Cyclohexyl mercaptan Property

Melting point:

-30 °C

Boiling point:

158-160 °C (lit.)

Density 

0.95 g/mL at 25 °C (lit.)

vapor density 

4 (vs air)

vapor pressure 

10.3 mm Hg ( 37.7 °C)

refractive index 

n20/D 1.493(lit.)

Flash point:

110 °F

storage temp. 

Flammables area

solubility 

insoluble

form 

liquid

pka

10.96±0.20(Predicted)

color 

Colorless to Almost colorless

Odor

sulfurous

explosive limit

1.1%(V)

Water Solubility 

insoluble

Sensitive 

Air Sensitive/Stench

BRN 

1236342

LogP

3.05-3.7 at 35℃

CAS DataBase Reference

1569-69-3(CAS DataBase Reference)

NIST Chemistry Reference

Cyclohexanethiol(1569-69-3)

EPA Substance Registry System

Cyclohexanethiol (1569-69-3)

Safety

Hazard Codes 

Xn,F,Xi,N

Risk Statements 

10-20/22-51/53-36/37/38

Safety Statements 

36/37/39-57-37/39-26-16

RIDADR 

UN 3054 3/PG 3

OEL

Ceiling: 0.5 ppm (2.4 mg/m3) [15-minute]

WGK Germany 

3

RTECS 

GV7525000

Hazard Note 

Irritant/Flammable/Stench/Air Sensitive

HazardClass 

3

PackingGroup 

III

HS Code 

29309070

Hazardous Substances Data

1569-69-3(Hazardous Substances Data)

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H331Toxic if inhaled

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

Cyclohexyl mercaptan Chemical Properties,Usage,Production

Chemical Properties

CLEAR LIQUID

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 6057, 1994 DOI: 10.1016/0040-4039(94)88074-3

General Description

A colorless liquid with a strong disagreeable odor. Insoluble in water and less dense than water. Vapors heavier than air. Flash point near 50°F.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Cyclohexyl mercaptan is incompatible with the following: Oxidizers, reducing agents, strong acids, alkali metals .

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Flammability and Explosibility

Flammable

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion, subcutaneous, and intramuscular routes. Mildly toxic by skin contact. Human systemic effects by inhalation: conjunctiva irritation and changes in the olfactory and respiratory systems. Has caused damage to kidneys, liver, and blood vessels in experimental animals. Experimental reproductive effects. Human mutation data reported. A severe eye irritant. Narcotic-like action. Flammable when exposed to heat or flame; can react with oxiduing materials. Iptes on contact with chromium trioxide. Violent reaction with HNO3. Incompatible with oxidants. To fight fire, use alcohol foam, foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also ALCOHOLS.