2-IODOBENZALDEHYDE
- Product Name
- 2-IODOBENZALDEHYDE
- CAS No.
- 26260-02-6
- Chemical Name
- 2-IODOBENZALDEHYDE
- Synonyms
- o-Iodobenzaldehyde;2-IODOBENZALDEHYDE;Benzaldehyde, 2-iodo-;2-Iodobenzaldehyde 97%;2-Iodobenzaldehyde,98%;2-Iodobenzaldehyde o-Iodobenzaldehyde
- CBNumber
- CB9193914
- Molecular Formula
- C7H5IO
- Formula Weight
- 232.02
- MOL File
- 26260-02-6.mol
2-IODOBENZALDEHYDE Property
- Melting point:
- 36-39 °C (lit.)
- Boiling point:
- 129 °C (14 mmHg)
- Density
- 1.8576 (estimate)
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- solubility
- soluble in Methanol
- form
- Low Melting Crystalline Mass or Powder
- color
- White to light beige
- Sensitive
- Light Sensitive
- BRN
- 1927296
- InChI
- InChI=1S/C7H5IO/c8-7-4-2-1-3-6(7)5-9/h1-5H
- InChIKey
- WWKKTHALZAYYAI-UHFFFAOYSA-N
- SMILES
- C(=O)C1=CC=CC=C1I
- CAS DataBase Reference
- 26260-02-6(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-37/39
- WGK Germany
- 3
- HazardClass
- IRRITANT, AIR SENSITIVE, KEEP COLD
- HS Code
- 29130000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 550779
- Product name
- 2-Iodobenzaldehyde
- Purity
- 97%
- Packaging
- 1g
- Price
- $121.8
- Updated
- 2025/07/31
- Product number
- I0610
- Product name
- 2-Iodobenzaldehyde
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $95
- Updated
- 2025/07/31
- Product number
- I0610
- Product name
- 2-Iodobenzaldehyde
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $282
- Updated
- 2025/07/31
- Product number
- I689000
- Product name
- 2-Iodo-benzaldehyde
- Packaging
- 2.5g
- Price
- $120
- Updated
- 2021/12/16
- Product number
- 007490
- Product name
- 2-Iodobenzaldehyde
- Purity
- 98%
- Packaging
- 1g
- Price
- $28
- Updated
- 2021/12/16
2-IODOBENZALDEHYDE Chemical Properties,Usage,Production
Chemical Properties
white to light beige low melting crystalline
Uses
2-Iodo-benzaldehyde is a very useful synthetic intermediate. It is halogenated Benzaldehyde (B119740) which is mainly used as a precursor to other organic compounds, such as pharmaceuticals, and plastic additives.
Uses
2-Iodobenzaldehyde may be used as a reactant in the synthesis of the following heterocycles:
- 2,3-diaryl-1-indenones
- indolo[1,2-a]quinazolines
- Baylis-Hillman (BH) adducts
- 5-phenylindazolo[3,2-b]quinazolin-7(5H)-one
- 4-(3-iodophenyl)-2,2:6,2-terpyridine
- fluoren-9-one
- 2-formyl-3′-methoxybiphenyl
General Description
2-Iodobenzaldehyde (o-iodobenzaldehyde) is a 2-halobenzaldehyde derivative. Its crystals belong to the orthorhombic crystal system and P212121 space group.
Synthesis
40138-16-7
26260-02-6
General procedure for the synthesis of 2-iodobenzaldehyde from 2-formylphenylboronic acid: 2-formylphenylboronic acid (0.067 g, 0.4 mmol), copper powder (0.0052 g, 0.08 mmol), (CF3)2CFI (0.178 g, 0.6 mmol) and DMF (2 mL) were added to a closed tube with a rubber stopper. The reaction mixture was stirred at room temperature for 24 hours. Upon completion of the reaction, the resulting suspension was poured into water and extracted with ethyl acetate. The organic layers were combined, dried with anhydrous Na2SO4 and concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography using petroleum ether/ethyl acetate (20:1, v/v) as eluent to give 0.086 g of 2-iodobenzaldehyde as a light yellow solid (0.35 mmol, 87% yield).
References
[1] Journal of Fluorine Chemistry, 2016, vol. 189, p. 59 - 67
2-IODOBENZALDEHYDE Preparation Products And Raw materials
Raw materials
Preparation Products
2-IODOBENZALDEHYDE Suppliers
- Tel
- --
- Fax
- --
- mduris@georganics.sk
- Country
- Slovakia
- ProdList
- 246
- Advantage
- 58
- Tel
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- Fax
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- georganics@nextra.sk
- Country
- Slovakia
- ProdList
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- Advantage
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View Lastest Price from 2-IODOBENZALDEHYDE manufacturers
- Product
- 2-Iodobenzaldehyde 26260-02-6
- Price
- US $0.00-0.00/g
- Min. Order
- 10mg
- Purity
- 99%HPLC
- Supply Ability
- 2000tons
- Release date
- 2020-01-15
- Product
- 2-IODOBENZALDEHYDE 26260-02-6
- Price
- US $6.60/KG
- Min. Order
- 1KG
- Purity
- 97%-99%
- Supply Ability
- 1kg -1000kg
- Release date
- 2020-01-02