Reaction
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Bis(triphenylphosphine)nickel(II)chloride

Reaction
Product Name
Bis(triphenylphosphine)nickel(II)chloride
CAS No.
14264-16-5
Chemical Name
Bis(triphenylphosphine)nickel(II)chloride
Synonyms
NiCl2(PPh3)2;Bis(triphenylphosphine)nickel dichloride;BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE;DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II);BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE;NSC 137147;(II) dichL;(PPh3)2NiCl2;phosphine)nickeL;Bis(triphenylphosphine)nick
CBNumber
CB8433158
Molecular Formula
C36H30Cl2NiP2
Formula Weight
654.17
MOL File
14264-16-5.mol
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Bis(triphenylphosphine)nickel(II)chloride Property

Melting point:
250 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Crystals or Powder
color 
Dark green to dark gray
Water Solubility 
insoluble
Sensitive 
Hygroscopic
Exposure limits
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference
14264-16-5(CAS DataBase Reference)
NIST Chemistry Reference
dichlorobis(triphenylphosphine)nickel(14264-16-5)
EPA Substance Registry System
Nickel, dichlorobis(triphenylphosphine)- (14264-16-5)
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Safety

Hazard Codes 
T
Risk Statements 
45-43-52/53-34-20/21/22
Safety Statements 
53-36/37-45-60-36/37/39-26
RIDADR 
3260
WGK Germany 
3
RTECS 
QR6170000
F 
21
TSCA 
Yes
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29310095
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H350May cause cancer

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
237116
Product name
Bis(triphenylphosphine)nickel(II) dichloride
Purity
synthesis grade
Packaging
10g
Price
$56.8
Updated
2024/03/01
Sigma-Aldrich
Product number
237116
Product name
Bis(triphenylphosphine)nickel(II) dichloride
Purity
synthesis grade
Packaging
50g
Price
$106.8
Updated
2024/03/01
TCI Chemical
Product number
B1571
Product name
Bis(triphenylphosphine)nickel(II) Dichloride
Purity
>96.0%(T)
Packaging
10g
Price
$43
Updated
2024/03/01
TCI Chemical
Product number
B1571
Product name
Bis(triphenylphosphine)nickel(II) Dichloride
Purity
>96.0%(T)
Packaging
100g
Price
$200
Updated
2024/03/01
Alfa Aesar
Product number
013930
Product name
Dichlorobis(triphenylphosphine)nickel(II), 98%
Packaging
10g
Price
$43.65
Updated
2024/03/01
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Bis(triphenylphosphine)nickel(II)chloride Chemical Properties,Usage,Production

Reaction

  1. Catalyst for hydrosilylation of styrene with diphenysilane
  2. Catalyst for carboxylation of various aryl chlorides and other derivatives
  3. Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
  4. Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
  5. Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.

Chemical Properties

dark green to dark grey crystals or powder

Uses

Coordination compund.

Uses

suzuki reaction

Uses

Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.

Purification Methods

Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]

Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials

Raw materials

Nickel(II) chloride hexahydrate Ethanol Dichloromethane Triphenylphosphine

Preparation Products

6,6'-Dimethyl-2,2'-dipyridyl 3-PHENYLPIPERIDINE
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View Lastest Price from Bis(triphenylphosphine)nickel(II)chloride manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2021-10-15
Hebei Mojin Biotechnology Co., Ltd
Product
Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-23
Shanghai Yunao International Trade Co., Ltd
Product
Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
Price
US $200.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500t
Release date
2021-09-29

14264-16-5, Bis(triphenylphosphine)nickel(II)chlorideRelated Search:

Potassium chloride Nickel(II) chloride hexahydrate Ammonium chloride Calcium chloride Triphenylphosphine Bis(triphenylphosphine)palladium(II) chloride Polyvinyl chloride Nickel oxide Tris(triphenylphosphine)rhodiu Choline chloride Nickel chloride Sodium chloride Thionyl chloride (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Bis-(triphenylphosphino)-cuprous borohydride BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE Bis(tricyclohexylphosphine)nickel(II) chloride, 99%

