2-Iodobutane Property

Melting point:

-104 °C (lit.)

Boiling point:

119-120 °C (lit.)

Density 

1.598 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.499(lit.)

Flash point:

75 °F

storage temp. 

Flammables area

solubility 

alcohol: soluble(lit.)

form 

clear liquid

color 

Colorless to Red to Green

Water Solubility 

Insoluble in water. Soluble in alcohol and diethyl ether.

Sensitive 

Light Sensitive

Merck 

14,1574

BRN 

1718777

Stability:

Stable. Flammable. Incompatible with strong oxidizing agents. Light sensitive.

CAS DataBase Reference

513-48-4(CAS DataBase Reference)

NIST Chemistry Reference

Butane, 2-iodo-(513-48-4)

EPA Substance Registry System

Butane, 2-iodo- (513-48-4)

Safety

Hazard Codes 

Xi,F

Risk Statements 

10-36/37/38

Safety Statements 

26-36

RIDADR 

UN 2390 3/PG 2

WGK Germany 

3

RTECS 

EK4410000

F 

8

Hazard Note 

Irritant/Flammable/Light Sensitive

TSCA 

Yes

HazardClass 

3

PackingGroup 

II

HS Code 

29033080

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

2-Iodobutane Chemical Properties,Usage,Production

Chemical Properties

liquid

Uses

It is used as a solvent organic synthesis and as pharmaceutical intermediate.

General Description

2-iodobutane is a colorless liquid. Less dense than water. Vapors heavier than air. Used to make other chemicals and as a solvent.

Air & Water Reactions

Highly flammable. Slightly soluble in water.

Reactivity Profile

Halogenated aliphatic compounds, such as 2-Iodobutane, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Purification Methods

Purify the iodide by shaking with conc H2SO4, then washing it with water, aqueous Na2SO3 and again with water. Dry (MgSO4) and distil. Alternatively, pass it through a column of activated alumina before distillation, or treat with bromine, followed by extraction of the free halogen with aqueous Na2S2O3, thoroughly washing with water, drying and distilling. It is stored over silver powder and distilled before use. [Beilstein 1 IV 272.]