ChemicalBook > CAS DataBase List > (R)-DM-BINAP
(R)-DM-BINAP
Reaction- Product Name
- (R)-DM-BINAP
- CAS No.
- 137219-86-4
- Chemical Name
- (R)-DM-BINAP
- Synonyms
- Xylbinap;(R)-(+)-XyL;(R)-DM-BINAP;RAC-XYLYL-BINAP;(R)-Xylyl-BINAP;98% (R)-XylBINAP;(R)-(+)-XylBINAP;(R)-3,5-Xyl-BINAP;(R)-3,5-XYLYL-BINAP;2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
- CBNumber
- CB8381549
- Molecular Formula
- C52H48P2
- Formula Weight
- 734.89
- MOL File
- 137219-86-4.mol
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(R)-DM-BINAP Property
- Melting point:
- 203-206°C
- Boiling point:
- 825.3±65.0 °C(Predicted)
- alpha
- 169 º (c=1 in chloroform)
- storage temp.
- Inert atmosphere,Room Temperature
- Water Solubility
- Insoluble in water
- form
- crystal
- color
- white to pale yellow
- optical activity
- [α]20/D +169°, c = 1 in chloroform
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 692379
- Product name
- (R)-DM-BINAP
- Packaging
- 100mg
- Price
- $78.7
- Updated
- 2024/03/01
TCI Chemical
- Product number
- X0070
- Product name
- (R)-(+)-XylBINAP
- Purity
- >97.0%(HPLC)
- Packaging
- 200mg
- Price
- $60
- Updated
- 2024/03/01
TCI Chemical
- Product number
- X0070
- Product name
- (R)-(+)-XylBINAP
- Purity
- >97.0%(HPLC)
- Packaging
- 1g
- Price
- $203
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- H27680
- Product name
- (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
- Packaging
- 500mg
- Price
- $214
- Updated
- 2021/12/16
Alfa Aesar
- Product number
- H27680
- Product name
- (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
- Packaging
- 100mg
- Price
- $72.4
- Updated
- 2021/12/16
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(R)-DM-BINAP Chemical Properties,Usage,Production
Reaction
- Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
- Ligand used in the enantioselective fluorination of oxindoles.
- Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
- Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
- Asymmetric hydroboration of unsaturated imines.
Uses
(R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction.
Uses
(R)-DM-BINAP Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (R)-DM-BINAP manufacturers
Chemwill Asia Co.,Ltd.
- Product
- (R)-DM-BINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl 137219-86-4
- Price
- US $6.00/kg
- Min. Order
- 1kg
- Purity
- High quality Professional Factory
- Supply Ability
- Ms Ella chemwill_asia@126.com www.chemwill.com
- Release date
- 2019-04-04
Career Henan Chemical Co
- Product
- (R)-DM-BINAP 137219-86-4
- Price
- US $1.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 95%-99%
- Supply Ability
- 100KG
- Release date
- 2019-08-29
137219-86-4, (R)-DM-BINAPRelated Search:
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE
(R)-(+)-TolBINAP
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
RuCl2[(R)-DM-BINAP][(R,R)-DPEN]
RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN]
(R)-3,5-XYLYL-BINAP
(S)-Ru(OAc)2(DM-BINAP)
(S)-RuCl[(p-cymene)(DM-BINAP)]Cl
(R)-Ru(OAc)2(DM-BINAP)
RuCl2[(R)-DM-BINAP][(R)-DAIPEN]
RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN]
(R)-RuCl[(p-cymene)(DM-BINAP)]Cl
(R)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2],(S)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2]