[1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide
- Product Name
- [1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide
- CAS No.
- 30018-16-7
- Chemical Name
- [1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide
- Synonyms
- SKL720;CEETPPB;1-(Ethoxycarbonyl)ethyl;Sacubitril Impurity 110;1-(Ethoxycarbonyl)ethyltriphen;CARBOETHOXYETHYL TRIPHENYLPHOSPHONIUM BROMIDE;Ethoxyformyl ethyl triphenylphosphine bromide;carbethoxy Ethyl Triphenyl Phosphonium Bromide;1-CARBETHOXYETHYL TRIPHENYLPHOSPHONIUM BROMIDE;Ethoxycarbonylethyltriphenylphosphoniumbromide
- CBNumber
- CB8678320
- Molecular Formula
- C23H24BrO2P
- Formula Weight
- 443.32
- MOL File
- 30018-16-7.mol
[1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide Property
- Melting point:
- 152 °C
- storage temp.
- Refrigerator (+4°C)
- solubility
- Chloroform, Methanol
- form
- Solid
- color
- Pale Yellow
- Water Solubility
- soluble
- Sensitive
- Hygroscopic
- BRN
- 3822244
- InChI
- InChI=1S/C23H24O2P.BrH/c1-3-25-23(24)19(2)26(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-19H,3H2,1-2H3;1H/q+1;/p-1
- InChIKey
- RSYXORMKBUFAMS-UHFFFAOYSA-M
- SMILES
- [P+](C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)C(C)C(=O)OCC.[Br-]
- CAS DataBase Reference
- 30018-16-7(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-29-22
- Safety Statements
- 26-36-8-37/39
- Hazard Note
- Irritant/Hygroscopic
- HS Code
- 29310099
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- S702536
- Product name
- (1-(ETHOXYCARBONYL)ETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
- Purity
- AldrichCPR
- Packaging
- 50MG
- Price
- $185
- Updated
- 2025/07/31
- Product number
- E1300
- Product name
- (1-Ethoxy-1-oxopropan-2-yl)triphenylphosphonium Bromide
- Packaging
- 5G
- Price
- $35
- Updated
- 2025/07/31
- Product number
- E1300
- Product name
- (1-Ethoxy-1-oxopropan-2-yl)triphenylphosphonium Bromide
- Packaging
- 25G
- Price
- $110
- Updated
- 2025/07/31
- Product number
- E890630
- Product name
- (1-(ETHOXYCARBONYL)ETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
- Packaging
- 2.5g
- Price
- $85
- Updated
- 2021/12/16
- Product number
- AK-86007
- Product name
- (1-Ethoxy-1-oxopropan-2-yl)triphenylphosphonium Bromide
- Purity
- 97%
- Packaging
- 5g
- Price
- $8
- Updated
- 2021/12/16
[1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide Chemical Properties,Usage,Production
Chemical Properties
White to off-white powder
Uses
suzuki reaction
Uses
1-Ethoxycarbonylethyl)triphenylphosphonium bromide is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. It is widely used as an organophosphine catalyst.
Synthesis
603-35-0
535-11-5
30018-16-7
1.0 g of triphenylphosphine was dissolved in 15 mL of ethyl acetate and 0.55 mL of ethyl 2-bromopropionate was added to this solution. The reaction mixture was stirred at room temperature for 24 hours. Upon completion of the reaction, the bulk of the resulting white solid product was collected by diafiltration. The solids were washed with ethyl acetate to give a final 1.35 g of white solid product ethoxycarbonyl ethyltriphenylphosphonium bromide in 80.5% yield.
References
[1] European Journal of Organic Chemistry, 2016, vol. 2016, # 12, p. 2110 - 2114
[2] Chemistry - A European Journal, 2015, vol. 21, # 20, p. 7408 - 7412
[3] Tetrahedron, 2010, vol. 66, # 26, p. 4745 - 4759
[4] Journal of Organic Chemistry, 1984, vol. 49, # 22, p. 4293 - 4295
[5] Patent: CN103864753, 2016, B. Location in patent: Paragraph 0087; 0110-0111
[1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide Preparation Products And Raw materials
Raw materials
Preparation Products
[1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide Suppliers
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View Lastest Price from [1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide manufacturers
- Product
- [1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide 30018-16-7
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-01-29
- Product
- [1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide 30018-16-7
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-10
- Product
- (1-ethoxy-1-oxopropan-2-yl)-triphenylphosphanium,bromide 30018-16-7
- Price
- US $5.00-0.50/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-13