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ABS Resins

Product Name
ABS Resins
CAS No.
9003-56-9
Chemical Name
ABS Resins
Synonyms
abs;Acrylonitrile-butadiene-styrene;ACRYLONITRILE-BUTADIENE-STYRENE RESIN;acrylonitrile-butadiene-styrenecopolymers;ACRYLONITRILE-BUTADIENE-STYRENE COPOLYMER;KRYLENE;ABS rod;absresin;absresins;ABSPOLYMER
CBNumber
CB8405764
Molecular Formula
C45H51N3X2
Formula Weight
633.91
MOL File
9003-56-9.mol
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ABS Resins Property

Melting point:
58.54(±0.5)℃
Density 
1.05 g/mL at 25 °C
solubility 
acetone, MEK and DMF: soluble
form 
powder
color 
natural
SMILES
C(C/C=C/CC(C#N)CCC(C/C=C/CC(C*)C#N)C1=CC=CC=C1)(CCC(C#N)C/C=C/CC(C*)C1C=CC=CC=1)C1=CC=CC=C1 |$;;;;;;;;;;;;;;;;;*;;;;;;;;;;;;;;;;;;;;*;;;;;;;;;;;;$|
EPA Substance Registry System
Acrylonitrile 1,3-butadiene styrene polymer (9003-56-9)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38-20/21/22
Safety Statements 
26-36
RIDADR 
UN 2215 8 / PGIII
WGK Germany 
3
RTECS 
AT6970000
Hazardous Substances Data
9003-56-9(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
GF31714994
Product name
Polyacrylonitrile-Butadiene-Styrene
Purity
(ABS), rod, diam. 12.7?mm, L 300?mm, natural
Packaging
1EA
Price
$173
Updated
2024/03/01
Sigma-Aldrich
Product number
GF31714994
Product name
Polyacrylonitrile-Butadiene-Styrene
Purity
(ABS), rod, diam. 12.7?mm, L 300?mm, natural
Packaging
5EA
Price
$700
Updated
2024/03/01
Sigma-Aldrich
Product number
GF31714994
Product name
Polyacrylonitrile-Butadiene-Styrene
Purity
(ABS), rod, diam. 12.7?mm, L 300?mm, natural
Packaging
10EA
Price
$1280
Updated
2024/03/01
Sigma-Aldrich
Product number
GF30278358
Product name
Polyacrylonitrile-Butadiene-Styrene
Purity
(ABS), sheet, thickness 1.59?mm, size 150 × 150?mm, white
Packaging
1EA
Price
$154
Updated
2024/03/01
Sigma-Aldrich
Product number
GF30278358
Product name
Polyacrylonitrile-Butadiene-Styrene
Purity
(ABS), sheet, thickness 1.59?mm, size 150 × 150?mm, white
Packaging
5EA
Price
$623
Updated
2024/03/01
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ABS Resins Chemical Properties,Usage,Production

Chemical Properties

As has already been mentioned, the range of possible ABS polymers is very large since both the ratio of the three monomers and the manner in which they are assembled in the final product can be varied considerably. Thus commercial ABS polymers are available with appreciable differences in properties, but they are generally characterized by high impact strengths and softening points as high as, or higher than, straight polystyrene.
The ABS polymers prepared by grafting contain varying amounts of ungrafted polybutadiene (which has a low glass transition temperature) and therefore have good low-temperature impact strength. Also, the ABS polymers prepared by grafting are superior to those obtained by blending in that moulded specimens commonly have a better surface appearance. In recent years, special grades of ABS polymers have been produced in which a fourth monomer is present. For example, heat-resistant grades contain a-methylstyrene and transparent grades incorporate methyl methacrylate.
ABS polymers can be injection moulded and extruded and have been used in a great variety of applications which require toughness, rigidity and good appearance, e.g. automobile fascia panels and radiator grilles, household appliances, business machines, telephones and pipe and pipe fittings.

Chemical Properties

white to off-white powder

Uses

Typical Applications Include:

  • Semi-con: HDD Components; Wafer Handling; Jigs;Casings; & Connectors
  • Industiral: Converying;Metering; and Sensing applications

Production Methods

acrylonitrile-butadiene-styrene resins are commonly referred to as ABS resins. These materials are thermoplastic resins that are produced by grafting styrene and acrylonitrile onto a diene-rubber backbone. The usually preferred substrate is polybutadiene because of its low glasstransition temperature (just above ?80 °C). Where ABS resin is prepared by suspension or mass polymerization methods, stereospecific diene rubber made by solution polymerization is the preferred diene. Otherwise the diene used normally is a high-gel or cross-linked latex made by a “hot-emulsion” process.

