ChemicalBook > CAS DataBase List > 2,3,4,4'-Tetrahydroxybenzophenone

2,3,4,4'-Tetrahydroxybenzophenone

Product Name
2,3,4,4'-Tetrahydroxybenzophenone
CAS No.
31127-54-5
Chemical Name
2,3,4,4'-Tetrahydroxybenzophenone
Synonyms
4HBP;2,3,4,4'2,3,4,4'-THBP;4'-Tetrahydroxybenzophenone;3,4,4'-Tetrahydroxybenzophenone;2,3,4,4-TETRAHYDROXYBENZOPHENONE;2,3,4,4'-Tetrehydroxybenzophenone;2,3,4,4'-Tetrahydroxybenzophenone;2,3,4,4'-Tetraanhydroxybenzophenone;2,3,4,4-TETRAHYDROXYBENZOPHENONE 98%
CBNumber
CB9195392
Molecular Formula
C13H10O5
Formula Weight
246.22
MOL File
31127-54-5.mol
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2,3,4,4'-Tetrahydroxybenzophenone Property

Melting point:
199-204°C
Boiling point:
519.0±50.0 °C(Predicted)
Density 
1.526±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
pka
7.38±0.40(Predicted)
color 
Light yellow to Amber to Dark green
Water Solubility 
15.07g/L(24.99 ºC)
InChI
InChI=1S/C13H10O5/c14-8-3-1-7(2-4-8)11(16)9-5-6-10(15)13(18)12(9)17/h1-6,14-15,17-18H
InChIKey
ZRDYULMDEGRWRC-UHFFFAOYSA-N
SMILES
C(C1=CC=C(O)C=C1)(C1=CC=C(O)C(O)=C1O)=O
CAS DataBase Reference
31127-54-5(CAS DataBase Reference)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HS Code 
2914500090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T1594
Product name
2,3,4,4'-Tetrahydroxybenzophenone
Purity
>98.0%(T)
Packaging
25g
Price
$50
Updated
2025/07/31
TRC
Product number
T795543
Product name
2,3,4,4''-Tetrahydroxybenzophenone
Packaging
500mg
Price
$60
Updated
2021/12/16
TRC
Product number
T795543
Product name
2,3,4,4''-Tetrahydroxybenzophenone
Packaging
250mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
2620-1-55
Product name
2,3,4,4'-Tetrahydroxybenzophenone
Purity
98%
Packaging
100g
Price
$149
Updated
2021/12/16
AK Scientific
Product number
F594
Product name
2,3,4,4'-Tetrahydroxybenzophenone
Packaging
100g
Price
$301
Updated
2021/12/16
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2,3,4,4'-Tetrahydroxybenzophenone Chemical Properties,Usage,Production

Chemical Properties

Yellow powder

Uses

2,3,4,4'-Tetrahydroxybenzophenone can be used for positive resist composition.

Preparation

Preparation by benzoylation of pyrogallol with p-hydroxybenzoic acid in the presence of Amberlyst-15 in refluxing toluene for 21 h under azeotropical removal of water (86%).

Synthesis

87-66-1

99-96-7

31127-54-5

General procedure for the synthesis of (4-hydroxyphenyl)(2,3,4-trihydroxyphenyl)methanone from o-hydroxybenzenetriol and p-hydroxybenzoic acid: 0.11 moles of p-hydroxybenzoic acid and 0.1 moles of pyrophosphoric acid as an acylating agent as well as 0.015 moles of concentrated sulfuric acid were added in a reactor and mixed well. An inert gas was passed for 10 minutes to remove air. After increasing the system temperature to 70-80°C, the reactor was closed, the temperature was adjusted to 110-130°C, the pressure was maintained at 0.1-5 MPa and the reaction was carried out for 3 hours. Upon completion of the reaction, the reaction mixture was cooled to 50-60 °C and held at this temperature for 1.5 hours. Subsequently, 200 ml of 20% ethanol solution was added and crystallized at 0-5°C. The crystals were collected by filtration and dried to give the target product (4-hydroxyphenyl)(2,3,4-trihydroxyphenyl)methanone. The molar yield of this step was 78.16% and the purity was ≥98.5% by HPLC.

References

[1] Patent: CN106349036, 2017, A. Location in patent: Paragraph 0032-0037
[2] Patent: CN106365961, 2017, A. Location in patent: Paragraph 0030; 0031; 0032; 0033; 0034; 0035
[3] Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 2, p. 482
[4] Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 2, p. 483
[5] Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 2, p. 483

2,3,4,4'-Tetrahydroxybenzophenone Preparation Products And Raw materials

Raw materials

Preparation Products

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2,3,4,4'-Tetrahydroxybenzophenone Suppliers

Aladdin Scientific
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View Lastest Price from 2,3,4,4'-Tetrahydroxybenzophenone manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
2,3,4,4'-Tetrahydroxybenzophenone 31127-54-5
Price
US $2.20-8.80/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons
Release date
2025-07-08
WUHAN FORTUNA CHEMICAL CO., LTD
Product
2,3,4,4'-Tetrahydroxybenzophenone 31127-54-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-25
Henan Aochuang Chemical Co.,Ltd.
Product
2,3,4,4'-Tetrahydroxybenzophenone 31127-54-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-16

31127-54-5, 2,3,4,4'-Tetrahydroxybenzophenone Related Search:


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