4-(CHLOROMETHYL)BENZYL ALCOHOL 99

Product Name: 4-(CHLOROMETHYL)BENZYL ALCOHOL 99
CAS No.: 16473-35-1
Chemical Name: 4-(CHLOROMETHYL)BENZYL ALCOHOL 99
Synonyms: 1-(Chloromethyl)-4-(hydroxymethyl)benzene;Pulesafu impurity 13;Plerixafor Impurity 44;p-hydroxymethylbenzyl chloride;4-(hydroxymethyl)benzyl chloride;BenzeneMethanol, 4-(chloroMethyl)-;4-(CHLOROMETHYL)BENZYL ALCOHOL 99;4-(ChloroMethyl)benzyl alcohol 99%;4-(ChloroMethyl)benzyl alcohol;Benzenemethanol, 4-(chloromethyl)- (9CI, ACI)
CBNumber: CB8504524
Molecular Formula: C8H9ClO
Formula Weight: 156.61
MOL File: 16473-35-1.mol

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4-(CHLOROMETHYL)BENZYL ALCOHOL 99 Property

Melting point:: 58-60 °C (lit.)
Boiling point:: 276℃
Density: 1.195
Flash point:: 123℃
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: wooly solid
pka: 14.27±0.10(Predicted)
color: White
InChI: InChI=1S/C8H9ClO/c9-5-7-1-3-8(6-10)4-2-7/h1-4,10H,5-6H2
InChIKey: OGALXJIOJZXBBP-UHFFFAOYSA-N
SMILES: C1(CO)=CC=C(CCl)C=C1

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 1759 8/PG 2
WGK Germany: 3
HS Code: 2906290090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 526126
Product name: 4-(Chloromethyl)benzyl alcohol
Purity: 99%
Packaging: 1g
Price: $36.5
Updated: 2025/07/31

Sigma-Aldrich

Product number: 526126
Product name: 4-(Chloromethyl)benzyl alcohol
Purity: 99%
Packaging: 5g
Price: $106
Updated: 2025/07/31

TCI Chemical

Product number: C1877
Product name: [4-(Chloromethyl)phenyl]methanol
Purity: min. 98.0 %
Packaging: 5G
Price: $87
Updated: 2025/07/31

TCI Chemical

Product number: C1877
Product name: [4-(Chloromethyl)phenyl]methanol
Purity: min. 98.0 %
Packaging: 25G
Price: $261
Updated: 2025/07/31

TRC

Product number: C588013
Product name: (4-(Chloromethyl)phenyl)methanol
Packaging: 50mg
Price: $45
Updated: 2021/12/16

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4-(CHLOROMETHYL)BENZYL ALCOHOL 99 Chemical Properties,Usage,Production

Uses

4-(Chloromethyl)benzyl alcohol may be used in the synthesis of 4-(chloromethyl)benzyl acetate.

General Description

4-(Chloromethyl)benzyl alcohol can be synthesized from 4-(chloromethyl)benzoyl chloride.

Synthesis

1642-81-5

16473-35-1

Example 1: (1) Synthesis of [4-(chloromethyl)benzyl]alcohol: To a solution of tetrahydrofuran containing 4-(chloromethyl)benzoic acid (60 mL THF), 1M borane-THF solution (90 mL) was slowly added. The reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, methanol (50 mL) was added to quench the reaction. Subsequently, the solvent was removed by rotary evaporator and the obtained residue was purified by silica gel column chromatography (eluent: hexane/ethyl acetate = 4/1 to 3/1) to afford 4-(chloromethyl)benzyl alcohol (8.84 g, 96% yield) as a colorless solid.

References

[1] Patent: WO2003/106403, 2003, A1. Location in patent: Page 23
[2] Patent: US5387709, 1995, A
[3] Patent: WO2015/51045, 2015, A2. Location in patent: Page/Page column 161-162
[4] Patent: US2016/215288, 2016, A1. Location in patent: Paragraph 0602; 0611
[5] Bioorganic and Medicinal Chemistry Letters, 2007, vol. 17, # 16, p. 4481 - 4486

4-(CHLOROMETHYL)BENZYL ALCOHOL 99 Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(CHLOROMETHYL)BENZYL ALCOHOL 99 Suppliers

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View Lastest Price from 4-(CHLOROMETHYL)BENZYL ALCOHOL 99 manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: (4-Chloromethyl-phenyl)-methanol 16473-35-1
Price: US $3.00-9.00/KG
Min. Order: 0.1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2025-06-19

Hebei Fengqiang Trading Co., LTD

Product: 4-(CHLOROMETHYL)BENZYL ALCOHOL 99 16473-35-1
Price: US $100.00/bag
Min. Order: 1bag
Purity: 99
Supply Ability: 5000
Release date: 2023-09-15

Career Henan Chemical Co

Product: 4-(CHLOROMETHYL)BENZYL ALCOHOL 99 16473-35-1
Price: US $1.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1000KG
Release date: 2018-12-16

16473-35-1, 4-(CHLOROMETHYL)BENZYL ALCOHOL 99Related Search:

1,2-Bis(chloromethyl)benzene 4-Methylbenzyl chloride P-XYLENE 4-CHLOROMETHYLBENZALDEHYDE; >95%DISCONTINUED 10/25/01 1,4-Benzenedimethanol 1,3-Bis(chloromethyl)benzene 1,2-BIS(TOSYLOXY)ETHANE Ethyl 4-chloromethylbenzoate 4-(Chloromethyl)benzoic acid Methyl 4-(chloromethyl)benzoate Methyl 4-chlorocarbonylbenzoate 4-Chloroformylphthalic anhydride 5-CHLOROMETHYLFLUORESCEIN DIACETATE 4-(CHLOROMETHYL)BENZYL ALCOHOL 99 2,4-DIFLUOROPHENYL 4-(CHLOROMETHYL)BENZOATE CHEMBRDG-BB 5401661 5-(AND-6)-CHLOROMETHYL-2',7'-DICHLORODIHYDROFLUORESCEIN DIACETATE 5-(CHLOROMETHYL)MECONIN

4-(CHLOROMETHYL)BENZYL ALCOHOL 99

BenzeneMethanol, 4-(chloroMethyl)-

1-(Chloromethyl)-4-(hydroxymethyl)benzene

4-<WBR>(ChloroMethyl)<WBR>benzyl alcohol

4-(ChloroMethyl)benzyl alcohol 99%

p-hydroxymethylbenzyl chloride

4-(hydroxymethyl)benzyl chloride

Plerixafor Impurity 44

Benzenemethanol, 4-(chloromethyl)- (9CI, ACI)

Pulesafu impurity 13

16473-35-1

ClCH2C6H4CH2OH

Alcohols

C7 to C8

Oxygen Compounds

16473-35-1