risk Statements 
22-36/37/38-34-11
Safety Statements 
23-26-36/37/39-45-16
HazardClass 
IRRITANT
HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

AK Scientific
Product number
J52301
Product name
6-Methylquinoxaline
Packaging
1g
Price
$10
Updated
2021/12/16
Oakwood
Product number
002740
Product name
6-Methylquinoxaline
Purity
99%
Packaging
1g
Price
$10
Updated
2021/12/16
Oakwood
Product number
002740
Product name
6-Methylquinoxaline
Purity
99%
Packaging
5g
Price
$26
Updated
2021/12/16
Matrix Scientific
Product number
006430
Product name
6-Methylquinoxaline
Purity
99%
Packaging
5g
Price
$27
Updated
2021/12/16
SynQuest Laboratories
Product number
3H32-1-2D
Product name
6-Methylquinoxaline
Packaging
5G
Price
$80
Updated
2021/12/16
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6-Methylquinoxaline Chemical Properties,Usage,Production

Uses

6-Methylquinoxaline (CAS# 6344-72-5) can be used as a conductive roller for electrophotographic apparatus. It has also be known for its sequential synthesis, olfactory properties, and biological activity.

Definition

ChEBI: 6-Methylquinoxaline is a quinoxaline derivative.

Synthesis

517-21-5

496-72-0

6344-72-5

Synthesis of 6-methylquinoxaline: 3,4-diaminotoluene (Aldrich, 100 g, 0.82 mol) was dissolved in 600 mL of hot water (70-75°C) and quickly added to a slurry of glyoxal-sodium bisulfite adduct (Aldrich, 239.5 g, 0.9 mol, 1.1 equiv) in 400 mL of water at 60°C. The reaction mixture was heated at 60 °C for 1 h and then 5 g (0.02 mol) of the glyoxal adduct was added retrospectively. After cooling to room temperature, it was filtered through a paper filter. The filtrate was neutralized to pH 7.5-7.8 with 5 M NaOH aqueous solution and subsequently extracted with ether (4 x 400 mL). The combined organic phases were dried over anhydrous Na2SO4 and concentrated by rotary evaporation to give 92 g of brown oil. This crude product was purified by vacuum distillation (boiling point 100-102 °C, 10 mmHg; literature value: 86 °C, 1 mmHg) to give 89 g (75% yield) of light yellow oily target product.

References

[1] Patent: US2005/282820, 2005, A1. Location in patent: Page/Page column 17-18
[2] Journal of the Chemical Society - Perkin Transactions 1, 1999, # 7, p. 803 - 810
[3] Journal of the American Chemical Society, 1947, vol. 69, p. 795,796

6-Methylquinoxaline Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 6-Methylquinoxaline manufacturers

JINING XINHE CHEMICAL CO., LTD
Product
6-Methylquinoxaline 6344-72-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
10ton
Release date
2024-07-22