ChemicalBook > CAS DataBase List > 2-Bromobutane

2-Bromobutane

Product Name
2-Bromobutane
CAS No.
78-76-2
Chemical Name
2-Bromobutane
Synonyms
S-BUTYL BROMIDE;SEC-BUTYL BROMIDE;BROMOBUTANE, 2-(SG);1-BROMO-1-METHYLPROPANE;2-Bromobutane sec-Butylbromide;sec-C4H9Br;2-Brombutan;2-BROMOBUTANE;2-bromo-butan;bromo-2butane
CBNumber
CB9854376
Molecular Formula
C4H9Br
Formula Weight
137.02
MOL File
78-76-2.mol
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2-Bromobutane Property

Melting point:
-112 °C
Boiling point:
91 °C(lit.)
Density 
1.255 g/mL at 25 °C(lit.)
vapor pressure 
70 hPa (20 °C)
refractive index 
n20/D 1.4369(lit.)
Flash point:
70 °F
storage temp. 
Store at +2°C to +8°C.
solubility 
<1g/l
form 
Liquid
color 
Clear colorless to yellow-brown
explosive limit
2.6-6.6%(V)
Water Solubility 
insoluble
Merck 
14,1554
BRN 
505949
Dielectric constant
8.6400000000000006
Stability:
Stable. Flammable. Incompatible with strong oxidizing agents.
InChIKey
UPSXAPQYNGXVBF-UHFFFAOYSA-N
LogP
3 at 35℃ and pH7
CAS DataBase Reference
78-76-2(CAS DataBase Reference)
NIST Chemistry Reference
Butane, 2-bromo-(78-76-2)
EPA Substance Registry System
Butane, 2-bromo- (78-76-2)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38-10-52
Safety Statements 
16-23-24/25-37/39-26
RIDADR 
UN 2339 3/PG 2
WGK Germany 
2
RTECS 
EJ6228000
Autoignition Temperature
265 °C
Hazard Note 
Irritant/Highly Flammable
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29033036
Hazardous Substances Data
78-76-2(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B59500
Product name
2-Bromobutane
Purity
98%
Packaging
100g
Price
$50.3
Updated
2024/03/01
Sigma-Aldrich
Product number
B59500
Product name
2-Bromobutane
Purity
98%
Packaging
500g
Price
$128
Updated
2024/03/01
TCI Chemical
Product number
B0561
Product name
2-Bromobutane
Purity
>98.0%(GC)
Packaging
25g
Price
$17
Updated
2024/03/01
TCI Chemical
Product number
B0561
Product name
2-Bromobutane
Purity
>98.0%(GC)
Packaging
500g
Price
$82
Updated
2024/03/01
Alfa Aesar
Product number
A15069
Product name
2-Bromobutane, 98%
Packaging
250g
Price
$51.7
Updated
2024/03/01
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2-Bromobutane Chemical Properties,Usage,Production

Chemical Properties

colourless liquid with a pleasant odour

Uses

2-Bromobutane is utilized in the synthesis of non-nucleosides. It is used as a solvent as well as an intermediate in organic synthesis. It is an important raw material used to prepare Grignard reagent by reacting with magnesium. Further, it reacts with hydrocyanic acid to prepare sodium salt to get (+-)-sec-butyl cyanide. It is an important raw material used to prepare Grignard reagent by reacting with magnesium.

Uses

2-Bromobutane is used in the various organic synthesis, existing as a grignard reagent.

General Description

A colorless to pale-yellow colored liquid with a pleasant odor. Flash point 65°F. Insoluble in water and denser than water. Vapors are heavier than air and may be narcotic in high concentrations. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Halogenated aliphatic compounds, such as 2-Bromobutane , are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Gives toxic fumes of bromine when burned.

Hazard

Narcotic in high concentration. Flammable, dangerous fire risk.

Health Hazard

Irritating to eyes, nose, throat, upper respiratory tract, and skin. Symptoms of exposure include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.

Safety Profile

Narcotic in high concentrations. Questionable carcinogen with experimental neoplastigenic data. See also BROMIDES and CHLORINATED HYDROCARBONS, ALIPHATIC. Flammable liquid. Dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Br-; can react with oxidzing materials. To fight fire, use water, spray or mist, foam, Co2, dry chemical.

Purification Methods

Wash 2-bromobutane with conc HCl, water, 10% aqueous NaHSO3, and then water. Dry it with CaCl2, Na2SO4 or anhydrous K2CO3, and fractionally distil it through a 1m glass helices packed column. [Beilstein 1 IV 261.]

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2-Bromobutane Suppliers

CHANGZHOU XINYOU GOODS AND MAT
Tel
0519-88861658 15351933796
Email
601763459@qq.com
Country
China
ProdList
38
Advantage
58
Yancheng Longshen Chemical Co.,Ltd.
Tel
0515-0515-88718898 18352070236
Fax
0515-88718898
Email
wendy@longshenchem.com
Country
China
ProdList
103
Advantage
60
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1390
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
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View Lastest Price from 2-Bromobutane manufacturers

Hebei Miaoyin Technology Co.,Ltd
Product
2-Bromobutane 78-76-2
Price
US $30.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
10000
Release date
2023-04-14
Hebei Yanxi Chemical Co., Ltd.
Product
2-Bromobutane 78-76-2
Price
US $0.00/kgkg
Min. Order
1kgkg
Purity
0.99
Supply Ability
5000kg
Release date
2023-10-12
Hebei Chuanghai Biotechnology Co,.LTD
Product
2-bromobutane 78-76-2
Price
US $10.00/KG
Min. Order
1KG
Purity
99.%
Supply Ability
10 ton
Release date
2024-07-30

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