ChemicalBook > CAS DataBase List > N,N,N',N'-Tetramethyl-1,6-hexanediamine

N,N,N',N'-Tetramethyl-1,6-hexanediamine

Product Name
N,N,N',N'-Tetramethyl-1,6-hexanediamine
CAS No.
111-18-2
Chemical Name
N,N,N',N'-Tetramethyl-1,6-hexanediamine
Synonyms
TMHD;N1,N1,N6,N6-TetraMethylhexane-1,6-diaMine;TMHDA;u1000;TMHMDA;koolizer1;Ambap3162;toyocatmr;minicotmhd;u1000(amine)
CBNumber
CB8362757
Molecular Formula
C10H24N2
Formula Weight
172.31
MOL File
111-18-2.mol
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N,N,N',N'-Tetramethyl-1,6-hexanediamine Property

Melting point:
-46 °C
Boiling point:
209-210 °C(lit.)
Density 
0.806 g/mL at 25 °C(lit.)
vapor pressure 
12.4Pa at 20℃
refractive index 
n20/D 1.4359(lit.)
Flash point:
165 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
miscible
form 
Liquid
pka
10.07±0.28(Predicted)
color 
Clear colorless to yellow
Water Solubility 
miscible
LogP
1.99 at 23℃
CAS DataBase Reference
111-18-2(CAS DataBase Reference)
NIST Chemistry Reference
(CH3)2N(CH2)6N(CH3)2(111-18-2)
EPA Substance Registry System
N,N,N',N'-Tetramethyl-1,6-hexanediamine (111-18-2)
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Safety

Hazard Codes 
T
Risk Statements 
22-24-34-23/24
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3390 6.1/PG 1
WGK Germany 
1
RTECS 
MO1370000
HazardClass 
8
PackingGroup 
III
HS Code 
29212900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H330Fatal if inhaled

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
105139
Product name
N,N,N′,N′-Tetramethyl-1,6-hexanediamine
Purity
99%
Packaging
100ml
Price
$162
Updated
2024/03/01
Sigma-Aldrich
Product number
105139
Product name
N,N,N′,N′-Tetramethyl-1,6-hexanediamine
Purity
99%
Packaging
1l
Price
$855
Updated
2024/03/01
TCI Chemical
Product number
T0537
Product name
N,N,N',N'-Tetramethyl-1,6-diaminohexane
Purity
>98.0%(GC)(T)
Packaging
25mL
Price
$34
Updated
2024/03/01
TCI Chemical
Product number
T0537
Product name
N,N,N',N'-Tetramethyl-1,6-diaminohexane
Purity
>98.0%(GC)(T)
Packaging
500mL
Price
$161
Updated
2024/03/01
TRC
Product number
T302885
Product name
N,N,N'',N''-Tetramethyl-1,6-hexanediamine
Packaging
10g
Price
$155
Updated
2021/12/16
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N,N,N',N'-Tetramethyl-1,6-hexanediamine Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellow liquid

Uses

N,N,N'',N''-Tetramethyl-1,6-hexanediamine is used in the synthesis of fluorene containing poly(arylene ether sulfone) as anion exchange membranes for alkaline fuel cells.

Preparation

N,N,N',N'-Tetramethyl-1,6-hexanediamine can be made from adipodinitrile and dimethylamine or from 1,6- hexanediamine and formaldehyde.

Flammability and Explosibility

Not classified

Solubility in organics

The amine is infinitely miscible with water, methanol, acetone, ether, and benzene, but insoluble in heptane. Because of its reactivity, CCl4 cannot be used as solvent. N,N,N',N'-Tetramethyl-1,6-hexanediamine (DETA) is hygroscopic and has a strong ammoniacal odor.

N,N,N',N'-Tetramethyl-1,6-hexanediamine Preparation Products And Raw materials

Raw materials

Preparation Products

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N,N,N',N'-Tetramethyl-1,6-hexanediamine Suppliers

Apin Chemicals Limited (UK)
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United Kingdom
ProdList
6184
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60
Whyte Chemicals
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Manchester Organics
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Leancare Ltd.
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United Kingdom
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6446
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MOLEKULA Ltd.
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kevinbanks@molekula.com
Country
United Kingdom
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6140
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CARBONE SCIENTIFIC CO.,LTD
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sales@carbonesci.com
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ARIAC - Armenian Institute of Applied Chemistry
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ariac@web.am
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Apin Chemicals Ltd.
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Dow Haltermann Custom Processing
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View Lastest Price from N,N,N',N'-Tetramethyl-1,6-hexanediamine manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
N,N,N',N`-Tetramethylhexanediamine 111-18-2
Price
US $79.00-38.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-11-25
HebeiShuoshengImportandExportco.,Ltd
Product
N,N,N',N'-Tetramethyl-1,6-hexanediamine 111-18-2
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-07
Hebei Jingbo New Material Technology Co., Ltd
Product
N,N,N',N'-Tetramethyl-1,6-hexanediamine 111-18-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000000
Release date
2023-12-05

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