2-Bromo-3-nitroanisole
Uses- Product Name
- 2-Bromo-3-nitroanisole
- CAS No.
- 67853-37-6
- Chemical Name
- 2-Bromo-3-nitroanisole
- Synonyms
- TIMTEC-BB SBB008642;2-BROMO-3-NITROANISOLE;2-Bromo-3-nitroanisole 99%;2-Bromo-3-methoxynitrobenzene;2-BROMO-1-METHOXY-3-NITROBENZENE;Benzene, 2-bromo-1-methoxy-3-nitro-;2-Bromo-3-nitroanisole ISO 9001：2015 REACH;2-Bromo-3-methoxynitrobenzene, 2-Bromo-1-methoxy-3-nitrobenzene, 2-Bromo-3-nitrophenyl methyl ether
- CBNumber
- CB4109787
- Molecular Formula
- C7H6BrNO3
- Formula Weight
- 232.03
- MOL File
- 67853-37-6.mol
2-Bromo-3-nitroanisole Property
- Boiling point:
- 273.3±20.0 °C(Predicted)
- Density
- 1.640±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- powder
- color
- Yellow
- InChI
- InChI=1S/C7H6BrNO3/c1-12-6-4-2-3-5(7(6)8)9(10)11/h2-4H,1H3
- InChIKey
- KCFDURKFXBLIAY-UHFFFAOYSA-N
- SMILES
- C1(OC)=CC=CC([N+]([O-])=O)=C1Br
- CAS DataBase Reference
- 67853-37-6(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 20/21/22-22
- Safety Statements
- 26-36/37/39
- Hazard Note
- Irritant
- HS Code
- 2909309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- TMT00303
- Product name
- 2-Bromo-1-methoxy-3-nitrobenzene
- Packaging
- 1g
- Price
- $550
- Updated
- 2025/07/31
- Product number
- B688108
- Product name
- 2-Bromo-3-nitroanisole
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- B688108
- Product name
- 2-Bromo-3-nitroanisole
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- B688108
- Product name
- 2-Bromo-3-nitroanisole
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- OR6218
- Product name
- 2-Bromo-3-nitroanisole
- Purity
- 99%
- Packaging
- 1g
- Price
- $15
- Updated
- 2021/12/16
2-Bromo-3-nitroanisole Chemical Properties,Usage,Production
Uses
2-Bromo-3-nitroanisole belongs to the class of bromoanisoles and can be used to synthesize rhodopsin coupling promoters and new drugs.
Synthesis
101935-40-4
74-88-4
67853-37-6
General procedure for the synthesis of 2-bromo-3-nitroanisole from 2-bromo-3-nitrophenol (3.1 g, 14.2 mmol) and iodomethane (2.6 mL, 42.5 mmol): 2-bromo-3-nitrophenol was dissolved in N,N-dimethylformamide (DMF, 20 mL), to which was added ground cesium carbonate (5.58 g, 17.1 mmol), followed by the addition of iodomethane. The reaction mixture was stirred at room temperature overnight. After completion of the reaction, DMF was removed by rotary evaporator and the residue was dissolved in ether (200 mL) and washed sequentially with water (200 mL) and saturated sodium chloride solution (4 x 100 mL). The organic phase was dried with anhydrous magnesium sulfate, filtered and concentrated to give the crude product 2-bromo-3-nitroanisole (94% yield, 3.1 g) as an orange solid. Mass spectrometry (MS) analysis showed m/z 234 ([M+2H]+). High performance liquid chromatography (HPLC, TFA system, 220 nm detection) showed a product purity of 98%.
References
[1] Patent: WO2004/103996, 2004, A1. Location in patent: Page 40-41
[2] Patent: WO2006/7700, 2006, A1. Location in patent: Page/Page column 62
[3] Patent: US2006/19905, 2006, A1. Location in patent: Page/Page column 24
[4] Patent: WO2006/85, 2006, A1. Location in patent: Page/Page column 75-76
[5] Patent: WO2007/9227, 2007, A1. Location in patent: Page/Page column 35
2-Bromo-3-nitroanisole Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-Bromo-3-nitroanisole manufacturers
- Product
- 2-Bromo-3-nitroanisole 67853-37-6
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-26
- Product
- 2-Bromo-3-nitroanisole 67853-37-6
- Price
- US $0.00-0.00/Kg
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 100 tons
- Release date
- 2020-01-10
- Product
- 2-Bromo-3-nitroanisole 67853-37-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2019-05-23