Preparation

Two basic processes are used commercially to prepare ABS polymers, namely blending and grafting. These processes give rise to materials which are rather different to each other. Of the two processes, grafting is now the more important.
(a) Blending
The products obtained by this method are mechanical blends of styreneacrylonitrile copolymers and acrylonitrile-butadiene rubbers. The preferred method of preparation is by blending latices of the two copolymers and coagulating the mixture. A wide range of products is possible, depending on the composition of each copolymer and the relative amounts of each employed. A typical blend would consist of the following (solids):
70 parts of styrene-acrylonitrile copolymer (70: 30)
40 parts of acrylonitrile-butadiene rubber (35: 65)
It has been found that non-cross-linked acrylonitrile-butadiene rubbers are compatible with styrene-acrylonitrile copolymers and the mixtures show little improvement in impact strength and have low softening points. However, if the rubber is sufficiently cross-linked so as to be not completely soluble in the copolymer then the mixtures have high impact strengths and high softening points. A convenient method of preparing a suitably crosslinked acrylonitrile-butadiene rubber is to take an emulsion polymerization to high conversion; alternatively, a small amount of divinylbenzene can be added to the emulsion recipe. After the two latices have been mixed, coagulation is brought about by the addition of either an acid or a salt. The resulting crumb is washed, filtered, dried, extruded and chopped into granules.
An alternative method of preparing a blend of the two copolymers is by mixing the solids on a two-roll mill. In this case, a non-cross-linked acrylonitrile-butadiene rubber may be used as starting material. The rubber is firstly cross-linked by milling with a peroxide and then the styrene-acrylonitrile copolymer is added.
The physical nature of these blends does not appear to be the same as that of rubber-modified polystyrenes. When this type of ABS polymer is treated with a solvent such as methyl ethyl ketone the sample swells and only partially breaks up; this indicates that rubber networks permeate the styreneacrylonitrile copolymer matrix. When rubber-modified polystyrenes are treated with a solvent such as toluene, complete disintegration into fine particles occurs.
(b) Grafting
In this method of preparing ABS polymers, acrylonitrile and styrene are polymerized in the presence of a polybutadiene latex. A wide range of products is possible, depending on the relative quantities of reactants.
The reaction is carried out at about 50°C. The solid product is then isolated from the latex.
ABS polymers prepared in this way consist of a continuous matrix of styrene-acrylonitrile copolymer, dispersed particles of polybutadiene and a boundary layer of poly butadiene grafted with acrylonitrile and styrene.

General Description

3DXTech? ABS is made in the USA using 100% virgin resin and colorants - precision extruded onto 1kg reels (2.2 lbs.). The filament is then vacuum-sealed with desiccant to protect it from moisture.

Advantages

ABS Resins is a strong and durable polymer. It is a chemically resistant resin. It gets easily attacked by polar solvents. It offers greater impact properties and slightly higher heat distortion temperature than HIPS.
It has a low melting temperature making it suitable for processing by 3D printing on an FDM machine.
ABS shows excellent mechanical properties. It is hard and tough in nature and thus delivers good impact strength. It offers a high degree of surface quality. Apart from these characteristics, Acrylonitrile Butadiene Styrene exhibits good electrical insulating properties.
It is an ideal material of choice for various structural applications. This is because of its several physical properties such as:
High rigidity, good weldability, and insulating properties; Good impact resistance, even at low temperatures; Good abrasion and strain resistance; High dimensional stability (Mechanically strong and stable over time); High surface brightness and excellent surface aspect

ABS Resins Preparation Products And Raw materials

Raw materials

Preparation Products

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ABS Resins Suppliers

BOC Sciences
Tel
1-631-485-4226; 16314854226
Email
info@bocsci.com
Country
United States
ProdList
14059
Advantage
65
Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939 15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
15873
Advantage
55
Hubei Jusheng Technology Co.,Ltd
Tel
027-59599241 18871490274
Fax
027-59599241
Email
1400878000@qq.com
Country
China
ProdList
9972
Advantage
58
Chizhou Kailong Import and Export Trade Co., Ltd.
Tel
Fax
-
Email
xg01_gj@163.com
Country
China
ProdList
9503
Advantage
50
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51471
Advantage
80
Nanjing Vital Chemical Co., Ltd.
Tel
025-87193546 18652950785
Fax
025-87193546
Email
chemweiao@163.com
Country
China
ProdList
9030
Advantage
60
Shanghai Orgchem Co.,Ltd.
Tel
+86-21-5877 1921
Fax
+86-21-5877 1925
Email
info@chemofchina.com
Country
China
ProdList
9661
Advantage
55
JinJin Le Chemical Co., Ltd
Tel
10106090
Email
jjlchem2@163.com
Country
China
ProdList
9986
Advantage
58
Shanghai Shuai Sun Industrial Co., Ltd.
Tel
021-37590756 57450129
Fax
021-57450128
Country
China
ProdList
4287
Advantage
58
Henan Alfachem Co.,Ltd.
Tel
0371-0371-55051623 18137891487
Fax
QQ:2853979817
Email
2853979817@qq.com
Country
China
ProdList
9954
Advantage
58
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View Lastest Price from ABS Resins manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
ABS Resins 9003-56-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2020-04-26
Career Henan Chemical Co
Product
ABS Resins 9003-56-9
Price
US $9.80/KG
Min. Order
1KG
Purity
≥98%
Supply Ability
20 tons
Release date
2020-01-09

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