2-Methyl-4-nitropyridine
- Product Name
- 2-Methyl-4-nitropyridine
- CAS No.
- 13508-96-8
- Chemical Name
- 2-Methyl-4-nitropyridine
- Synonyms
- NSC 170691;4-NITRO-2-PICOLINE;2-Amino-5-hydroxypyr;2-Mehtyl-4-nitropyridine;4-NITRO-2-METHYLPYRIDINE;2-METHYL-4-NITROPYRIDINE;Pyridine, 2-methyl-4-nitro-;2-Methyl-4-nitropyridine ,97%;Pyridine, 2-methyl-4-nitro- (9CI);2-METHYL-4-NITROPYRIDINE,4-NITRO-2-PICOLINE
- CBNumber
- CB3779886
- Molecular Formula
- C6H6N2O2
- Formula Weight
- 138.12
- MOL File
- 13508-96-8.mol
2-Methyl-4-nitropyridine Property
- Melting point:
- 32-34 °C
- Boiling point:
- 241.5±20.0 °C(Predicted)
- Density
- 1.246±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Chloroform, Dichloromethane
- form
- Solid
- pka
- 2.04±0.10(Predicted)
- color
- Yellow
- CAS DataBase Reference
- 13508-96-8(CAS DataBase Reference)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 22-41
- Safety Statements
- 26-39-24/25
- HS Code
- 29333990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P330Rinse mouth.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
N-Bromosuccinimide Price
- Product number
- M325625
- Product name
- 2-Methyl-4-nitropyridine
- Packaging
- 250mg
- Price
- $50
- Updated
- 2021/12/16
- Product number
- M325625
- Product name
- 2-Methyl-4-nitropyridine
- Packaging
- 2g
- Price
- $105
- Updated
- 2021/12/16
- Product number
- M3526-70
- Product name
- 2-Methyl-4-nitropyridine
- Packaging
- 1g
- Price
- $531
- Updated
- 2021/12/16
- Product number
- CHM0021364
- Product name
- 2-METHYL-4-NITROPYRIDINE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $624.07
- Updated
- 2021/12/16
- Product number
- CHM0021364
- Product name
- 2-METHYL-4-NITROPYRIDINE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $902.1
- Updated
- 2021/12/16
2-Methyl-4-nitropyridine Chemical Properties,Usage,Production
Chemical Properties
Yellow Solid
Uses
2-Methyl-4-nitropyridine (cas# 13508-96-8) is a compound useful in organic synthesis.
Synthesis
5470-66-6
13508-96-8
a) To a chloroform solution of 4-nitro-2-methylpyridine-N-oxide (11 g, 71.5 mmol) was slowly added a chloroform solution of phosphorus trichloride (PCl3, 33 mL, 0.37 mmol) at 0 °C and under argon protection. The reaction mixture was stirred at room temperature for 3 hours. Upon completion of the reaction, the mixture was poured into ice water and neutralized with ammonium hydroxide solution to neutral, followed by extraction with dichloromethane. The organic phases were combined and concentrated to give a yellow solid product. The solid was washed with a mixed ether-petroleum ether solvent to give 7.8 g of 2-methyl-4-nitropyridine in 79% yield with a melting point of 35 °C.
References
[1] Organic Letters, 2000, vol. 2, # 22, p. 3525 - 3526
[2] Chemical and Pharmaceutical Bulletin, 1998, vol. 46, # 10, p. 1656 - 1657
[3] Chemical and Pharmaceutical Bulletin, 1990, vol. 38, # 9, p. 2446 - 2458
[4] Journal of Organic Chemistry, 1998, vol. 63, # 15, p. 5013 - 5030
[5] Synlett, 2009, # 18, p. 2927 - 2930
2-Methyl-4-nitropyridine Preparation Products And Raw materials
Raw materials
Preparation Products
2-Methyl-4-nitropyridine Suppliers
- Tel
- 021-50182298 021-50180596
- Fax
- +86-21-57758967
- sales@boylechem.com
- Country
- China
- ProdList
- 2208
- Advantage
- 55
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 4006356688 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40228
- Advantage
- 62
- Tel
- +49 3493/605464
- Fax
- +49 3493/605470
- sales@intatrade.de
- Country
- Germany
- ProdList
- 3572
- Advantage
- 66
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- 0311-89250318 031166536426
- Fax
- 4000311741
- master@sjzsdyn.com
- Country
- China
- ProdList
- 2809
- Advantage
- 65
- Tel
- 86-027-67849912
- Fax
- 86-027-87531808
- sales@chemwish.com
- Country
- China
- ProdList
- 35896
- Advantage
- 56
- Tel
- +86 (0) 571 85 58 67 18
- Fax
- 0086-571-85864795
- Country
- China
- ProdList
- 18207
- Advantage
- 66
- Tel
- 13817811078
- Fax
- 86-021-50426522,50426273
- sales@jingyan-chemical.com
- Country
- China
- ProdList
- 9976
- Advantage
- 60
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9310
- Advantage
- 66
View Lastest Price from 2-Methyl-4-nitropyridine manufacturers
- Product
- 2-Methyl-4-nitropyridine 13508-96-8
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons min
- Release date
- 2021-09-08
- Product
- 2-Methyl-4-nitropyridine 13508-96-8
- Price
- US $100.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2018-08-03