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Triethylenediamine

Product Name
Triethylenediamine
CAS No.
280-57-9
Chemical Name
Triethylenediamine
Synonyms
DABCO;1,4-DIAZABICYCLO[2.2.2]OCTANE;teda;TED;BACO;Diazabicyclooctane;1,4-diazabicyclooctane;1,4-diazobicyclo[2.2.2]octane;Bicyclo[2.2.2]-1,4-diazaoctane;Dabco 33LV
CBNumber
CB9164730
Molecular Formula
C6H12N2
Formula Weight
112.17
MOL File
280-57-9.mol
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Triethylenediamine Property

Melting point:
156-159 °C(lit.)
Boiling point:
174 °C
Density 
1.02 g/mL
vapor pressure 
2.9 mm Hg ( 50 °C)
refractive index 
n20/D 1.4634(lit.)
Flash point:
198 °F
storage temp. 
Store below +30°C.
solubility 
400g/l
form 
Hygroscopic Crystals
pka
3.0, 8.7(at 25℃)
color 
White to pale yellow
Water Solubility 
46 g/100 mL (26 ºC)
Sensitive 
Hygroscopic
Merck 
14,9669
BRN 
103618
Stability:
Stable, but very hygroscopic. Incompatible with strong oxidizing agents, strong acids. Highly flammable.
LogP
-0.49 at 20℃
CAS DataBase Reference
280-57-9(CAS DataBase Reference)
NIST Chemistry Reference
Triethylenediamine(280-57-9)
EPA Substance Registry System
1,4-Diazabicyclo[2.2.2]octane (280-57-9)
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Safety

Hazard Codes 
Xn,F
Risk Statements 
22-36/37/38-52/53-41-36/38-11
Safety Statements 
26-60-37/39-3-16-36/37-61
RIDADR 
UN 1325 4.1/PG 2
WGK Germany 
1
RTECS 
HM0354200
F 
3
Autoignition Temperature
350 °C
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29335920
Hazardous Substances Data
280-57-9(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 700 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.03456
Product name
1,4-Diazabicyclo[2.2.2]octane
Purity
for synthesis
Packaging
100g
Price
$75.7
Updated
2024/03/01
Sigma-Aldrich
Product number
8.03456
Product name
1,4-Diazabicyclo[2.2.2]octane
Purity
for synthesis
Packaging
250g
Price
$148
Updated
2024/03/01
Sigma-Aldrich
Product number
8.03456
Product name
1,4-Diazabicyclo[2.2.2]octane
Purity
for synthesis
Packaging
1kg
Price
$470
Updated
2024/03/01
Sigma-Aldrich
Product number
290734
Product name
Dabco? 33-LV
Packaging
100ml
Price
$83.6
Updated
2024/03/01
Sigma-Aldrich
Product number
290734
Product name
Dabco? 33-LV
Packaging
500ml
Price
$278
Updated
2024/03/01
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Triethylenediamine Chemical Properties,Usage,Production

Chemical Properties

Triethylenediamine also known as DABCO or TEDA, is a highly symmetrical molecule with a cage structure. The colorless extremely hygroscopic crystals is a highly nucleophilic tertiary amine base, which is used as a catalyst and reagent in polymerization and organic synthesis.

Uses

An anti-fade reagent shown to scavenge free-radicals due to flurochrome excitation.

Uses

1,4-Diazabicyclo[2.2.2]octane is used as polyurethane catalyst, Balis-Hillman reaction catalyst complexing ligand and lewis base. It finds use in dye lasers and in mounting samples for fluorescence microscopy and as anti-fade reagent shown to scavenge free radicals due to flurochrome excitation of fluorochromes. Further, it is an oxidation and polymerization catalyst.

Definition

ChEBI: Triethylenediamine is an organic heterobicylic compound that is piperazine with an ethane-1,2-diyl group forming a bridge between N1 and N4. It is typically used as a catalyst in polymerization reactions. It has a role as a catalyst, a reagent and an antioxidant. It is a bridged compound, a tertiary amino compound, a saturated organic heterobicyclic parent and a diamine.

Preparation

Triethylenediamine can be produced from ethylenediamine or ethanolamine, diethanolamine, or diethylenetriamine with a variety of different catalysts.

Reactions

Triethylenediamine reacts virtually quantitatively with bromine to give a 1/1 adduct. With alkyl halides it forms quaternary salts, even in nonpolar solvents. Apart from its highly nucleophilic nature, triethylenediamine exhibits catalytic activity in base-catalyzed reactions.

General Description

Dabco?33-LV (Db) is a gelling catalyst and a bidentate ligand that forms a self-assembled monolayer (SAM) on a variety of substrates. It functionalizes the surface and immobilizes the surface atoms.

Hazard

Skin irritant.

Flammability and Explosibility

Flammable

Purification Methods

DABCO crystallises from 95% EtOH, pet ether or MeOH/diethyl ether (1:1). Dry it under vacuum over CaCl2 and BaO. It can be sublimed in vacuo, and readily at room temperature. It has also been purified by removal of water during azeotropic distillation of a *benzene solution. It is then recrystallised twice from anhydrous diethyl ether under argon, and stored under argon [Blackstock et al. J Org Chem 52 1451 1987]. [Beilstein 23/3 V 487.]

