ChemicalBook > CAS DataBase List > 4-Bromo-2-(trifluoromethoxy)aniline

4-Bromo-2-(trifluoromethoxy)aniline

Product Name
4-Bromo-2-(trifluoromethoxy)aniline
CAS No.
175278-09-8
Chemical Name
4-Bromo-2-(trifluoromethoxy)aniline
Synonyms
4-BROMO-2-(TRIFLUOROMETHOXY)ANILINE;4-Bromo-2-trifluoromethoxy-phenylamine;BUTTPARK 50\01-74;TIMTEC-BB SBB005835;4-Bromo-2-Trifluoromethox;4-bromo-2-(trifluoromrthoxy)aniline;4-Bromo-2-(trifluoeomethoxy)aniline;4-Bromo-2-trifluoromethoxyaniline,97%;4-Bromo-2-(trifluoromethoxy)aniline98%;4-Bromo-2-(trifluoromethoxy)aniline 98%
CBNumber
CB8419851
Molecular Formula
C7H5BrF3NO
Formula Weight
256.02
MOL File
175278-09-8.mol
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4-Bromo-2-(trifluoromethoxy)aniline Property

Boiling point:
98-100 °C/15 mmHg (lit.)
Density 
1.691 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.5130(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
1.75±0.10(Predicted)
CAS DataBase Reference
175278-09-8(CAS DataBase Reference)
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Safety

Hazard Codes 
T,Xi
Risk Statements 
25-43-52/53-36/37/38
Safety Statements 
36/37-45-37/39-26
RIDADR 
UN 2810 6.1/PG 3
WGK Germany 
2
Hazard Note 
Toxic
HazardClass 
IRRITANT
HazardClass 
6.1
PackingGroup 
HS Code 
29222990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H317May cause an allergic skin reaction

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
631256
Product name
4-Bromo-2-(trifluoromethoxy)aniline
Purity
97%
Packaging
5g
Price
$53.8
Updated
2022/05/15
Sigma-Aldrich
Product number
631256
Product name
4-Bromo-2-(trifluoromethoxy)aniline
Purity
97%
Packaging
25g
Price
$233
Updated
2022/05/15
TCI Chemical
Product number
B3786
Product name
4-Bromo-2-(trifluoromethoxy)aniline
Purity
>98.0%(GC)
Packaging
5g
Price
$24
Updated
2024/03/01
TCI Chemical
Product number
B3786
Product name
4-Bromo-2-(trifluoromethoxy)aniline
Purity
>98.0%(GC)
Packaging
25g
Price
$63
Updated
2024/03/01
Alfa Aesar
Product number
B20885
Product name
4-Bromo-2-(trifluoromethoxy)aniline, 97%
Packaging
10g
Price
$134
Updated
2021/12/16
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4-Bromo-2-(trifluoromethoxy)aniline Chemical Properties,Usage,Production

Chemical Properties

clear pale yellow to orange-yellow liquid

Uses

4-Bromo-2-(trifluoromethoxy)aniline is a versatile building block that can be used to create a range of compounds, such as methyl 4- amino-3-(trifluoromethoxy)benzoate, 1-Bromo-3-(trifluoromethoxy)benzene, etc.
To a solution of 4-bromo-2-(trifluoromethoxy)aniline (10 g, 50.21 mmol) in methanol (150 mL) in a pressure tank reactor was added TEA (11.84 g, 117.01 mmol), Pd(dppf)Ci2 CH2Q2 (2.4 g, 2.94 mmol). Then the reactor was charged with CO (g) (20 atm). The resulting reaction was stirred for 1.5 days at 100°C. Then it was diluted with water (200 mL), extracted with ethyl acetate (3 x 100 mL) and the organic layers combined and dried in an oven under reduced pressure. The resulting mixture was concentrated in a vacuo. The residue was purified by silica gel column chromatography with ethyl acetate/petroleum ether (1:50) to afford methyl 4- amino-3-(trifluoromethoxy)benzoate as yellow solid (5 g, 54 %).

4-Bromo-2-(trifluoromethoxy)aniline Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromo-2-(trifluoromethoxy)aniline Suppliers

Acros Organics
Tel
--
Fax
--
Email
info@acros.com
Country
Belgium
ProdList
6772
Advantage
81
Maybridge Chemical Co., Ltd.
Tel
--
Fax
--
Country
Belgium
ProdList
6293
Advantage
73
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View Lastest Price from 4-Bromo-2-(trifluoromethoxy)aniline manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
4-Bromo-2-trifluoromethoxyaniline 175278-09-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-Bromo-2-trifluoromethoxyaniline 175278-09-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09
Career Henan Chemical Co
Product
4-Bromo-2-trifluoromethoxyaniline 175278-09-8
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2020-01-07

175278-09-8, 4-Bromo-2-(trifluoromethoxy)anilineRelated Search:


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  • 4-BROMO-2-(TRIFLUOROMETHOXY)ANILINE
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  • 2-Amino-5-bromo-alpha,alpha,alpha-trifluoroanisole, 2-Amino-5-bromophenyl trifluoromethyl ether
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  • 4-Bromo-2-trifluoromethoxyaniline ISO 9001:2015 REACH
  • 175278-09-8
  • C7H5BrF4O
  • C7H5BrF3NO
  • C7
  • Building Blocks
  • Amines
  • Organic Building Blocks
  • Nitrogen Compounds
  • ARYL AMINE
  • Fluorine series
  • Nitrogen Compounds
  • Organic Building Blocks
  • Building Blocks
  • Chemical Synthesis
  • Amines
  • C7
  • Nitrogen Compounds
  • Anilines, Aromatic Amines and Nitro Compounds
  • Trifluoroanisole series