lycorenine

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Product Name: lycorenine
CAS No.: 477-19-0
Chemical Name: lycorenine
Synonyms: ycorenine;lycorenine;lycorenine USP/EP/BP;9,10-Dimethoxy-1-methyllycorenan-7α-ol;(7alpha)-9,10-dimethoxy-1-methyllycorenan-7-ol;(5aR,7S,11bS,11cS)-9,10-dimethoxy-1-methyl-3,5,5a,7,11b,11c-hexahydro-2H-isochromeno[3,4-g]indol-7-ol;(5aR,7S,11bS,11cS)-1,2,3,5,5a,7,11b,11c-Octahydro-9,10-dimethoxy-1-methyl-[2]benzopyrano[3,4-g]indol-7-ol;[2]Benzopyrano[3,4-g]indol-7-ol, 1,2,3,5,5a,7,11b,11c-octahydro-9,10-dimethoxy-1-methyl-,(5aR,7S,11bS,11cS)-
CBNumber: CB91377212
Molecular Formula: C18H23NO4
Formula Weight: 317.38
MOL File: 477-19-0.mol

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lycorenine Property

Melting point:: 199-200℃
Boiling point:: 477.7±45.0 °C(Predicted)
Density: 1.28
solubility: Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form: Cryst.
pka: 11.98±0.20(Predicted)

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Usbiological

Product number: 300598
Product name: Lycorenine
Packaging: 20mg
Price: $490
Updated: 2021/12/16

Biorbyt Ltd

Product number: orb105529
Product name: Lycorenine
Purity: >98%
Packaging: 20mg
Price: $569.5
Updated: 2021/12/16

AvaChem

Product number: 1806
Product name: Lycorenin
Packaging: 10mg
Price: $690
Updated: 2021/12/16

DC Chemicals

Product number: DCS-119
Product name: Lycorenine
Purity: >98%,StandardReferencesGrade
Packaging: 20mg
Price: $280
Updated: 2021/12/16

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lycorenine Chemical Properties,Usage,Production

Description

An alkaloid isolated from Lycoris radiata Herb. the base crystallizes from Me2CO in rhombic prisms and has [α]²⁰_D + 149.3°. The alkaloid yields crystalline salts and derivatives, e.g. the aurichloride decomposing at 116°C, platinichloride, also decomposing before melting at 210°C; picrate, m.p. 162°C (dec.); monoacetyl derivative, m.p. 185 _7°C. The diacetyl compound has been prepared although with some difficulty and under forcing conditions, m.p. 17 5-6°C. The alkaloid behaves as a pseudo-base giving an oxime hydrochloride which decomposes at 258°C. On catalytic hydrogenation it yields the dihydro-derivative, m.p. 175- 7°C and prolonged hydrogenation eventually forms deoxytetrahydrolycorenine, ClsH2S03N, m.p. 165-8°C although other compounds are also formed at the same time, e.g. C1sH27 0 2N, m.p. l65-7°C and ClsH2S03N, m.p. l20-3°C. The methiodide decomposes when heated at 260°C and on treatment with silver oxide forms two methine bases, of which the (±)-form has been isolated as the methiodide, m.p. 223°C (dec.). The complete structure has been determined primarily from the mass spectrum.

Uses

Lycorenine is an antibacterial agent extracted from the bulb of Lycoris radiata.

Definition

ChEBI: Lycorenine is an alkaloid.

target

Antifection

References

Kondo, Tomimura, Ishiwatari., J. Pharrn. Soc., Japan, 52, 51 (1932) Spectra: Inuka et aI., Tetrahedron Lett., 4745 (1966) Stereochemistry: Mizukami., Tetrahedron, 11,89 (1960)

lycorenine Preparation Products And Raw materials

Raw materials

Preparation Products

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477-19-0, lycorenineRelated Search:

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lycorenine

[2]Benzopyrano[3,4-g]indol-7-ol, 1,2,3,5,5a,7,11b,11c-octahydro-9,10-dimethoxy-1-methyl-,(5aR,7S,11bS,11cS)-

9,10-Dimethoxy-1-methyllycorenan-7α-ol

(5aR,7S,11bS,11cS)-9,10-dimethoxy-1-methyl-3,5,5a,7,11b,11c-hexahydro-2H-isochromeno[3,4-g]indol-7-ol

(5aR,7S,11bS,11cS)-1,2,3,5,5a,7,11b,11c-Octahydro-9,10-dimethoxy-1-methyl-[2]benzopyrano[3,4-g]indol-7-ol

ycorenine

lycorenine USP/EP/BP

(7alpha)-9,10-dimethoxy-1-methyllycorenan-7-ol

477-19-0