N-Formylpiperidine

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N-Formylpiperidine

Product Name: N-Formylpiperidine
CAS No.: 2591-86-8
Chemical Name: N-Formylpiperidine
Synonyms: PIPERIDINE-1-CARBALDEHYDE;1-FORMYLPIPERIDINE;nfp;1-PIPERIDINECARBOXALDEHYDE;FORMYLPIPERIDINE;N-Formylpiperidin;1-FormyL;N-Formylpiperdine;1-formyl-piperidin;N-FORMYLPIPERIDINE
CBNumber: CB9149092
Molecular Formula: C6H11NO
Formula Weight: 113.16
MOL File: 2591-86-8.mol

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N-Formylpiperidine Property

Melting point:: -31 °C
Boiling point:: 222 °C(lit.)
Density: 1.019 g/mL at 25 °C(lit.)
vapor pressure: 0.1 mm Hg ( 25 °C)
refractive index: n20/D 1.484(lit.)
Flash point:: 197 °F
storage temp.: Store below +30°C.
form: Liquid
pka: -0.44±0.20(Predicted)
Specific Gravity: 1.02
color: Clear colorless to slightly yellow
Water Solubility: freely soluble
BRN: 107697
Dielectric constant: 26.149999999999999
CAS DataBase Reference: 2591-86-8(CAS DataBase Reference)
NIST Chemistry Reference: 1-Piperidinecarboxaldehyde(2591-86-8)
EPA Substance Registry System: N-Formylpiperidine (2591-86-8)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 21/22-36/37/38
Safety Statements: 26-36/37-36
RIDADR: UN 2810 6.1/PG 3
WGK Germany: 3
RTECS: TN0380000
TSCA: Yes
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29333999

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: F17407
Product name: 1-Formylpiperidine
Purity: 99%
Packaging: 100g
Price: $70.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: F17407
Product name: 1-Formylpiperidine
Purity: 99%
Packaging: 500g
Price: $167.4
Updated: 2024/03/01

TCI Chemical

Product number: F0234
Product name: 1-Formylpiperidine
Purity: >98.0%(GC)
Packaging: 25mL
Price: $26
Updated: 2024/03/01

TCI Chemical

Product number: F0234
Product name: 1-Formylpiperidine
Purity: >98.0%(GC)
Packaging: 100mL
Price: $45
Updated: 2024/03/01

Alfa Aesar

Product number: B23452
Product name: 1-Formylpiperidine, 99%
Packaging: 50g
Price: $42.65
Updated: 2024/03/01

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N-Formylpiperidine Chemical Properties,Usage,Production

Description

This simple piperidine base has recently been discovered in the oxygenated fraction from Piper nigrum. The structure has been elucidated from chemical and spectroscopic data.

Chemical Properties

CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID

Uses

Solvent for polar and nonpolar compounds, as well as many high polymers; gas absorption; plastics modifiers.

Uses

Reactant for:

Direct amidation of azoles with formamides via metal-free C-H activation in the presence of tert-butyl perbenzoate
Vilsmeier-type reactions of pyrazoles with amides in the presence of phosphorous oxychloride
CO-free aminocarbonylation of N-substituted formamides with aryl iodides/bromides catalyzed by palladium acetate and Xantphos for synthesis of arylamides
Synthesis of alternating copolymers for organic photovoltaic applications
One-pot double functionalization of π-deficient heterocyclic lithium reagents
Synthesis of thermally stable piezofluorochromic aggregation-induced emission compounds

Definition

ChEBI: 1-Piperidinecarboxaldehyde is a member of piperidines.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 42, p. 1655, 1994 DOI: 10.1248/cpb.42.1655
Synthetic Communications, 20, p. 447, 1990 DOI: 10.1080/00397919008052787

References

Debrauwere, Verzale, Bull. Soc. Chim. Belg., 84, 167 (1975)

N-Formylpiperidine Preparation Products And Raw materials

Raw materials

Preparation Products

TERT-BUTYL 4-FORMYLPYRIDIN-3-YLCARBAMATE 5-BROMO-2-FLUOROPYRIDINE-3-CARBALDEHYDE

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View Lastest Price from N-Formylpiperidine manufacturers

Henan Fengda Chemical Co., Ltd

Product: Formylpiperidine 2591-86-8
Price: US $122.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-01-11

Shanghai CRM New Material Technology Co., LTD

Product: Formylpiperidine 2591-86-8
Price: US $10.00-15.00/g
Min. Order: 10g
Purity: 99%
Supply Ability: 10t
Release date: 2022-09-22

Qiuxian Baitai New Material Co., LTD

Product: n-formylpiperidine 2591-86-8
Price: US $73.00/g
Min. Order: 100g
Purity: 99%
Supply Ability: 500ton/Month
Release date: 2021-11-05

2591-86-8, N-FormylpiperidineRelated Search:

Triacetonediamine Haloperidol Formaldehyde N-Formylmorpholine DROPERIDOL TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN 4-Benzyloxycarbonylaminopiperidine Hydrochloride Hexahydroisonicotinamide DL-Pipecolinic acid Piperazine-2-carboxylic acid dihydrochloride 3-CBZ-AMINOPIPERIDINE HCL tert-Butyl 1-piperazinecarboxylate PIPERIDIN-3-ONE HYDROCHLORIDE Piperidine Diphenoxylate N-Carbethoxy-4-piperidone ETHYL 1-PIPERIDINEGLYOXYLATE 2-METHOXY-1-FORMYLPIPERIDINE,N-Methoxy-1-formylpiperidine

1-formyl-piperidin

1-Piperidinecarbaldehyde

N-Formylpiperdine

N-Formylpiperidin

1-Formylpiperidine,99%

N-Carbaldehyde piperidine

N-Formylpiperidine for synthesis

N-ForMylpiperidine, 99% 250ML

1-forMylpiperidin-1-iuM-1-yl

N-Piperidinecarboxaldehyde

1-PIPERIDINECARBOXALDEHYDE, N-PIPERIDINECARBOXALDEHYDE

1-(2-ISOPROPYL PHENYL)PIPERAZINE

N-FORMYL PIPERIDINE PIPERIDINE-1-CARBALDEHYDE

nfp

1-PIPERIDINECARBOXALDEHYDE

1-FORMYLPIPERIDINE

TIMTEC-BB SBB004316

FORMYLPIPERIDINE

piperidine-N-carbaldehyde

N-FORMYLPIPERIDINE 99+%

Piperidine, 1-formyl-

Piperidinoformamide

PIPERIDINE-1-CARBOXALDEHYDE

PIPERIDINE-1-CARBALDEHYDE

N'-FORMYL PIPERIDINE

N-FORMYLPIPERIDINE

1-FormyL

1-Formylpiperidine&gt

1-Piperidinecarboxaldehyde (6CI, 7CI, 8CI, 9CI, ACI)

2591-86-8

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