ChemicalBook > CAS DataBase List > Diethyl 1,1-cyclopropanedicarboxylate
Diethyl 1,1-cyclopropanedicarboxylate
- Product Name
- Diethyl 1,1-cyclopropanedicarboxylate
- CAS No.
- 1559-02-0
- Chemical Name
- Diethyl 1,1-cyclopropanedicarboxylate
- Synonyms
- DIETHYL CYCLOPROPANE-1,1-DICARBOXYLATE;1,1-CYCLOPROPANEDICARBOXYLIC ACID DIETHYL ESTER;Diethyl 1;NSC 21376;RARECHEM AL BO 0836;opropane-1,1-dicarboxyL;DiethyldifluoroMalonate96%;1-Cyclopropanedicarboxylate;1,1-Dicarbethoxycyclopropane;Ethyl 1,1-cyclopropanedicarboxylate
- CBNumber
- CB8853145
- Molecular Formula
- C9H14O4
- Formula Weight
- 186.21
- MOL File
- 1559-02-0.mol
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Diethyl 1,1-cyclopropanedicarboxylate Property
- Melting point:
- 134-136 °C(lit.)
- Boiling point:
- 94-96 °C/10 mmHg (lit.)
- Density
- 1.055 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.433(lit.)
- Flash point:
- 188 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Acetone (Slightly), Chlorform (Slightly), Methanol (Slightly)
- form
- Liquid
- color
- Clear colorless
- BRN
- 2049509
- CAS DataBase Reference
- 1559-02-0(CAS DataBase Reference)
- NIST Chemistry Reference
- Diethyl 1,1-cyclopropanedicarboxylate(1559-02-0)
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-24/25-23
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- HazardClass
- IRRITANT
- HS Code
- 29172090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H227Combustible liquid
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P501Dispose of contents/container to..…
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 147710
- Product name
- Diethyl cyclopropane-1,1-dicarboxylate
- Purity
- 97%
- Packaging
- 5g
- Price
- $103
- Updated
- 2023/06/20
Sigma-Aldrich
- Product number
- 147710
- Product name
- Diethyl cyclopropane-1,1-dicarboxylate
- Purity
- 97%
- Packaging
- 25g
- Price
- $381
- Updated
- 2023/06/20
TCI Chemical
- Product number
- C1341
- Product name
- Diethyl 1,1-Cyclopropanedicarboxylate
- Purity
- >96.0%(GC)
- Packaging
- 5g
- Price
- $16
- Updated
- 2024/03/01
TCI Chemical
- Product number
- C1341
- Product name
- Diethyl 1,1-Cyclopropanedicarboxylate
- Purity
- >96.0%(GC)
- Packaging
- 25g
- Price
- $37
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- H56568
- Product name
- Diethyl cyclopropane-1,1-dicarboxylate
- Packaging
- 1g
- Price
- $27.65
- Updated
- 2024/03/01
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Diethyl 1,1-cyclopropanedicarboxylate Chemical Properties,Usage,Production
Chemical Properties
clear colorless liquid
Uses
Diethyl 1,1-Cyclopropanedicarboxylate (cas# 1559-02-0) is a compound useful in organic synthesis.
Synthesis Reference(s)
Synthesis, p. 690, 1980 DOI: 10.1055/s-1980-29171
General Description
Diethyl cyclopropane-1,1-dicarboxylate participates in ring-opening addition reactions with various nucleophilic reagents.
Purification Methods
If it is free from OH bands in the IR, then fractionally distil the ester and redistil the middle fraction. Otherwise shake it with aqueous NaHCO3, dry it (MgSO4), filter and distil as before or re-esterify it. [As synthon see Danishefsky Acc Chem Res 12 66 1979, Beilstein 9 I 314, 9 II 512, 9 III 3595, 9 IV 2786.]
Diethyl 1,1-cyclopropanedicarboxylate Preparation Products And Raw materials
Raw materials
Preparation Products
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Diethyl 1,1-cyclopropanedicarboxylate Suppliers
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- Country
- Switzerland
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- 6968
- Advantage
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- Switzerland
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- Switzerland
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View Lastest Price from Diethyl 1,1-cyclopropanedicarboxylate manufacturers
Hebei Weibang Biotechnology Co., Ltd
- Product
- Diethyl 1,1-cyclopropanedicarboxylate 1559-02-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-11-01
Hebei Mojin Biotechnology Co., Ltd
- Product
- Diethyl 1,1-cyclopropanedicarboxylate 1559-02-0
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-10-16
Henan Aochuang Chemical Co.,Ltd.
- Product
- Diethyl 1,1-cyclopropanedicarboxylate 1559-02-0
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-09-29
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