ChemicalBook > CAS DataBase List > 2-BROMO-5-NITROANISOLE

2-BROMO-5-NITROANISOLE

Product Name
2-BROMO-5-NITROANISOLE
CAS No.
77337-82-7
Chemical Name
2-BROMO-5-NITROANISOLE
Synonyms
2-Bromo-5-nitroanisoL;2-BROMO-5-NITROANISOLE;2-Bromo-5-nitroanisole >2-Bromo-5-nitroanisole,98%;2-bromo-5-nitrobenzyl ether;2-BroMo-5-nitroanisole, 97+%;4-BROMO-3-METHOXYNITROBENZENE;2-Methoxy-4-nitrobromobenzene;2-BroMo-5-nitroanisole, 98% 10GR;1-BROMO-2-METHOXY-4-NITROBENZENE
CBNumber
CB8719656
Molecular Formula
C7H6BrNO3
Formula Weight
232.03
MOL File
77337-82-7.mol
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2-BROMO-5-NITROANISOLE Property

Melting point:
99-103 °C
Boiling point:
302.1±22.0 °C(Predicted)
Density 
1.640±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Water Solubility 
Insoluble in water
form 
Crystalline Powder
color 
Light brown
λmax
324nm(EtOH)(lit.)
BRN 
2520496
CAS DataBase Reference
77337-82-7(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-22
Safety Statements 
24/25-26
Hazard Note 
Irritant
HS Code 
29093090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3418
Product name
2-Bromo-5-nitroanisole
Purity
>98.0%(GC)
Packaging
5g
Price
$77
Updated
2025/07/31
TCI Chemical
Product number
B3418
Product name
2-Bromo-5-nitroanisole
Purity
>98.0%(GC)
Packaging
25g
Price
$306
Updated
2025/07/31
TRC
Product number
B688118
Product name
2-Bromo-5-nitroanisole
Packaging
5g
Price
$75
Updated
2021/12/16
ChemScene
Product number
CS-W014685
Product name
2-Bromo-5-nitroanisole
Packaging
100g
Price
$89
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0018783
Product name
2-BROMO-5-NITROANISOLE
Purity
95.00%
Packaging
1G
Price
$127.05
Updated
2021/12/16
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2-BROMO-5-NITROANISOLE Chemical Properties,Usage,Production

Chemical Properties

light brown crystalline powder

Synthesis

97-52-9

77337-82-7

General procedure for the synthesis of 2-bromo-5-nitroanisole from 2-methoxy-4-nitroaniline: a catalytic amount of copper bromide (1 mol%) was added to a solution of 2-methoxy-4-nitroaniline (2.5 mmol) in acetonitrile (30 ml), followed by camphorsulfonic acid (3.0 mmol), sodium nitrite or tert-butyl nitrite (3.0 mmol), and tetrabutylammonium bromide (5.0 mmol). The reaction mixture was stirred at 60°C for 24 h (Tables 1 and 2). Nitrogen release was observed immediately during the reaction. After completion of the reaction (confirmed by β-naphthol test and thin layer chromatography), the solvent was removed using a rotary evaporator. The residue was washed with water and extracted with dichloromethane. The organic phases were combined, dried with anhydrous magnesium sulfate and concentrated under reduced pressure. Finally, purification by column chromatography using a hexane/dichloromethane solvent mixture as eluent gave the pure product 2-bromo-5-nitroanisole. The physical properties and 1H NMR data of the product were consistent with the commercially available analytically pure sample.

References

[1] Tetrahedron, 2013, vol. 69, # 16, p. 3511 - 3517
[2] Tetrahedron, 2010, vol. 66, # 37, p. 7418 - 7422
[3] Tetrahedron Letters, 2010, vol. 51, # 51, p. 6769 - 6771
[4] Chemical and Pharmaceutical Bulletin, 2014, vol. 62, # 10, p. 979 - 988
[5] Journal of the American Chemical Society, 1935, vol. 57, p. 1592,1594

2-BROMO-5-NITROANISOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMO-5-NITROANISOLE Suppliers

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View Lastest Price from 2-BROMO-5-NITROANISOLE manufacturers

Henan Fengda Chemical Co., Ltd
Product
2-BROMO-5-NITROANISOLE 77337-82-7
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Honest Joy Holdings Limited
Product
2-BROMO-5-NITROANISOLE 77337-82-7
Price
US $0.00/KG
Min. Order
1KG
Purity
97.8%
Supply Ability
100 tons
Release date
2022-01-14
Shaanxi Dideu Medichem Co. Ltd
Product
2-Bromo-5-nitroanisole 77337-82-7
Price
US $0.00-0.00/Kg
Min. Order
1KG
Purity
99.0%
Supply Ability
100 tons
Release date
2020-01-10

77337-82-7, 2-BROMO-5-NITROANISOLERelated Search:

2-bromo-5-nitrobenzaldehyde 1-CYANO-2-BROMO-5-NITROBENZENE 4-BROMO-3-NITROANISOLE 2-BROMO-5-NITROETHOXYBENZENE 1-Bromo-4-nitrobenzene 2-Bromoanisole 4-BROMO-3-METHOXYANILINE 2-BROMO-5-NITROANISOLE 3-BROMO-5-NITROANISOLE 2-BROMO-4-NITROANISOLE 95%,2-BROMO-4-NITROANISOLE 2-Bromo-3-nitroanisole 99%,2-BROMO-3-NITROANISOLE 4-BROMO-2-NITROANISOLE 3-BROMO-4-NITROANISOLE 3-Bromo-2-nitroanisole 5-amino-2-bromophenol 1-bromo-2,5-dimethoxy-4-nitrobenzene 2-Bromo-4-nitrophenol 3-BROMO-4-NITROANISOLE 95%

  • 4-BROMO-3-METHOXYNITROBENZENE
  • 1-BROMO-2-METHOXY-4-NITROBENZENE
  • 2-BroMo-5-nitroanisole, 98% 10GR
  • 2-BroMo-5-nitroanisole, 97+%
  • 2-BROMO-5-NITROANISOLE
  • 2-Bromo-5-nitroanisole,98%
  • 2-Methoxy-4-nitrobroMobenzene[2-BroMo-5-nitroanisole]
  • 2-Bromo-5-nitroanisoL
  • 2-Bromo-5-nitroanisole &gt
  • Benzene, 1-bromo-2-methoxy-4-nitro-
  • 2-BROMO-5-NITROANISOLE ISO 9001：2015 REACH
  • 2-Bromo-5-nitroanisole[2-Methoxy-4-nitrobromobenzene
  • 2-bromo-5-nitrobenzyl ether
  • 2-Methoxy-4-nitrobromobenzene
  • 77337-82-7
  • Alcohols
  • Building Blocks
  • C7 to C8
  • Chemical Synthesis
  • New Products for Chemical Synthesis
  • Nitrogen Compounds
  • Organic Building Blocks
  • Oxygen Compounds
  • Aromatic Halides (substituted)
  • Phenyls & Phenyl-Het
  • Anisole
  • Miscellaneous
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Bromine Compounds
  • Nitro Compounds
  • Phenyls & Phenyl-Het