2-Methyl-2-adamantanol
- Product Name
- 2-Methyl-2-adamantanol
- CAS No.
- 702-98-7
- Chemical Name
- 2-Methyl-2-adamantanol
- Synonyms
- NSC193482;ST5437305;323101_SIAL;AKOS BC-0511;ZINC01037087;SR-01000637601-1;Maybridge1_004158;RARECHEM AQ TC 1054;2-METHYL-2-ADAMANTOL;Methyl-2-adaMantanol
- CBNumber
- CB9147982
- Molecular Formula
- C11H18O
- Formula Weight
- 166.26
- MOL File
- 702-98-7.mol
2-Methyl-2-adamantanol Property
- Melting point:
- 214-218 °C
- Boiling point:
- 234.5°C (rough estimate)
- Density
- 0.8802 (rough estimate)
- refractive index
- 1.5000 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- form
- Crystalline Powder
- pka
- 14.99±0.20(Predicted)
- color
- White
- Water Solubility
- insoluble
- InChI
- InChI=1S/C11H18O/c1-11(12)9-3-7-2-8(5-9)6-10(11)4-7/h7-10,12H,2-6H2,1H3
- InChIKey
- JKOZWMQUOWYZAB-UHFFFAOYSA-N
- SMILES
- C12CC3CC(CC(C3)C1(C)O)C2
- CAS DataBase Reference
- 702-98-7(CAS DataBase Reference)
- NIST Chemistry Reference
- 2-Methyl-2-adamantanol(702-98-7)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 24/25-36-26
- WGK Germany
- 3
- HazardClass
- IRRITANT
- HS Code
- 29029090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 323101
- Product name
- 2-Methyl-2-adamantanol
- Purity
- 97%
- Packaging
- 5g
- Price
- $199
- Updated
- 2023/06/20
- Product number
- M1334
- Product name
- 2-Methyl-2-adamantanol
- Purity
- >99.0%(GC)
- Packaging
- 5g
- Price
- $108
- Updated
- 2025/07/31
- Product number
- M1334
- Product name
- 2-Methyl-2-adamantanol
- Purity
- >99.0%(GC)
- Packaging
- 25g
- Price
- $324
- Updated
- 2025/07/31
- Product number
- M341490
- Product name
- 2-Methyl-2-adamantanol
- Packaging
- 10g
- Price
- $265
- Updated
- 2021/12/16
- Product number
- M341490
- Product name
- 2-Methyl-2-adamantanol
- Packaging
- 1g
- Price
- $45
- Updated
- 2021/12/16
2-Methyl-2-adamantanol Chemical Properties,Usage,Production
Chemical Properties
white crystalline powder
Uses
2-Methyl-2-adamantanol is a chemical used in various research applications for the preparation of photoresist compositions.
Synthesis
700-58-3
917-54-4
702-98-7
Dissolve 2-adamantanone (1.50 g, 10 mmol) in ether under nitrogen protection and cool to 0°C. Methyl lithium solution (7.5 mL, 1.6 M in ether, 12 mmol) was added slowly and dropwise. The reaction mixture was continued to be stirred at 0 °C for 1 h, then brought to room temperature and stirred overnight. Upon completion of the reaction, the reaction was quenched by the addition of saturated ammonium chloride solution and extracted three times with ether. The organic phases were combined, dried over anhydrous magnesium sulfate and concentrated under reduced pressure. The crude product was purified by fast column chromatography (eluent: dichloromethane to 5% methanol/dichloromethane) to afford 2-methyl-2-adamantanol (56) as a white solid (1.58 g, 95% yield).1H-NMR (360 MHz, CDCl3) δ 2.20-2.16 (m, 2H), 1.89-1.75 (m, 6H), 1.68 ( br s, 4H), 1.57-1.54 (m, 2H), 1.48 (br s, 1H), 1.35 (s, 3H); 13C-NMR (90 MHz, CDCl3) δ 74.06, 39.30, 38.49, 35.33, 33.16, 27.73, 27.60, 27.22; ESI-MS: C11H18O(M+H)+ calculated value 167.3, measured value 167.3.
References
[1] Patent: WO2011/22191, 2011, A1. Location in patent: Page/Page column 34
[2] J. Gen. Chem. USSR (Engl. Transl.), 1987, vol. 57, p. 147 - 150
[3] Zhurnal Obshchei Khimii, 1987, vol. 57, # 1, p. 171 - 174
[4] Journal of the American Chemical Society, 1968, vol. 90, # 18, p. 4929 - 4939
[5] Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, 1981, vol. 37, p. 129 - 134
2-Methyl-2-adamantanol Preparation Products And Raw materials
Raw materials
Preparation Products
2-Methyl-2-adamantanol Suppliers
- Tel
- 320-37350700
- Fax
- +32 (0)37350701
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- Country
- Europe
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View Lastest Price from 2-Methyl-2-adamantanol manufacturers
- Product
- 2-Methyl-2-adamantanol 702-98-7
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.9%
- Supply Ability
- 100 Tons Min
- Release date
- 2025-09-17
- Product
- 2-Methyl-2-adamantanol 702-98-7
- Price
- US $5.00-0.50/KG
- Min. Order
- 1KG
- Purity
- 99% hplc
- Supply Ability
- 500TONS
- Release date
- 2025-05-30
- Product
- 2-Methyl-2-adamantanol 702-98-7
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99%+
- Supply Ability
- 100000kg per Month
- Release date
- 2024-03-04