3-Methyl-4-nitropyridine N-Oxide
- Product Name
- 3-Methyl-4-nitropyridine N-Oxide
- CAS No.
- 1074-98-2
- Chemical Name
- 3-Methyl-4-nitropyridine N-Oxide
- Synonyms
- 3-Methyl-4-nitropyri;3-Methyl-4-nitro-1$l^{5;-4-nitropyridine N-Oxide;4-NITRO-3-PICOLINE N-OXIDE;4-Nitro-B-picoline N-oxide;4-Nitro-3-picoline 1-oxide;3-Picoline, 4-nitro-, 1-oxide;4-Nitro-beta-picoline N-oxide;4-Nitro-3-picoline-N-oxide 99%;3-Methyl-4-nitropyridin-1-oxid
- CBNumber
- CB9205071
- Molecular Formula
- C6H6N2O3
- Formula Weight
- 154.12
- MOL File
- 1074-98-2.mol
3-Methyl-4-nitropyridine N-Oxide Property
- Melting point:
- 135-139 °C
- Boiling point:
- 277.46°C (rough estimate)
- Density
- 1.4564 (rough estimate)
- refractive index
- 1.5100 (estimate)
- storage temp.
- 2-8°C
- pka
- -1.22±0.10(Predicted)
- form
- Crystalline Needles or Powder
- color
- Yellow
- BRN
- 140157
- InChI
- InChI=1S/C6H6N2O3/c1-5-4-7(9)3-2-6(5)8(10)11/h2-4H,1H3
- InChIKey
- SSOURMYKACOBIV-UHFFFAOYSA-N
- SMILES
- C1[N+]([O-])=CC=C([N+]([O-])=O)C=1C
- CAS DataBase Reference
- 1074-98-2(CAS DataBase Reference)
- NIST Chemistry Reference
- 4-Nitro-3-picoline-n-oxide(1074-98-2)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 40-20/21/22-36/37/38
- Safety Statements
- 45-36/37-36-26-22
- RIDADR
- 2811
- WGK Germany
- 3
- RTECS
- UT5775000
- Hazard Note
- Irritant/Possible Mutagen
- HazardClass
- 6.1
- PackingGroup
- II
- HS Code
- 29333990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 370061
- Product name
- 3-Methyl-4-nitropyridine N-oxide
- Purity
- 98%
- Packaging
- 1g
- Price
- $105
- Updated
- 2024/03/01
- Product number
- 370061
- Product name
- 3-Methyl-4-nitropyridine N-oxide
- Purity
- 98%
- Packaging
- 5g
- Price
- $386
- Updated
- 2024/03/01
- Product number
- N0527
- Product name
- 3-Methyl-4-nitropyridine N-Oxide
- Purity
- >97.0%(T)
- Packaging
- 5g
- Price
- $123
- Updated
- 2024/03/01
- Product number
- N0527
- Product name
- 3-Methyl-4-nitropyridine N-Oxide
- Purity
- >97.0%(T)
- Packaging
- 25g
- Price
- $369
- Updated
- 2024/03/01
- Product number
- L06099
- Product name
- 4-Nitro-3-picoline N-oxide, 98%
- Packaging
- 5g
- Price
- $163
- Updated
- 2021/12/16
3-Methyl-4-nitropyridine N-Oxide Chemical Properties,Usage,Production
Chemical Properties
yellow crystalline needles or powder
General Description
3-Methyl-4-nitropyridine N-Oxide (POM) is an efficient nonlinear optical organic material having a high nonlinear coefficient and achieving the parametric emission process within the desired spectral range (1–2 μm). POM crystallizes in the orthorhombic class, space group P212121, and point group 222. It is a positive biaxial crystal. It melts at 136°C and the nonlinear coefficient is deff=10 pm/V[1]. This compound exhibits a negative-linear-compressibility (NLC) region as well as exceptionally large positive thermal expansion. The initial compression of the weak supramolecular network in the molecular POM crystal is analogous to the hydrostatic responses of the framework crystals with much stronger cohesion forces. 3-Methyl-4-nitropyridine N-Oxide is a commercial NLO material for pico- and femtosecond optics in the near-IR range[2].
Synthesis
Nitration of picoline-N-oxide in the fourth position yields 3-Methyl-4-nitropyridine N-Oxide. Initially, Picoline-N-oxide (50 g) was melted at 38C and mixed with sulfuric acid (250 ml) in cold condition. Later, nitration of this mixture was done at room temperature by addition of sodium nitrate (70 g) and the solution was continuously stirred until all the solid particles dissolves. Temperature was increased slowly to 70C by keeping it in an oil bath and solution was stirred continuously for 2 h at this temperature. To ensure complete nitration, the solution was maintained about 95–100C for 12 h with continuous stirring. The reaction mixture was taken out from the oil bath and cooled. It is then poured over crushed ice and neutralized with ammonia solution till the pH reaches about 7–8. On cooling, bright yellow crystalline 3-Methyl-4-nitropyridine N-Oxide powder was obtained. It was washed and dried in vacuum[1].
References
[1] Boomadevi, S. , H. P. Mittal , and R. Dhansekaran . "Synthesis, crystal growth and characterization of 3-methyl 4-nitropyridine 1-oxide (POM) single crystals."Journal of Crystal Growth 261.1(2004):55-62.
[2] Cai, Weizhao , et al. "Anomalous compression of a weakly CHO bonded nonlinear optical molecular crystal." Journal of Materials Chemistry C 2.32(2014).
3-Methyl-4-nitropyridine N-Oxide Preparation Products And Raw materials
Raw materials
Preparation Products
3-Methyl-4-nitropyridine N-Oxide Suppliers
- Tel
- 320-37350700
- Fax
- +32 (0)37350701
- sales@tcieurope.eu
- Country
- Europe
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- Advantage
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View Lastest Price from 3-Methyl-4-nitropyridine N-Oxide manufacturers
- Product
- 4-Nitro-3-picoline N-oxide 1074-98-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-10-09
- Product
- 4-Nitro-3-picoline N-oxide 1074-98-2
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 Tons
- Release date
- 2021-10-18
- Product
- 4-Nitro-3-picoline N-oxide 1074-98-2
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons min
- Release date
- 2021-09-08