ChemicalBook > CAS DataBase List > (R)-(-)-2-Aminobutane

(R)-(-)-2-Aminobutane

Product Name
(R)-(-)-2-Aminobutane
CAS No.
13250-12-9
Chemical Name
(R)-(-)-2-Aminobutane
Synonyms
(R)-2-Butanamine;(2R)-butan-2-amine;(R)-N-sec-Butylamine;(R)-(-)-2-Aminobutane;(2R)-(-)-2-Aminobutane;(R)-(-)-sec-Butylamine;(R)-1-Methylpropylamine;R(-)-SEC-BUTYLAMINE 99+%;(R)-(-)-2-Aminobutane,98%;2-Butanamine, (2R)- (9CI)
CBNumber
CB8853044
Molecular Formula
C4H11N
Formula Weight
73.14
MOL File
13250-12-9.mol
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(R)-(-)-2-Aminobutane Property

Melting point:
-105°C
alpha 
-7.5 º (c=neat 19 ºC)
Boiling point:
63 °C(lit.)
Density 
0.72 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.393(lit.)
Flash point:
-19°C
storage temp. 
Flammables area
pka
10.74±0.10(Predicted)
form 
clear liquid
color 
Colorless to Almost colorless
optical activity
[α]19/D 7.5°, neat
Water Solubility 
> 10 mg/L
Sensitive 
Air Sensitive
Merck 
14,1544
BRN 
1718760
CAS DataBase Reference
13250-12-9(CAS DataBase Reference)
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Safety

Hazard Codes 
F,C,N,F+
Risk Statements 
11-34-50-35-20/22
Safety Statements 
16-26-36/37/39-45-9-61-28A-28
RIDADR 
UN 2733 3/PG 2
WGK Germany 
3
F 
10-23
HazardClass 
3
PackingGroup 
II
HS Code 
29211999
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
296643
Product name
(R)-(?)-sec-Butylamine
Purity
99%
Packaging
250mg
Price
$55.8
Updated
2024/03/01
Sigma-Aldrich
Product number
296643
Product name
(R)-(?)-sec-Butylamine
Purity
99%
Packaging
1g
Price
$201
Updated
2024/03/01
TCI Chemical
Product number
B2917
Product name
(R)-(-)-sec-Butylamine
Packaging
100MG
Price
$37
Updated
2024/03/01
TCI Chemical
Product number
B2917
Product name
(R)-(-)-sec-Butylamine
Packaging
1G
Price
$173
Updated
2024/03/01
Alfa Aesar
Product number
L03889
Product name
(R)-(-)-2-Aminobutane, 99%
Packaging
1g
Price
$218
Updated
2023/06/20
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(R)-(-)-2-Aminobutane Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(R)-(-)-2-Aminobutane is a chiral amine plays an important role in pharmaceutical chemistry and in organic synthesis as chiral auxiliary, which is used to determine the enantiomeric excess (ee).

Uses

(R)-(?)-sec-Butylamine can be used:

  • To prepare (R)-(?)-sec-butylbis(2-hydroxyethyl)amine, an intermediate for the synthesis of aminodiphosphine ligands.
  • As a substrate to demonstrate the stereochemistry of Mitsunobu reaction in the synthesis of secondary amines.
  • As a model compound in the study of singlet-triplet transitions in circular dichroism.

Purification Methods

Dry it over solid NaOH overnight and fractionate it through a short helices packed column. The L-hydrogen tartrate salt has m 139-140o (from H2O), the 1H2O has m 96o []D +18.1o (c 11, H2O), the hydrochloride has m 152o [ ] 21 -1.1o (c 13, H2O) and the benzoyl derivative crystallises from EtOH as needles with m 97o, [] 21 -34.9o (c 11, H2O). [Bruck et al. J Chem Soc 921 1956,Kjaer & Hansen Acta Chem Scand 11 898 1957.] [Beilstein 4 H 161, 4 I 372, 4 III 308, 4 IV 617.] The S -(+)-enantiomer has has same properties except for the optical rotation which has the opposite sign.

(R)-(-)-2-Aminobutane Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(-)-2-Aminobutane Suppliers

Americas 1 Belgium 3 China 56 Europe 1 Germany 8 India 8 Japan 2 Switzerland 2 United Kingdom 7 United States 19 Global 107
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View Lastest Price from (R)-(-)-2-Aminobutane manufacturers

Career Henan Chemical Co
Product
(R)-(-)-2-Aminobutane 13250-12-9
Price
US $10.00/KG/Tin
Min. Order
1KG/Tin
Purity
99%
Supply Ability
100
Release date
2019-06-27

13250-12-9, (R)-(-)-2-AminobutaneRelated Search:

1,2,3,4-Butanetetracarboxylic acid ISOBUTANE 1-Chlorobutane n-Butane 1-Chloro-2-methylpropane 1-Bromo-2-methylpropane 1-Bromobutane 2,2-DICHLOROBUTANE NITROCYCLOPENTANE TPCK 1,8-DIAMINO-P-MENTHANE Cyclobutylamine N-ALPHA-BENZOYL-L-ARGININE 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE 1-ETHYNYLCYCLOHEXYLAMINE sec-Butylamine Aminobutane,1-Aminobutane, n-Butylamine,1-AMINOBUTANE Nalpha-Cbz-L-Arginine

  • (R)-(-)-sec-Butylamine
  • (R)-1-Methylpropylamine
  • (R)-2-Butanamine
  • (R)-N-sec-Butylamine
  • (2R)-(-)-2-Aminobutane
  • (1R)-(-)-1-Methylpropylamine
  • (2R)-(-)-2-Aminobutane, R-(-)-sec-Butylamine
  • (R)-(-)-2-Aminobutane,98%
  • (R)-(-)-sec-Butylamine 99%
  • (2R)-butan-2-amine
  • R(-)-SEC-BUTYLAMINE 99+%
  • (R)-(-)-2-Aminobutane
  • (R)-(-)-2-BUTYLAMINE HYDROCHLORIDE
  • 2-Butanamine, (2R)- (9CI)
  • (R)-(-)-2-Aminobutane ISO 9001：2015 REACH
  • 13250-12-9
  • C2H5CHNH2CH3
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Amines
  • Organic Building Blocks
  • chiral
  • Amines (Chiral)
  • Chiral Building Blocks
  • Synthetic Organic Chemistry