Reaction
ChemicalBook > CAS DataBase List > (R)-DM-BINAP

(R)-DM-BINAP

Reaction
Product Name
(R)-DM-BINAP
CAS No.
137219-86-4
Chemical Name
(R)-DM-BINAP
Synonyms
Xylbinap;(R)-(+)-XyL;(R)-DM-BINAP;RAC-XYLYL-BINAP;(R)-Xylyl-BINAP;98% (R)-XylBINAP;(R)-(+)-XylBINAP;(R)-3,5-Xyl-BINAP;(R)-3,5-XYLYL-BINAP;2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
CBNumber
CB8381549
Molecular Formula
C52H48P2
Formula Weight
734.89
MOL File
137219-86-4.mol
More
Less

(R)-DM-BINAP Property

Melting point:
203-206°C
Boiling point:
825.3±65.0 °C(Predicted)
alpha 
169 º (c=1 in chloroform)
storage temp. 
Inert atmosphere,Room Temperature
Water Solubility 
Insoluble in water
form 
crystal
color 
white to pale yellow
optical activity
[α]20/D +169°, c = 1 in chloroform
More
Less

Safety

Risk Statements 
36/37/38
Safety Statements 
26-37
WGK Germany 
3
TSCA 
No
HS Code 
2931.90.6000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692379
Product name
(R)-DM-BINAP
Packaging
100mg
Price
$78.7
Updated
2024/03/01
TCI Chemical
Product number
X0070
Product name
(R)-(+)-XylBINAP
Purity
>97.0%(HPLC)
Packaging
200mg
Price
$60
Updated
2024/03/01
TCI Chemical
Product number
X0070
Product name
(R)-(+)-XylBINAP
Purity
>97.0%(HPLC)
Packaging
1g
Price
$203
Updated
2024/03/01
Alfa Aesar
Product number
H27680
Product name
(R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
Packaging
500mg
Price
$214
Updated
2021/12/16
Alfa Aesar
Product number
H27680
Product name
(R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
Packaging
100mg
Price
$72.4
Updated
2021/12/16
More
Less

(R)-DM-BINAP Chemical Properties,Usage,Production

Reaction

  1. Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
  2. Ligand used in the enantioselective fluorination of oxindoles.
  3. Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
  4. Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
  5. Asymmetric hydroboration of unsaturated imines.

Uses

(R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-DM-BINAP Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(R)-DM-BINAP Suppliers

China 102 Germany 3 India 4 Japan 2 Norway 1 Russia 1 Switzerland 1 United Kingdom 1 United States 18 Global 133
TCI Chemicals (India) Pvt. Ltd.
Tel
--
Fax
--
Email
sales-in@tcichemicals.com
Country
India
ProdList
6768
Advantage
58
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
India
ProdList
6905
Advantage
58
More
Less

View Lastest Price from (R)-DM-BINAP manufacturers

Chemwill Asia Co.,Ltd.
Product
(R)-DM-BINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl 137219-86-4
Price
US $6.00/kg
Min. Order
1kg
Purity
High quality Professional Factory
Supply Ability
Ms Ella chemwill_asia@126.com www.chemwill.com
Release date
2019-04-04
Career Henan Chemical Co
Product
(R)-DM-BINAP 137219-86-4
Price
US $1.00/KG
Min. Order
1KG
Purity
95%-99%
Supply Ability
100KG
Release date
2019-08-29

137219-86-4, (R)-DM-BINAPRelated Search:

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE (R)-(+)-TolBINAP (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl RuCl2[(R)-DM-BINAP][(R,R)-DPEN] RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN] (R)-3,5-XYLYL-BINAP (S)-Ru(OAc)2(DM-BINAP) (S)-RuCl[(p-cymene)(DM-BINAP)]Cl (R)-Ru(OAc)2(DM-BINAP) RuCl2[(R)-DM-BINAP][(R)-DAIPEN] RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN] (R)-RuCl[(p-cymene)(DM-BINAP)]Cl (R)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2],(S)-[(RuCl(DM-BINAP))2(μ-Cl)3][NH2Me2]

  • (R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
  • (R)-(+)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL
  • RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
  • RAC-XYLYL-BINAP
  • (R)-3,5-XYLYL-BINAP
  • (R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-B
  • (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%(R)-3,5-xylyl-BINAP
  • (R)-(+)-2,2'-bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl
  • (R)-3,5-Xyl-BINAP
  • (R)-DM-BINAP
  • Xylbinap
  • (r)-(+)-2,2'-bis(di(3,5-xylyl)phosphino)-1,1'-binaphthy
  • PHOSPHINE, 1,1''-[(1R)-[1,1''-BINAPHTHALENE]-2,2''-DIYL]BIS[1,1-BIS(3,5-DIMETHYLPHENYL)-
  • (R)-(+)-2,2μ-Bis[di(3,5-xylyl)phosphino]-1,1μ-binaphthyl, (R)-(+)-1,1μ-Binaphthalene-2,2μ-diyl)bis[bis(3,5-dimethylphenyl)phosphine]
  • 2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
  • 2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL
  • (R)-(+)-2,2''-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1''-BINAPHTHYL (R)-3,5-XYLYL-BINAP
  • (R)-Xylyl-BINAP
  • 1,1'-[(1R)-[1,1'-binaphthalene]-2,2'-diyl]bis[1,1-bis(3,5-dimethylphenyl)-Phosphine
  • (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP
  • (R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, 98%((R)-Xylyl-BINAP)
  • 98% (R)-XylBINAP
  • (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%
  • (R)-(+)-XylBINAP
  • (R)-DM-BINAP (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
  • (R)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,(R)-XylBINAP
  • (R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-BINAP)
  • (R)-(+)-XyL
  • (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl [(R)-DM-Binap
  • (r)-2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl
  • (R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl [(R)-DM-Binap
  • 137219-86-4
  • BINAP Series
  • Chiral Phosphine