ChemicalBook > CAS DataBase List > (S)-3-phenylmorpholine

(S)-3-phenylmorpholine

Product Name
(S)-3-phenylmorpholine
CAS No.
914299-79-9
Chemical Name
(S)-3-phenylmorpholine
Synonyms
(S)-3-phenylmorpholine;(S)-4-Phenylmorpholine;(3S)-3-phenylmorpholine;Morpholine, 3-phenyl-, (3S)-
CBNumber
CB91166254
Molecular Formula
C10H13NO
Formula Weight
163.22
MOL File
914299-79-9.mol
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(S)-3-phenylmorpholine Property

storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
Appearance
Off-white to light yellow Solid
optical activity
44.9069°(C=1.0038g/ml MEOH)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
P336653
Product name
(S)-3-Phenylmorpholine
Packaging
10mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
5326AC
Product name
(S)-3-Phenylmorpholine
Packaging
100mg
Price
$147
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0001511
Product name
(S)-3-PHENYLMORPHOLINE
Purity
95.00%
Packaging
1G
Price
$906.15
Updated
2021/12/16
AK Scientific
Product number
5326AC
Product name
(S)-3-Phenylmorpholine
Packaging
1g
Price
$440
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0001511
Product name
(S)-3-PHENYLMORPHOLINE
Purity
95.00%
Packaging
5MG
Price
$498.43
Updated
2021/12/16
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(S)-3-phenylmorpholine Chemical Properties,Usage,Production

Synthesis

1052209-96-7

914299-79-9

Step 3. A THF solution of (S)-5-phenylmorpholin-3-one (481 mg, dissolved in 6 mL of THF) was slowly added dropwise to a LiAlH4/THF suspension (0.47 g LiAlH4 dissolved in 2 mL of THF) at room temperature for a controlled time of over 5 minutes. After the dropwise addition, the reaction mixture was stirred at room temperature for 1 h, followed by transferring to a 72 °C oil bath for heating overnight. Upon completion of the reaction, the mixture was cooled to 0 °C and the reaction was quenched by sequential addition of H2O (0.47 mL), 3M NaOH aqueous solution (0.47 mL) and H2O (1.4 mL). The quenched mixture was diluted with Et2O (30 mL) and stirred for 10 min before separating the ether phase by filtration. The filtrate was concentrated and further dried under vacuum to give (S)-3-phenylmorpholine as a colorless solid (424 mg, 96% yield).LCMS (m/z): 164.2 (MH+), retention time 0.33 min.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 15, p. 4316 - 4320
[2] Angewandte Chemie - International Edition, 2013, vol. 52, # 20, p. 5319 - 5322
[3] Angew. Chem., 2013, vol. 125, # 20, p. 5427 - 5430,4
[4] Patent: US9242996, 2016, B2. Location in patent: Page/Page column 265; 266
[5] Patent: WO2018/116285, 2018, A1. Location in patent: Page/Page column 24

(S)-3-phenylmorpholine Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (S)-3-phenylmorpholine manufacturers

Career Henan Chemical Co
Product
(S)-3-phenylmorpholine 914299-79-9
Price
US $5.00/KG
Min. Order
1KG
Purity
95%-98%
Supply Ability
100kg
Release date
2019-09-03

914299-79-9, (S)-3-phenylmorpholineRelated Search:

3S-3-METHYLMORPHOLINE (S)-3-(tert-butyl)morpholine (R)-3-BENZYLMORPHOLINE (R)-3-ISOPROPYLMORPHOLINE, (S)-3-((S)-sec-butyl)Morpholine (R)-3-(tert-butyl)morpholine (R)-3-Methylmorpholine (S)-3-Isopropylmorpholine (R)-3-((R)-sec-butyl)morpholine (R)-3-Isobutylmorpholine tert-Butyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate (5S)-N-(tert-Butoxycarbonyl)-3,4,5,6-tetrahydro-5-phenyl-4(H)-1,4-oxazin-2-one (5R)-3,4,5,6-Tetrahydro-5-phenyl-4(H)-1,4-oxazin-2-one Aprepitant Fosaprepitant (5S)-3,4,5,6-TETRAHYDRO-5-PHENYL-N-(BENZYLOXYCARBONYL)-4(H)-1,4-OXAZIN-2-ONE (2R,6R,8S,12S)-1-AZA-10-OXA-12-PHENYLTRICYCLO[6.4.01,8.02,6]DODECAN-9-ONE

  • (S)-3-phenylmorpholine
  • Morpholine, 3-phenyl-, (3S)-
  • (3S)-3-phenylmorpholine
  • (S)-4-Phenylmorpholine
  • 914299-79-9