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Isobutyl acetoacetate

Product Name
Isobutyl acetoacetate
CAS No.
7779-75-1
Chemical Name
Isobutyl acetoacetate
Synonyms
ACIB;ISOBUTYL ACETOACETATE;Isobutyl 3-oxobutanoate;Isobutyl Acetoacetate >Isobutyl acetoacetate(IBAA);2-Methylpropyl acetoacetate;ACETOACETIC ACID ISOBUTYL ESTER;Isobutyl acetoacetate USP/EP/BP;Isobutyl Acetoacetate, 98.0%(GC);3-Oxobutyric acid isobutyl ester
CBNumber
CB9234174
Molecular Formula
C8H14O3
Formula Weight
158.2
MOL File
7779-75-1.mol
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Isobutyl acetoacetate Property

Melting point:
177-179 °C(Solv: ethyl ether (60-29-7))
Boiling point:
100 °C/22 mmHg (lit.)
Density 
0.98 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.424(lit.)
FEMA 
2177 | ISOBUTYL ACETOACETATE
Flash point:
173 °F
storage temp. 
Sealed in dry,Store in freezer, under -20°C
pka
10?+-.0.46(Predicted)
form 
liquid
color 
clear
Odor
at 10.00 % in dipropylene glycol. sweet wine brandy fruity
Odor Type
fruity
JECFA Number
597
BRN 
1761405
LogP
1.60
CAS DataBase Reference
7779-75-1(CAS DataBase Reference)
NIST Chemistry Reference
Butanoic acid, 3-oxo-, 2-methylpropyl ester(7779-75-1)
EPA Substance Registry System
Butanoic acid, 3-oxo-, 2-methylpropyl ester (7779-75-1)
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Safety

WGK Germany 
3
HS Code 
2918.30.9000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
00483
Product name
Isobutyl acetoacetate
Purity
≥98.0% (GC)
Packaging
100ml
Price
$64.3
Updated
2024/03/01
Sigma-Aldrich
Product number
688657
Product name
Isobutyl acetoacetate
Purity
Lonza quality, ≥97.0% (GC)
Packaging
1kg
Price
$101
Updated
2023/06/20
TCI Chemical
Product number
A0814
Product name
Isobutyl Acetoacetate
Purity
>98.0%(GC)
Packaging
25mL
Price
$22
Updated
2024/03/01
Sigma-Aldrich
Product number
688657
Product name
Isobutyl acetoacetate
Purity
Lonza quality, ≥97.0% (GC)
Packaging
180kg
Price
$3820
Updated
2022/05/15
TRC
Product number
I780045
Product name
Isobutyl Acetoacetate
Packaging
50g
Price
$120
Updated
2021/12/16
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Isobutyl acetoacetate Chemical Properties,Usage,Production

Description

Isobutyl acetoacetate has a sweet, winey, brandy-like odor and a sweet and slightly fruity flavor. May be prepared from isobutyl acetate by heating in the presence of sodium isobutylate.

Chemical Properties

Isobutyl acetoacetate has a sweet, winy, brandy-like odor and a sweet and slightly fruity flavor.

Chemical Properties

Isobutyl acetoacetate is a clear colorless liquid. Insoluble in water, soluble in alcohol and oils. B.P. approximately 196℃. The odor is somewhat fresher, not as "fermented" as that of the n-But yiester, while the taste of the iso-Butylester is somewhat less sweet. In general, the former is preferred for “winey” effects, while this (latter) is preferred for fruity effects, and partly as a fixative for the more volatile esters used in hard candy flavoring etc. Concentrations are usually around 25 ppm.

Uses

Isobutyl acetoacetate is used as intermediate for the production of pharmaceuticals (e.g. Nisoldipine). Product Data Sheet

Uses

Isobutyl Acetoacetate is a building block that has been used as a reactant in the preparation of b-annulated 1,4-dihydropyridine derivatives as TGFβ signaling inhibitors.

Definition

ChEBI: 2-Methylpropyl 3-oxobutanoate is an oxo carboxylic acid.

Preparation

From isobutyl acetate by heating in the presence of sodium isobutylate. Or by Claisen condensation of iso-ButyI acetate with Ethylacetate, using Sodium ethoxide catalyst.

Isobutyl acetoacetate Preparation Products And Raw materials

Raw materials

Preparation Products

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Isobutyl acetoacetate Suppliers

Chemspon Bio-Tech Co., Ltd
Tel
0571-88937695 88937835 13606537248
Fax
0571-88933015 QQ:1423821043
Email
sales@chemspon.com
Country
China
ProdList
242
Advantage
58
Jiujiang Huayao Biotechnology Co., Ltd.
Tel
0792-13970278 13970278471
Email
36516506@qq.com
Country
China
ProdList
95
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
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View Lastest Price from Isobutyl acetoacetate manufacturers

Career Henan Chemical Co
Product
Isobutyl acetoacetate 7779-75-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-08

7779-75-1, Isobutyl acetoacetateRelated Search:


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