Reaction
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(R)-DM-BINAP

Reaction
Product Name
(R)-DM-BINAP
CAS No.
137219-86-4
Chemical Name
(R)-DM-BINAP
Synonyms
Xylbinap;(R)-(+)-XyL;(R)-DM-BINAP;RAC-XYLYL-BINAP;(R)-Xylyl-BINAP;98% (R)-XylBINAP;(R)-(+)-XylBINAP;(R)-3,5-Xyl-BINAP;(R)-3,5-XYLYL-BINAP;2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
CBNumber
CB8381549
Molecular Formula
C52H48P2
Formula Weight
734.89
MOL File
137219-86-4.mol
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(R)-DM-BINAP Property

Melting point:
203-206°C
Boiling point:
825.3±65.0 °C(Predicted)
alpha 
169 º (c=1 in chloroform)
storage temp. 
Inert atmosphere,Room Temperature
Water Solubility 
Insoluble in water
form 
crystal
color 
white to pale yellow
optical activity
[α]20/D +169°, c = 1 in chloroform
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-37
WGK Germany 
3
TSCA 
No
HS Code 
2931.90.6000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692379
Product name
(R)-DM-BINAP
Packaging
100mg
Price
$78.7
Updated
2024/03/01
TCI Chemical
Product number
X0070
Product name
(R)-(+)-XylBINAP
Purity
>97.0%(HPLC)
Packaging
200mg
Price
$60
Updated
2024/03/01
TCI Chemical
Product number
X0070
Product name
(R)-(+)-XylBINAP
Purity
>97.0%(HPLC)
Packaging
1g
Price
$203
Updated
2024/03/01
Alfa Aesar
Product number
H27680
Product name
(R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
Packaging
500mg
Price
$214
Updated
2021/12/16
Alfa Aesar
Product number
H27680
Product name
(R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
Packaging
100mg
Price
$72.4
Updated
2021/12/16
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(R)-DM-BINAP Chemical Properties,Usage,Production

Reaction

  1. Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
  2. Ligand used in the enantioselective fluorination of oxindoles.
  3. Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
  4. Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
  5. Asymmetric hydroboration of unsaturated imines.

Uses

(R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-DM-BINAP Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-DM-BINAP Suppliers

China 102 Germany 3 India 4 Japan 2 Norway 1 Russia 1 Switzerland 1 United Kingdom 1 United States 18 Global 133
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TAKASAGO INTERNATIONAL CORPORATION
Tel
--
Fax
--
Email
finechemicals@takasago.com
Country
Japan
ProdList
203
Advantage
75
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View Lastest Price from (R)-DM-BINAP manufacturers

Chemwill Asia Co.,Ltd.
Product
(R)-DM-BINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl 137219-86-4
Price
US $6.00/kg
Min. Order
1kg
Purity
High quality Professional Factory
Supply Ability
Ms Ella chemwill_asia@126.com www.chemwill.com
Release date
2019-04-04
Career Henan Chemical Co
Product
(R)-DM-BINAP 137219-86-4
Price
US $1.00/KG
Min. Order
1KG
Purity
95%-99%
Supply Ability
100KG
Release date
2019-08-29

137219-86-4, (R)-DM-BINAPRelated Search:

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE (R)-(+)-TolBINAP (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl RuCl2[(R)-DM-BINAP][(R,R)-DPEN] RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN] (R)-3,5-XYLYL-BINAP (S)-Ru(OAc)2(DM-BINAP) (S)-RuCl[(p-cymene)(DM-BINAP)]Cl (R)-Ru(OAc)2(DM-BINAP) RuCl2[(R)-DM-BINAP][(R)-DAIPEN] RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN] (R)-RuCl[(p-cymene)(DM-BINAP)]Cl (R)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2],(S)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2]

  • (R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
  • (R)-(+)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL
  • RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
  • RAC-XYLYL-BINAP
  • (R)-3,5-XYLYL-BINAP
  • (R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-B
  • (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%(R)-3,5-xylyl-BINAP
  • (R)-(+)-2,2'-bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl
  • (R)-3,5-Xyl-BINAP
  • (R)-DM-BINAP
  • Xylbinap
  • (r)-(+)-2,2'-bis(di(3,5-xylyl)phosphino)-1,1'-binaphthy
  • PHOSPHINE, 1,1''-[(1R)-[1,1''-BINAPHTHALENE]-2,2''-DIYL]BIS[1,1-BIS(3,5-DIMETHYLPHENYL)-
  • (R)-(+)-2,2μ-Bis[di(3,5-xylyl)phosphino]-1,1μ-binaphthyl, (R)-(+)-1,1μ-Binaphthalene-2,2μ-diyl)bis[bis(3,5-dimethylphenyl)phosphine]
  • 2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
  • 2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL
  • (R)-(+)-2,2''-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1''-BINAPHTHYL (R)-3,5-XYLYL-BINAP
  • (R)-Xylyl-BINAP
  • 1,1'-[(1R)-[1,1'-binaphthalene]-2,2'-diyl]bis[1,1-bis(3,5-dimethylphenyl)-Phosphine
  • (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP
  • (R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, 98%((R)-Xylyl-BINAP)
  • 98% (R)-XylBINAP
  • (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%
  • (R)-(+)-XylBINAP
  • (R)-DM-BINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
  • (R)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,(R)-XylBINAP
  • (R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-BINAP)
  • (R)-(+)-XyL
  • (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl [(R)-DM-Binap
  • (r)-2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl
  • (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl [(R)-DM-Binap
  • 137219-86-4
  • BINAP Series
  • Chiral Phosphine