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Methyl-5-norbornene-2,3-dicarboxylic anhydride

Product Name
Methyl-5-norbornene-2,3-dicarboxylic anhydride
CAS No.
25134-21-8
Chemical Name
Methyl-5-norbornene-2,3-dicarboxylic anhydride
Synonyms
MNA;NMA;XMNA;mea610;MEA 610;tk10524;epicurenma;Epicure NMA;kayahardmcd;Kayahard MCD
CBNumber
CB9163814
Molecular Formula
C10H10O3
Formula Weight
178.18
MOL File
25134-21-8.mol
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Methyl-5-norbornene-2,3-dicarboxylic anhydride Property

Boiling point:
140°C (10 mmHg)
Density 
1.232 g/mL at 25 °C(lit.)
vapor density 
6.1 (20 °C, vs air)
vapor pressure 
5 mm Hg ( 120 °C)
refractive index 
n20/D 1.506(lit.)
Flash point:
>230 °F
storage temp. 
room temp
solubility 
Miscible with acetone, benzene, naphtha and xylene.
pka
4.42[at 20 ℃]
form 
Oily Liquid
color 
Clear light yellow
Water Solubility 
REACTS
Sensitive 
Moisture Sensitive
BRN 
162395
LogP
-4.01 at 20℃
CAS DataBase Reference
25134-21-8(CAS DataBase Reference)
NIST Chemistry Reference
4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-(25134-21-8)
EPA Substance Registry System
4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aR,4S,7R,7aS)-rel- (25134-21-8)
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Safety

Hazard Codes 
Xn,C
Risk Statements 
22-36/37/38-42-34
Safety Statements 
39-45-36/37/39-26
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
RTECS 
RB9100000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29172000
Hazardous Substances Data
25134-21-8(Hazardous Substances Data)
Toxicity
LD50 oral in rat: 914mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
45347
Product name
Epoxy embedding medium, hardener MNA
Purity
≥95.0%
Packaging
250ML
Price
$120
Updated
2024/03/01
Sigma-Aldrich
Product number
45347
Product name
Epoxy embedding medium, hardener MNA
Purity
≥95.0%
Packaging
1L
Price
$189
Updated
2024/03/01
Sigma-Aldrich
Product number
235431
Product name
Methyl-5-norbornene-2,3-dicarboxylic anhydride
Purity
90%
Packaging
250g
Price
$34.32
Updated
2024/03/01
Sigma-Aldrich
Product number
235431
Product name
Methyl-5-norbornene-2,3-dicarboxylic anhydride
Purity
90%
Packaging
1kg
Price
$207
Updated
2024/03/01
TCI Chemical
Product number
M0690
Product name
Methyl-5-norbornene-2,3-dicarboxylic Anhydride (mixture of isomers)
Purity
>80.0%(GC)
Packaging
25g
Price
$27
Updated
2024/03/01
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Methyl-5-norbornene-2,3-dicarboxylic anhydride Chemical Properties,Usage,Production

Chemical Properties

clear light yellow oily liquid

Uses

Methyl-5-norbornene-2,3-dicarboxylic anhydride is used as a curing agent in epoxy resins and in the preparation of vertically aligned and penetrated carbon nanotube/polymer film. It serves as an intermediate in polyesters, alkyd resins and plasticizers. It is also used in electrical laminating and filament-winding. Further, it is used in the preparation of methyl nadimides endcapped resins based on tris(3-aminophenyl)phosphine oxide. It is utilized in the flame retarding treatment.

General Description

additional information see 45359 Epoxy Embedding Medium kit

Flammability and Explosibility

Non flammable

Purification Methods

Purify the anhydride by thin layer chromatography on Al2O3 (previously boiled in EtOAc) and eluted with hexane/*C6H6 (1:2) then recrystallise it from *C6H6/hexane. The free acid has m 118.5-119.5o. [Miranov et al. Tetrahedron 19 1939 1963, Beilstein 17/11 V 199.]

Methyl-5-norbornene-2,3-dicarboxylic anhydride Preparation Products And Raw materials

Raw materials

2-methylcyclopentenone p-Toluenesulfonic acid Hexane Maleic anhydride Dicyclopentadiene Diethyl ether Benzene Lithium Aluminum Hydride METHYLCYCLOPENTADIENE DIMER

Preparation Products

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Methyl-5-norbornene-2,3-dicarboxylic anhydride Suppliers

Americas 1 Belgium 2 China 261 Europe 1 France 2 Germany 4 India 3 Japan 4 Slovakia 1 South Korea 1 Switzerland 1 United Kingdom 3 United States 32 Global 316
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
Hitachi Chemical Co.,Ltd.
Tel
--
Fax
--
Email
kojinjyoho@hitachi-chem.co.jp
Country
Japan
ProdList
21
Advantage
77
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
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View Lastest Price from Methyl-5-norbornene-2,3-dicarboxylic anhydride manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Methyl-5-norbornene-2,3-dicarboxylic anhydride 25134-21-8
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-21
Hebei Chuanghai Biotechnology Co,.LTD
Product
Methyl-5-norbornene-2,3-dicarboxylic anhydride 25134-21-8
Price
US $100.00-50.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-20
Shaanxi Dideu Medichem Co. Ltd
Product
Methyl-5-norbornene-2,3-dicarboxylic anhydride 25134-21-8
Price
US $0.10/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000Tons
Release date
2024-08-05

