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1-ACETOXY-1-CYANOETHYLENE

Product Name
1-ACETOXY-1-CYANOETHYLENE
CAS No.
3061-65-2
Chemical Name
1-ACETOXY-1-CYANOETHYLENE
Synonyms
2-HYDROXYACRYLONITRILE;1-CYANOVINYL ACETATE;2-ACETOXYACRYLONITRILE;α-acetoxyacrylonitrile;1-cyanoethenyl acetate;alpha-cyanovinylacetate;alpha-Cyanovinyl acetate;1-cyanoethenyl ethanoate;1-ACETOXY-1-CYANOETHYLENE;ALPHA-ACETOXYACRYLONITRILE
CBNumber
CB8360889
Molecular Formula
C5H5NO2
Formula Weight
111.1
MOL File
3061-65-2.mol
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1-ACETOXY-1-CYANOETHYLENE Property

Boiling point:
80-82 °C30 mm Hg(lit.)
Density 
1.061 g/mL at 20 °C(lit.)
vapor pressure 
30 mm Hg ( 80 °C)
refractive index 
n20/D 1.426(lit.)
Flash point:
147 °F
storage temp. 
Sealed in dry,2-8°C
solubility 
sol most organic solvents other than pure hydrocarbons.
form 
clear liquid
color 
Colorless to Light yellow
BRN 
1751158
CAS DataBase Reference
3061-65-2(CAS DataBase Reference)
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Safety

Hazard Codes 
T
Risk Statements 
23/24/25-41-37/38
Safety Statements 
36/37/39-45-26
RIDADR 
UN 3276 6.1/PG 2
WGK Germany 
3
RTECS 
AG4550000
HS Code 
2926.90.5050
HazardClass 
6.1(a)
PackingGroup 
II
Toxicity
skn-rbt 10 mg/24H open MLD AIHAAP 23,95,62
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H227Combustible liquid

H301Toxic if swalloed

H310Fatal in contact with skin

H315Causes skin irritation

H318Causes serious eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P262Do not get in eyes, on skin, or on clothing.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P350IF ON SKIN: Gently wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
A1477
Product name
1-Cyanovinyl Acetate (stabilized with TBC)
Purity
>97.0%(GC)
Packaging
5g
Price
$307
Updated
2024/03/01
TCI Chemical
Product number
A1477
Product name
1-Cyanovinyl Acetate (stabilized with TBC)
Purity
>97.0%(GC)
Packaging
25g
Price
$1035
Updated
2023/06/20
TRC
Product number
C993058
Product name
1-Cyanovinyl Acetate (stabilized with TBC)
Packaging
2.5g
Price
$220
Updated
2021/12/16
AK Scientific
Product number
4737AL
Product name
1-Acetoxy-1-cyanoethylene
Packaging
5g
Price
$430
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0013468
Product name
ACETIC ACID 1-CYANOVINYL ESTER
Purity
95.00%
Packaging
1G
Price
$640.33
Updated
2021/12/16
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1-ACETOXY-1-CYANOETHYLENE Chemical Properties,Usage,Production

Reactivity Profile

1-cyanovinyl acetate is a ketene equivalent for use in the Diels-Alder reaction; undergoes other cycloaddition reactions; reacts with nucleophiles and radicals[1].

Safety Profile

Poison by inhalation, ingestion, andskin contact. A skin irritant. Whenheated to decomposition it emits toxic fumes of NOx andCN-.

storage

Handling, Storage, and Precautions: highly toxic; use only in a fume hood. Reagent can be absorbed through the skin. Always wear gloves when handling this reagent.

References

1. Ranganathan, S.; Ranganathan, D.; Mehrotra, A. K. S 1977, 289.
2. Brown, D. S.; Paquette, L. A. JOC 1992, 57, 4512.
3. Nowak, R. M. JOC 1963, 28, 1182.

1-ACETOXY-1-CYANOETHYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-ACETOXY-1-CYANOETHYLENE Suppliers

Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
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United States
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57505
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TCI America
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--
Fax
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Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
3B Scientific Corporation
Tel
--
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Email
sales@3bsc.com
Country
United States
ProdList
6962
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Riedel-de Haen AG
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Country
United States
ProdList
6773
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87
HONEST JOY HOLDINGS LIMITED
Tel
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Fax
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Email
sales@honestjoy.cn
Country
United States
ProdList
6675
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3B Scientific Corporation
Tel
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Fax
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Email
sales@3bsc.com
Country
United States
ProdList
6718
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3061-65-2, 1-ACETOXY-1-CYANOETHYLENERelated Search:


  • 1-Cyanovinyl ester of acetic acid
  • 1-Kyanvinylester kyseliny octove
  • 1-kyanvinylesterkyselinyoctove
  • 2-(acetyloxy)-2-propenenitril
  • 2-(acetyloxy)-2-propenenitrile
  • 2-hydroxy-acrylonitrilacetate
  • 2-hydroxy-acrylonitrilacetate(ester)
  • 2-Hydroxyacrylonitrile acetate
  • 2-Acetoxyacrylonitrile 1-Acetoxy-1-cyanoethylene Acetic Acid 1-Cyanovinyl Ester
  • 2-HYDROXYACRYLONITRILE
  • 2-ACETOXYACRYLONITRILE
  • 1-CYANOVINYL ACETATE
  • 1-ACETOXY-1-CYANOETHYLENE
  • alpha-Acetoxyacrylonitrilepurum
  • α-acetoxyacrylonitrile
  • 1-Cyanovinyl Acetate (stabilized with TBC)
  • α-Acetoxyacrylonitrile, 1-Acetoxy-1-cyanoethylene, 2-Hydroxyacrylonitrile acetate
  • 2-hydroxyacrylonitrileacetate(ester)
  • 2-Propenenitrile, 2-(acetyloxy)-
  • Acrylonitrile, 2-hydroxy-, acetate
  • alpha-Cyanovinyl acetate
  • alpha-cyanovinylacetate
  • 1-cyanoethenyl acetate
  • 1-cyanoethenyl ethanoate
  • 1-Acetoxy-1-cyanoethylene, 1-Cyanovinyl acetate, 2-Hydroxyacrylonitrile acetate
  • Acetic acid 1-cyanoethenyl ester
  • ALPHA-ACETOXYACRYLONITRILE
  • ACETIC ACID 1-CYANOVINYL ESTER
  • 1-CyanovinylAcetate(stabilizedwithTBC)&gt
  • 3061-65-2
  • CH2COCOCH3CN
  • Building Blocks
  • C1 to C5
  • Nitrogen Compounds
  • Organic Building Blocks
  • Cyanides/Nitriles
  • Nitrogen Compounds
  • Organic Building Blocks
  • Building Blocks
  • C1 to C5
  • Chemical Synthesis
  • Cyanides/Nitriles