DIETHYLSILANE
Description Sources- Product Name
- DIETHYLSILANE
- CAS No.
- 542-91-6
- Chemical Name
- DIETHYLSILANE
- Synonyms
- (C2H5)2SiH2;3-Silapentane;diethyl-silan;DIETHYLSILANE;diethylsilicon;Silane, diethyl-;Diethylsilane,97%;Diethylsilane,98+%;Diethylsilanealso high purity;Diethylsilane,highpuritymin99%
- CBNumber
- CB8680635
- Molecular Formula
- C4H12Si
- Formula Weight
- 88.22
- MOL File
- 542-91-6.mol
DIETHYLSILANE Property
- Melting point:
- -132°C
- Boiling point:
- 56 °C (lit.)
- Density
- 0.681 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.391(lit.)
- Flash point:
- −20 °F
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Miscible with terahydrofuran, diethyl ether, 1,4-dioxane and benzene.
- form
- liquid
- Specific Gravity
- 0.683
- Hydrolytic Sensitivity
- 3: reacts with aqueous base
- Sensitive
- Air Sensitive
- Merck
- 14,3128
- BRN
- 1730902
- CAS DataBase Reference
- 542-91-6(CAS DataBase Reference)
- EPA Substance Registry System
- Silane, diethyl- (542-91-6)
Safety
- Hazard Codes
- F
- Risk Statements
- 11
- Safety Statements
- 16-23-24/25
- RIDADR
- UN 1993 3/PG 2
- WGK Germany
- 1
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- II
N-Bromosuccinimide Price
- Product number
- 423815
- Product name
- Diethylsilane
- Purity
- 99%
- Packaging
- 5ml
- Price
- $80.6
- Updated
- 2024/03/01
- Product number
- 423815
- Product name
- Diethylsilane
- Purity
- 99%
- Packaging
- 25ml
- Price
- $308
- Updated
- 2024/03/01
- Product number
- L16468
- Product name
- Diethylsilane, 97+%
- Packaging
- 5g
- Price
- $60.3
- Updated
- 2024/03/01
- Product number
- L16468
- Product name
- Diethylsilane, 97+%
- Packaging
- 25g
- Price
- $190
- Updated
- 2024/03/01
- Product number
- FD61147
- Product name
- Diethylsilane
- Packaging
- 10g
- Price
- $240
- Updated
- 2021/12/16
DIETHYLSILANE Chemical Properties,Usage,Production
Description
Diethylsilane is a reagent used in the chemical vapor deposition of SiO2 for microelectronics. It is also used as a precursor to prepare (3-allylsulfanyl-propyl)-diethyl-silane by using (Ph3P)3RhCl as reagent. It can also be used as a reductant in catalytic reduction of secondary amides to imines and secondary amines has been achieved using readily available iridium catalysts such as [Ir(COE)2Cl]2. This system requires low catalyst loading and shows high efficiency and an appreciable level of functional group tolerance. As a reduction agent, it also be used to convert polycarboxylic acids into their corresponding alkanes.
Sources
Levy, R. A., J. M. Grow, and G. S. Chakravarthy. "Low-pressure chemical vapor deposition of silicon dioxide using diethylsilane." Cheminform 24.28(1993):851-854.
https://www.alfa.com/en/catalog/L16468/
https://www.sigmaaldrich.com/catalog/product/aldrich/423815?lang=en®ion=US
https://pubs.acs.org/doi/full/10.1021/ja304547s#citing
Nimmagadda, Rama D., and C. Mcrae. Cheminform 37.35(2006):3505-3508.
Uses
Diethylsilane is used as a precursor to prepare (3-allylsulfanyl-propyl)-diethyl-silane by using (Ph3P)3RhCl as reagent. It is also used in the chemical vapor deposition of SiO2 for microelectronics.
Application
Used in the ‘in-situ’ preparation of diborane and haloboranes.
DIETHYLSILANE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from DIETHYLSILANE manufacturers
- Product
- DIETHYLSILANE 542-91-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 97%-99.9%
- Supply Ability
- 100kg
- Release date
- 2019-12-25