25134-21-8, Methyl-5-norbornene-2,3-dicarboxylic anhydrideRelated Search:

Himic anhydride N,N-Dimethylformamide Propionic anhydride Trimellitic Anhydride Methacrylic anhydride CIS-BUTENEDIOIC ANHYDRIDE 3,4,5,6-Tetrahydrophthalic anhydride Sodium carboxymethyl cellulose Phthalic anhydride Glutaric anhydride 4-Methylphthalic anhydride Erythromycin Estolate Methyl tetrahydrophthalic anhydride Methanesulfonic anhydride Chromium(VI) oxide Methanol cis-1,2,3,6-Tetrahydrophthalic anhydride Succinic anhydride Methyl Nadic Anhydride

  • NADIC METHYL ANHYDRIDE
  • NADIC(R) METHYL ANHYDRIDE
  • NADIC(TM) METHYL ANHYDRIDE
  • NMA
  • MNA
  • 3-dione,3a,4,7,7a-tetrahydromethyl-7-methanoisobenzofuran-1
  • 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aalpha,4alpha,7alpha,7aalpha)-
  • 4,7-methanoisobenzofuran-1,3-dione,3a,4,7,7a-tetrahydromethyl-,(3aalpha,4al
  • 5-Norbornene-2,3-dicarboxylic anhydride, methyl-
  • 7alpha,7aalpha)-ph
  • 7-Methanoisobenzofuran-1,3-dione,3a,4,7,7a-tetrahydromethyl-4
  • endo-Methylenemethyltetrahydrophthalic anhydride
  • endo-methylenemethyltetrahydrophthalicanhydride
  • Epicure NMA
  • epicurenma
  • hardenerhy906
  • Kayahard MCD
  • kayahardmcd
  • MEA 610
  • mea610
  • Methyl-3,6-endomethylene-1,2,3,6-tetrahydrophthalicanhydride
  • methyl-5-norbornene-2,3-dicarboxylicanhydride,mixtureofisomers
  • methyl-5-norbornene-3-dicarboxylicanhydride
  • Methylbicyclo(2.2.1)heptene-2,3-dicarboxylic anhydride isomers
  • methylbicyclo(2.2.1)heptene-2,3-dicarboxylicanhydride
  • methylbicyclo(2.2.1)heptene-2,3-dicarboxylicanhydrideisomers
  • Methylbicyclo[2.2.1]Heptene-2,3-dicarboxylic anhydride
  • Methylendic anhydride
  • Methylbicyclo[2.2.1]heptene-2,3-carboxylic anhydride
  • 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aR,4S,7R,7aS)-rel-
  • Methyl-5-norbornene-2,3-dicarboxylic anhydride, mixture of isomers, tech
  • maleic anhydride/ methylcyclopentadiene adduct
  • Epon(R) MNA substitute, Methyl nadic anhydride, Methyl-5-norbornene-2,3-dicarboxylic anhydride, Methylnorbornene-2,3-dicarboxylic acid anhydride, MNA
  • ,7-methanoisobenzofuran-1,3-dione,3a,4,7,7a-tetrahydromethyl-
  • METHYL NADIC ANHYDRIDE (MNA)
  • NADIC METHYL ANHYDRIDE (MNA: NMA)
  • 3a,4,7,7a-tetrahydromethyl-4,7-Methanoisobenzofuran-1,3-dione
  • Nadic methyl anhydride (MNA)
  • Methyl-5-norbornene-2,3-dicarboxylic anhydride, 95%, mixture of isomers
  • Kayahard NMA
  • 3a,4,7,7a-tetrahydromethyl-4,7-Methanoisobenzofuran-1,3-d
  • 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aα,4α,7α,7aα)-
  • Methyl-5-norbornene-2,3-dicarboxylic anhydride ,95%
  • Methyl-5-norbornene-2,3-dicarboxylic anhydride Ⅲ
  • Modified methyl-5-norbornene-2,3-dicarboxylic anhydride Ⅱ
  • Epoxy embedding medium, hardener MNA,Epon MNA substitute, MNA, Methyl nadic anhydride, Methyl-5-norbornene-2,3-dicarboxylic anhydride, Methylnorbornene-2,3-dicarboxylic acid anhydride
  • Methyl-5-norbornene-2,3-dicarboxylic anhydride, Mixture of isoMers, 95% 250GR
  • Methy nadic Anhydride
  • methylendicanhydride
  • Methylnadic acid anhydride
  • tk10524
  • XMNA
  • 1,2,3,6-tetrahydromethyl-3,6-methanophthalic anhydride
  • Nadic Methyl Anhydride (NMA)
  • Methyl Anhydride
  • METHYLNORBORNENE-2,3-DICARBOXYLIC ANHY-D RIDE, MIXT. OF ISOM
  • METHYLNORBORNENE-2,3-DICARBOXYLIC ACID ANHYDRIDE
  • METHYLNORBORNENE-2,3-DICARBOXYLIC ANHYDRIDE