2,4-DIHYDROXYBENZONITRILE
- Product Name
- 2,4-DIHYDROXYBENZONITRILE
- CAS No.
- 64419-24-5
- Chemical Name
- 2,4-DIHYDROXYBENZONITRILE
- Synonyms
- 2,4-DIHYDROXYBENZONI;2,4-DIHYDROXYBENZONITRILE;Benzonitrile, 2,4-dihydroxy-
- CBNumber
- CB8493929
- Molecular Formula
- C7H5NO2
- Formula Weight
- 135.12
- MOL File
- 64419-24-5.mol
2,4-DIHYDROXYBENZONITRILE Property
- Melting point:
- 179 °C
- Boiling point:
- 339.4±12.0 °C(Predicted)
- Density
- 1.42±0.1 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- powder
- pka
- 6.95±0.10(Predicted)
- color
- Yellow
- InChI
- InChI=1S/C7H5NO2/c8-4-5-1-2-6(9)3-7(5)10/h1-3,9-10H
- InChIKey
- JFZAJWBGISKERI-UHFFFAOYSA-N
- SMILES
- C(#N)C1=CC=C(O)C=C1O
Safety
- HS Code
- 2926907090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- B427055
- Product name
- 2,4-dihydroxybenzonitrile
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- W7608
- Product name
- 2,4-Dihydroxybenzonitrile
- Packaging
- 250mg
- Price
- $70
- Updated
- 2021/12/16
- Product number
- FD59586
- Product name
- 2,4-Dihydroxybenzonitrile
- Packaging
- 2g
- Price
- $100
- Updated
- 2021/12/16
- Product number
- W7608
- Product name
- 2,4-Dihydroxybenzonitrile
- Packaging
- 1g
- Price
- $122
- Updated
- 2021/12/16
- Product number
- 119710
- Product name
- 2,4-Dihydroxybenzonitrile
- Purity
- 95+%
- Packaging
- 1g
- Price
- $144
- Updated
- 2021/12/16
2,4-DIHYDROXYBENZONITRILE Chemical Properties,Usage,Production
Chemical Properties
White to light yellow solid
Synthesis
5399-68-8
64419-24-5
The general procedure for the synthesis of 2,4-dihydroxybenzonitrile from 2,4-dihydroxybenzaldehyde oxime was as follows: n-C4F9SO2F (20.0 mmol, 2.0 eq.) was slowly added dropwise using a syringe to a solution of n-C4F9SO2F (20.0 mmol, 2.0 eq.) containing substrate 2,4-dihydroxybenzaldehyde oxime (10.0 mmol) and 1,8-diazabicyclo[5.4.0]undec-7-ene ( DBU, 50.0 mmol, 5.0 equiv) in a solution of dichloromethane (CH2Cl2, 20 mL). The reaction mixture was stirred at the same temperature for 10 min. Subsequently, the volatile components were removed by distillation under reduced pressure to obtain the crude product. The crude product was purified by silica gel column chromatography with the eluent being a solvent mixture of petroleum ether and ethyl acetate, resulting in the target product 2,4-dihydroxybenzonitrile in 95% yield.
References
[1] Synthetic Communications, 2013, vol. 43, # 13, p. 1778 - 1786
[2] Chinese Chemical Letters, 2016, vol. 27, # 1, p. 96 - 98
[3] Journal of the American Chemical Society, 1995, vol. 117, # 32, p. 8312 - 8321
[4] Soft Matter, 2011, vol. 7, # 18, p. 8266 - 8280
[5] Advanced Functional Materials, 2014, vol. 24, # 12, p. 1703 - 1717
2,4-DIHYDROXYBENZONITRILE Preparation Products And Raw materials
Raw materials
Preparation Products
2,4-DIHYDROXYBENZONITRILE Suppliers
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View Lastest Price from 2,4-DIHYDROXYBENZONITRILE manufacturers
- Product
- 2,4-DIHYDROXYBENZONITRILE 64419-24-5
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10
- Product
- 2,4-DIHYDROXYBENZONITRILE 64419-24-5
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09
- Product
- 2,4-DIHYDROXYBENZONITRILE 64419-24-5
- Price
- US $6.60/KG
- Min. Order
- 1KG
- Purity
- 97%-99%
- Supply Ability
- 1kg-1000kg
- Release date
- 2019-12-25