Triethylenediamine Preparation Products And Raw materials

Raw materials

Ethylenediamine PIPERAZINE HEXAHYDRATE Diethylenetriamine CHLOROETHANE Polyethylene-polyamines Triethylenetetramine 1,4,7,10,13-Pentaazatridecane

Preparation Products

Dehydroacetic acid (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL ETHYL 2-(BROMOMETHYL)ACRYLATE 3-Fluoropyridine-2-carboxylic acid (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 5-Bromopyrimidine-2-carbonitrile 1.1'-Binaphthyl-2.2'-diphemyl phosphine (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl Tribenuron methyl 2-Chloro-3-fluoropyridine-4-carboxylic acid 5-BROMOPYRIMIDINE-2-CARBOXYLIC ACID (R)-(+)-TolBINAP
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Triethylenediamine Suppliers

Americas 1 Austria 1 Belgium 3 Canada 3 China 497 Europe 5 France 4 Germany 15 India 35 Japan 7 New Zealand 1 Poland 1 Russia 1 Slovakia 1 South Korea 1 Sweden 1 Switzerland 2 The Netherlands 1 Ukraine 1 United Arab Emirates 1 United Kingdom 13 United States 58 Global 653
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View Lastest Price from Triethylenediamine manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Triethylenediamine Teda 280-57-9
Price
US $120.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-09
Hebei Weibang Biotechnology Co., Ltd
Product
Triethylenediamine/TEDA 280-57-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-10-29
Hebei Yanxi Chemical Co., Ltd.
Product
Triethylenediamine 280-57-9
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20tons
Release date
2023-09-14

280-57-9, TriethylenediamineRelated Search:

Dicyclopentadiene Diethylenetriaminepentaacetic acid N-OCTANE Hexamethylenediamine 2-(2-Aminoethylamino)ethanol Zidovudine Triethylenetetramine N,N-Diisopropylethylamine Ethyl Azidoacetate Diphenylphosphoryl azide Methoxydiethylborane Triisopropanolamine TRIFLUOROACETALDEHYDE HYDRATE Triethylene glycol diacrylate Triethylenethiophosphoramide Triethylsilane Triethanolamine Diethylaminoethanol

  • 1,4-Diaza[2.2.2]bicyclooctane
  • 1,4-diazabicyclooctane
  • 1,4-Diazobicyclo(2.2.2)octane
  • 1,4-diazobicyclo[2.2.2]octane
  • 1,4-Ethylenepiperazine
  • Bicyclo(2,2,2)-1,4-diazaoctane
  • o[2.2.2]octane
  • BACO
  • Dabco(rg~TEDA~Triethylenediamine
  • Diazabicyclooctane
  • TRIETHLENE DIAMINE
  • Triethylenediamine (DABCO)
  • 1,4-DIAZABICYCLO(2.2.2)OCTAN
  • 1,4-Diazabicyclo(2.2.2)octane, 97+%
  • 1,4-diazabicyclo[2.2.2]octane solution
  • teda, dabco
  • TRIETHYLENEDIAMINE=1,4-DIAZABICYCLO(2,2,2)OCTANE
  • 1,4-Diazabicyclooctan
  • 1,4-Diazabicyclo2.2.2üoctane
  • 1,4-Diazabicyclo2.2.2üoctane, 98+%
  • DABCO(R), TED, Triethylenediamine
  • DABCO(R) 33-LV
  • N,N'-2-hydroxyethyl piperazine
  • 1,4-Diazabicyclo[2.2.2]octane, 97% 100GR
  • Dabco 33-LV,1,4-Diazabicyclo[2.2.2]octane solution
  • 1,4-Diazabicyclo[2.2.2]octane{DABCO}
  • bicyclo(2.2.2)-1,4-diazaoctane
  • Bicyclo[2.2.2]-1,4-diazaoctane
  • Bicyclo[2.2.2]octane, 1,4-diaza-
  • D 33LV
  • d33lv
  • Dabco 33LV
  • Dabco crystalline
  • Dabco R-8020
  • Dabco S-25
  • dabco33lv
  • dabcocrystal
  • dabcoeg
  • dabcor-8020
  • dabcos-25
  • n,n’-endo-ethylenepiperazine
  • N,N'-endo-Ethylenepiperazine
  • teda
  • TEDA-L33
  • Tegoamin 33
  • Texacat TD-33
  • texacattd100
  • thancattd33
  • triethylene-diamine,hexahydrate
  • LUPRAGEN(R) N 201
  • LUPRAGEN(R) N 202
  • LUPRAGEN(R) N 203
  • DABCO(TM)
  • DABCO(TM) 33-LV
  • DABCO
  • AURORA 15187
  • 1,4-DIAZABICYCLO[2.2.2]OCTANE
  • 2,2'-Diazabicyclo[2.2.2]octane