  • Dichlorobis(triphenyIphosphine)-nickel
  • tributyl-phosphin compd. with nickelchloride
  • Nickel(II) chloride bis(triphenylphosphine)
  • Bis(triphenylphosphine)nick
  • Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride
  • Phosphine, tributyl-, compound with nickel chloride (2:1)
  • Dichlorobis(triphenylphosphine)nickel(Ⅱ)
  • Dichlorobis(triphenylphosphine)nickel(II), 98+%
  • Dichlorobis(triphehylphosphine)nickel(II) ,98%
  • Bis(triphenylphosphine)nickel(II)chloride, 98% 10GR
  • Bis(triphenylphosphine)nickel(II) chloride,98% (PPh3)2NiCl2
  • NSC 137147
  • BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORI
  • Bis (triphenylphosphine) nickel chloride
  • NiCl2(PPh3)2
  • Bis(triphenylphosphine)nickel(II) dichloride 99.99% trace metals basis
  • Bis(triphenylphosphine)nickel(II) dichloride synthesis grade
  • Bis(triphenylphosphine)nickel(II)chloride,(PPh3)2NiCl2
  • NICKEL(II)-BIS(TRIPHENYLPHOSPHINE) DICHLORIDE
  • NICKEL BIS(TRIPHENYLPHOSPHINE)DICHLORIDE
  • DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL
  • DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II)
  • BIS(TRIPHENYLPHOSPHINO)NICKEL(II) CHLORIDE
  • BIS(TRIPHENYLPHOSPHINE)NICKEL(2) DICHLORIDE
  • BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE
  • BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE
  • Bis(tri-N-butylphosphine)dichloronickel
  • bis(triphenylphosphine)dichloro-nicke
  • Bis(triphenylphosphine)dichloronickel
  • Bis(triphenylphosphine)nickel dichloride
  • Dichlorobis(triphenyIphosphine)-nickel(II)
  • dichlorobis(triphenylphosphine)-nicke
  • Nickel, bis(triphenylphosphine)dichloro-
  • Nickel, dichlorobis(triphenylphosphine)-
  • Phosphine, tributyl-, compd. with nickelchloride (2:1)
  • bis(triphenylphosphine)nickle(II)
  • Bis-(triphenylphosphino)-nickel chloride
  • tributyl-phosphincompd.withnickelchloride(2:1)
  • Bis(triphenylphosphine)nickel(II) chloride for synthesis
  • TRIPHENYLPHOSPHINE NICKEL (II) CHLORIDE
  • Bis(triphenylphosphine)nickel(II) chloride, 98+%
  • Bis(triphenylphosphine)dichloronickel(II)~Dichlorobis(triphenylphosphine)nickel(II)
  • Bis(triphenylphosphine)nickel(II)chloride,99%
  • Dichloro bis (Triphenyl phosphine) Nickel catalyst
  • Bis(triphenylphosphine)nickel(II)chloride,NiCl2(PPh3)2
  • Dichlorobis(triphenylphosphine)nickel(II), 98%, for synthesis
  • Bis(triphenylphosphine)nickel(II) Dichloride &gt
  • (II) dichL
  • phosphine)nickeL
  • Bis(triphenylphosphine)nickel(II)chloride ISO 9001：2015 REACH
  • Bis(triphenylphosphin)nickel(II)chlorid
  • dichloronickel triphenylphosphane
  • is(triphenylphosphine)nickel(II)chloride
  • (PPh3)2NiCl2
  • NICKEL(2+) ION BIS(TRIPHENYLPHOSPHINE) DICHLORIDE
  • Bis(Triphenylphosphoranyl)nickel(iv) chloride
  • 14264-16-5
  • 14262-16-5