Iodoethane

ChemicalBook > CAS DataBase List > Iodoethane

Product Name: Iodoethane
CAS No.: 75-03-6
Chemical Name: Iodoethane
Synonyms: ETHYL IODIDE;Iodethan;C2H5I;Iodoethane (stabilized with Copper chip);ENCH;Jodethan;IODOETHANE;Ethyliodid;Ethyljodid;iodo-ethan
CBNumber: CB9139251
Molecular Formula: C2H5I
Formula Weight: 155.97
MOL File: 75-03-6.mol

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Iodoethane Property

Melting point:: -108 °C
Boiling point:: 69-73 °C(lit.)
Density: 1.95 g/mL at 25 °C(lit.)
vapor density: 5.38 (vs air)
vapor pressure: 100 mm Hg ( 18 °C)
refractive index: n20/D 1.513(lit.)
Flash point:: 53 °C
storage temp.: Store below +30°C.
solubility: 4g/l (slow decomposition)
form: Liquid
color: Clear colorless to faint yellow or pink
Specific Gravity: 1.95
Odor: light delicate odor
Water Solubility: 4 g/L (20 ºC)
Sensitive: Light Sensitive
Merck: 14,3813
BRN: 505934
Dielectric constant: 7.4（20℃）
CAS DataBase Reference: 75-03-6(CAS DataBase Reference)
NIST Chemistry Reference: Iodoethane(75-03-6)
EPA Substance Registry System: Ethane, iodo- (75-03-6)

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Safety

Hazard Codes: Xn,T
Risk Statements: 20-36/37/38-42/43-10-23/24/25-22-20/22
Safety Statements: 23-26-36/37-45-37/39-16-36/37/39-27
RIDADR: 2922
WGK Germany: 3
RTECS: KI4750000
F: 1-8
TSCA: Yes
HS Code: 2903 39 80
HazardClass: 6.1
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

H341Suspected of causing genetic defects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: I7780
Product name: Iodoethane
Purity: contains copper as stabilizer, ReagentPlus , 99%
Packaging: 5g
Price: $31.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: I7780
Product name: Iodoethane
Purity: contains copper as stabilizer, ReagentPlus , 99%
Packaging: 100g
Price: $48.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.00896
Product name: Iodoethane
Purity: (stabilised with silver) for synthesis
Packaging: 100mL
Price: $150
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.00896
Product name: Iodoethane
Purity: (stabilised with silver) for synthesis
Packaging: 500mL
Price: $508
Updated: 2024/03/01

TCI Chemical

Product number: I0058
Product name: Iodoethane (stabilized with Copper chip)
Purity: >99.0%(GC)
Packaging: 25g
Price: $18
Updated: 2024/03/01

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Iodoethane Chemical Properties,Usage,Production

Chemical Properties

Colorless to yellow liquid. Iodoethane is a stable chemical substance. It is incompatible with strong bases, magnesium, and strong oxidising agents and gets discoloured when exposed to light, moisture, and air.

Uses

A useful synthetic reagent for the introduction of ethyl groups

Uses

Iodoethane is an excellent ethylating agent used in organic synthesis to introduce an ethyl group into a compound. It reacts with magnesium to form the Grignard reagent, ethylmagnesium iodide which is used in organic synthesis. It is involved in the preparation of 1-ethyl-3-nitro-2-phenyl-indole and also serves as hydrogen radical promoter.

Definition

A colorless liquid alkyl halide made by reaction of ethanol with iodine in the presence of red phosphorus.

Definition

ChEBI: An iodoalkane that is ethane substituted by an iodo group.

Synthesis Reference(s)

The Journal of Organic Chemistry, 12, p. 133, 1947 DOI: 10.1021/jo01165a017

General Description

Iodoethane also known as ethyl iodide is an alkyl iodide. The interaction of iodoethane with Pt(111) surfaces has been analyzed by using thermal desorption and X-ray photoelectron spectroscopy. Its microwave spectrum has been recorded and studied. The dynamics of the gas phase photolysis of iodoethane have been studied using resonance Raman spectra. Its thermodynamic characteristics in the ideal state have been reported.

Hazard

Toxic by inhalation and skin absorption, narcotic in high concentration.

Purification Methods

Drying the iodide with P2O5 is unsatisfactory, and with CaCl2 it is incomplete. It is probably best to dry it with sodium wire and distil [Hammond et al. J Am Chem Soc 82 704 1960]. Exposure of ethyl iodide to light leads to rapid decomposition, with the liberation of iodine. Free iodine can be removed by shaking with several portions of dilute aqueous Na2S2O3 (until the colour is discharged), followed by washing with water, drying (with CaCl2, then sodium), and distilling. The distilled ethyl iodide is stored, over mercury, in a dark bottle away from direct sunlight. Other purification procedures include passage through a 60cm column of silica gel, followed by distillation, and treatment with elemental bromine, extraction of free halogen with Na2S2O3 solution, followed by washing with water, drying and distilling. Free iodine and HI have also been removed by direct distillation through a LeBel-Henninger column containing copper turnings. Purification by shaking with alkaline solutions, and storage over silver, are reported to be unsatisfactory. [Beilstein 1 IV 163.]

Iodoethane Preparation Products And Raw materials

Raw materials

Industrial ethanol White phosphorus Phosphorus

Preparation Products

1-BOC-4-ETHYL-4-PIPERIDINECARBOXYLIC ACID 5-ETHYL-2-FURALDEHYDE 2-Acetyl-3-ethylpyrazine Rhodamine 6G 1,2-Diethoxybenzene 2,5-DIETHOXYBENZALDEHYDE N-(4,6-DIMETHYLPYRIMIDIN-2-YL)-N-ETHYLBENZENE-1,4-DIAMINE CARBON TETRAIODIDE 3,5-DIBROMO-2-ETHOXYBENZALDEHYDE Cyclohexylethylether ETHYL 3-PHENYLGLYCIDATE Phenacetin 1-ETHYLPIPERAZIN-2-ONE 3-ETHOXY-1,2-PROPANEDIOL Oxolinic acid 2-Methylisonicotinic acid 2-Ethoxybenzoic acid Gallamine triethiodide

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View Lastest Price from Iodoethane manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Iodoethane 75-03-6
Price: US $0.10/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000 tons
Release date: 2020-01-08

Career Henan Chemical Co

Product: Iodoethane 1975-03-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 995
Supply Ability: 25kg
Release date: 2019-07-12

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IODOETHANE (STABILISED WITH SILVER) FOR

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Iodoethane contains copper as stabilizer, ReagentPlus(R), 99%

Iodoethane, 98%, stabilized

Iodoethane, Stabilized

Ethyl Iodide 〔Iodoethane〕

HYDRIODIC ETHER

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ETHYL IODIDE

IODOETHANE REAGENTPLUS(TM) 99%

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IODOETHANE, STAB.

EthylIodideForSysnthesis

EthylIodide,>98%

Iodoethane,98+%,stab.withcopper

Iodoethane,98+%

Iodoethane,99%

Iodoethane, stabilized with silver, pure, 98%

Ethyliodid

Ethyljodid

Iodethan

iodo-ethan

iodured’ethyle

Jodethan

Monoiodoethane

1-IODOETHANE

ENCH

Iodoethane(stabilizedwithCopperchip)&gt

Iodoethane ISO 9001：2015 REACH

Ethyl iodide for synthesis 250ML

Iodoethane, Extra Pure, SLR, Fisher Chemical

Travoprost Impurity 27

75-03-6

1975-3-6

1975-03-6

*75-3-6

1975-03-06

1975/3/6

27459

75036

C9H5l