(R)-(-)-2-Aminobutane
- Product Name
- (R)-(-)-2-Aminobutane
- CAS No.
- 13250-12-9
- Chemical Name
- (R)-(-)-2-Aminobutane
- Synonyms
- (R)-2-Butanamine;(2R)-butan-2-amine;(R)-N-sec-Butylamine;(R)-(-)-2-Aminobutane;(2R)-(-)-2-Aminobutane;(R)-(-)-sec-Butylamine;(R)-1-Methylpropylamine;R(-)-SEC-BUTYLAMINE 99+%;(R)-(-)-2-Aminobutane,98%;2-Butanamine, (2R)- (9CI)
- CBNumber
- CB8853044
- Molecular Formula
- C4H11N
- Formula Weight
- 73.14
- MOL File
- 13250-12-9.mol
(R)-(-)-2-Aminobutane Property
- Melting point:
- -105°C
- alpha
- -7.5 º (c=neat 19 ºC)
- Boiling point:
- 63 °C(lit.)
- Density
- 0.72 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.393(lit.)
- Flash point:
- -19°C
- storage temp.
- Flammables area
- pka
- 10.74±0.10(Predicted)
- form
- clear liquid
- color
- Colorless to Almost colorless
- optical activity
- [α]19/D 7.5°, neat
- Water Solubility
- > 10 mg/L
- Sensitive
- Air Sensitive
- Merck
- 14,1544
- BRN
- 1718760
- CAS DataBase Reference
- 13250-12-9(CAS DataBase Reference)
Safety
- Hazard Codes
- F,C,N,F+
- Risk Statements
- 11-34-50-35-20/22
- Safety Statements
- 16-26-36/37/39-45-9-61-28A-28
- RIDADR
- UN 2733 3/PG 2
- WGK Germany
- 3
- F
- 10-23
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29211999
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H314Causes severe skin burns and eye damage
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 296643
- Product name
- (R)-(?)-sec-Butylamine
- Purity
- 99%
- Packaging
- 250mg
- Price
- $55.8
- Updated
- 2024/03/01
- Product number
- 296643
- Product name
- (R)-(?)-sec-Butylamine
- Purity
- 99%
- Packaging
- 1g
- Price
- $201
- Updated
- 2024/03/01
- Product number
- B2917
- Product name
- (R)-(-)-sec-Butylamine
- Packaging
- 100MG
- Price
- $37
- Updated
- 2024/03/01
- Product number
- B2917
- Product name
- (R)-(-)-sec-Butylamine
- Packaging
- 1G
- Price
- $173
- Updated
- 2024/03/01
- Product number
- L03889
- Product name
- (R)-(-)-2-Aminobutane, 99%
- Packaging
- 1g
- Price
- $218
- Updated
- 2023/06/20
(R)-(-)-2-Aminobutane Chemical Properties,Usage,Production
Chemical Properties
Colorless to light yellow liqui
Uses
(R)-(-)-2-Aminobutane is a chiral amine plays an important role in pharmaceutical chemistry and in organic synthesis as chiral auxiliary, which is used to determine the enantiomeric excess (ee).
Uses
(R)-(?)-sec-Butylamine can be used:
- To prepare (R)-(?)-sec-butylbis(2-hydroxyethyl)amine, an intermediate for the synthesis of aminodiphosphine ligands.
- As a substrate to demonstrate the stereochemistry of Mitsunobu reaction in the synthesis of secondary amines.
- As a model compound in the study of singlet-triplet transitions in circular dichroism.
Purification Methods
Dry it over solid NaOH overnight and fractionate it through a short helices packed column. The L-hydrogen tartrate salt has m 139-140o (from H2O), the 1H2O has m 96o []D +18.1o (c 11, H2O), the hydrochloride has m 152o [ ] 21 -1.1o (c 13, H2O) and the benzoyl derivative crystallises from EtOH as needles with m 97o, [] 21 -34.9o (c 11, H2O). [Bruck et al. J Chem Soc 921 1956,Kjaer & Hansen Acta Chem Scand 11 898 1957.] [Beilstein 4 H 161, 4 I 372, 4 III 308, 4 IV 617.] The S -(+)-enantiomer has has same properties except for the optical rotation which has the opposite sign.
(R)-(-)-2-Aminobutane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (R)-(-)-2-Aminobutane manufacturers
- Product
- (R)-(-)-2-AMinobutane 13250-12-9
- Price
- US $1.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 10000KG
- Release date
- 2020-01-07
- Product
- (R)-(-)-2-Aminobutane 13250-12-9
- Price
- US $10.00/KG/Tin
- Min. Order
- 1KG/Tin
- Purity
- 99%
- Supply Ability
- 100
- Release date
- 2019-06-27