ChemicalBook > CAS DataBase List > Methyl 4-bromophenylacetate
Methyl 4-bromophenylacetate
- Product Name
- Methyl 4-bromophenylacetate
- CAS No.
- 41841-16-1
- Chemical Name
- Methyl 4-bromophenylacetate
- Synonyms
- METHYL 2-(4-BROMOPHENYL)ACETATE;NSC 245163;ASISCHEM D13381;Aprocitentan Impurity 32;METHYL 4-BROMOPHENYLACETATE;Methyl 4-bromophenylaceta...;4 - broMobenzene Methyl acetate;Methyl 4-BroMophenylacetate, 97+%;methyl 2-(4-bromophenyl)ethanoate;4-BROMOPHENYL ACETIC ACID METHYL ESTER
- CBNumber
- CB9124541
- Molecular Formula
- C9H9BrO2
- Formula Weight
- 229.07
- MOL File
- 41841-16-1.mol
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Methyl 4-bromophenylacetate Property
- Melting point:
- 113-114 °C
- Boiling point:
- 138-140 °C(Press: 13 Torr)
- Density
- 1.445±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform, Ethyl Acetate
- form
- Oil
- color
- Clear Colorless to Pale Yellow
- InChI
- InChI=1S/C9H9BrO2/c1-12-9(11)6-7-2-4-8(10)5-3-7/h2-5H,6H2,1H3
- InChIKey
- QHJOWSXZDCTNQX-UHFFFAOYSA-N
- SMILES
- C1(CC(OC)=O)=CC=C(Br)C=C1
- CAS DataBase Reference
- 41841-16-1(CAS DataBase Reference)
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Safety
- Hazard Codes
- Xi
- HazardClass
- IRRITANT
- HS Code
- 29163990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
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N-Bromosuccinimide Price
TRC
- Product number
- M294310
- Product name
- Methyl4-Bromophenylacetate
- Packaging
- 10g
- Price
- $375
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- HCH0013002
- Product name
- 4-BROMOPHENYL ACETIC ACID METHYL ESTER
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $671.75
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- HCH0013002
- Product name
- 4-BROMOPHENYL ACETIC ACID METHYL ESTER
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $988.33
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- HCH0013002
- Product name
- 4-BROMOPHENYL ACETIC ACID METHYL ESTER
- Purity
- 95.00%
- Packaging
- 10G
- Price
- $1398.82
- Updated
- 2021/12/16
Ark Pharm
- Product number
- P000131726
- Product name
- Methyl 2-(4-bromophenyl)acetate
- Purity
- 98%
- Packaging
- 500g
- Price
- $168
- Updated
- 2021/12/16
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Methyl 4-bromophenylacetate Chemical Properties,Usage,Production
Chemical Properties
Pale Yellow Oil
Uses
Methyl 4-Bromophenylacetate (cas# 41841-16-1) is a compound useful in organic synthesis.
Synthesis
67-56-1
1878-68-8
41841-16-1
Step 3: Synthesis of methyl 4-bromophenylacetate Sulfuric acid (56.5 mL) was slowly added dropwise to a solution of 206.6 g of 4-bromophenylacetic acid in methanol (800 mL), with the rate of dropwise acceleration being controlled to prevent violent exotherm. After the dropwise addition, the reaction mixture was heated to reflux and maintained at reflux for 2 hours. Subsequently, the device was replaced and the reflux condenser was replaced with a distillation header and approximately 400 mL of methanol was removed by distillation at atmospheric pressure. The reaction system was cooled down to 50 °C and the reaction was continued with stirring for 16 hours. Upon completion of the reaction, the mixture was cooled to room temperature, transferred to a dispensing funnel and partitioned with dichloromethane (1 L) and water (600 mL). The organic phase was separated, washed with saturated sodium bicarbonate solution and dried with anhydrous magnesium sulfate. The organic phase was concentrated under reduced pressure to give 220.1 g (98% yield) of methyl 4-bromophenylacetate as a colorless oil. HNMR (CDCl3): δ 3.59 (s, 2H), 3.70 (s, 3H), 7.16 (d, 2H), 7.45 (d, 2H).
References
[1] Journal of Organic Chemistry, 1994, vol. 59, # 9, p. 2620 - 2622
[2] Bioorganic and Medicinal Chemistry, 2003, vol. 11, # 13, p. 2843 - 2866
[3] Journal of Medicinal Chemistry, 2001, vol. 44, # 17, p. 2701 - 2706
[4] Patent: US2008/21024, 2008, A1. Location in patent: Page/Page column 80
[5] Patent: WO2010/86820, 2010, A1. Location in patent: Page/Page column 41
Methyl 4-bromophenylacetate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Methyl 4-bromophenylacetate manufacturers
Hebei Chuanghai Biotechnology Co., Ltd
- Product
- Methyl 4-bromophenylacetate 41841-16-1
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-10-30
Hebei Yanxi Chemical Co., Ltd.
- Product
- Methyl 4-bromophenylacetate 41841-16-1
- Price
- US $10.00-5.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 15 tons
- Release date
- 2023-10-11
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- Methyl 4-bromophenylacetate 41841-16-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
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