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4-METHOXY-2-CHLOROANILINE

Product Name
4-METHOXY-2-CHLOROANILINE
CAS No.
29242-84-0
Chemical Name
4-METHOXY-2-CHLOROANILINE
Synonyms
5 graMs;2-Chloro-4-methoxyan;4-Amino-3-chloroanisole;4-METHOXY-2-CHLOROANILINE;2-chloro-4-methoxybenzenamine;2-Chloro-4-methoxyaniline 97+%;2-Chloro-4-Methoxy-phenylaMine;BenzenaMine,2-chloro-4-Methoxy-;4-AMino-3-chloroanisole[2-Chloro-4-Methoxyaniline]
CBNumber
CB92461170
Molecular Formula
C7H8ClNO
Formula Weight
157.6
MOL File
29242-84-0.mol
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4-METHOXY-2-CHLOROANILINE Property

Melting point:
114℃
Boiling point:
249℃
Density 
1.234
Flash point:
105℃
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
3.26±0.10(Predicted)
Appearance
Brown to black Liquid
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Safety

HS Code 
2921420090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P322Specific measures (see …on this label).

P330Rinse mouth.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
C349605
Product name
2-Chloro-4-methoxyaniline
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
C349605
Product name
2-Chloro-4-methoxyaniline
Packaging
500mg
Price
$65
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC67022
Product name
2-Chloro-4-methoxyaniline
Packaging
5G
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
119482
Product name
2-Chloro-4-methoxyaniline
Purity
95+%
Packaging
1g
Price
$93
Updated
2021/12/16
AK Scientific
Product number
W5185
Product name
2-Chloro-4-methoxyaniline
Packaging
5g
Price
$103
Updated
2021/12/16
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4-METHOXY-2-CHLOROANILINE Chemical Properties,Usage,Production

Synthesis

28987-59-9

29242-84-0

The general procedure for the synthesis of 2-chloro-4-methoxyaniline from 2-chloro-4-methoxynitrobenzene was as follows: iron powder (5.10 g, 91.69 mmol) was added to a water (22 mL) and methanol (70 mL) containing 2-chloro-4-methoxy-1-nitrobenzene (1.72 g, 9.17 mmol) and ammonium chloride (1.96 g, 36.68 mmol) in a ) in a mixed suspension. The reaction mixture was heated to 50 °C and stirred at this temperature for 1 hour. After completion of the reaction, the mixture was cooled to room temperature, filtered, and the solid was washed with distilled water (2 x 15 mL). The filtrate was extracted with ethyl acetate (2 x 50 mL) and the combined organic layers were dried over anhydrous sodium sulfate, filtered and concentrated. The crude product was purified by silica gel column chromatography (eluent: 10-22% ethyl acetate/hexane) to afford 2-chloro-4-methoxyaniline (orange oil, 1.24 g, 86% yield).HPLC-MS (Method A): retention time 7.37 min; ESI-MS m/z: 158 ([M+H]+).

References

[1] Patent: WO2018/13774, 2018, A1. Location in patent: Page/Page column 455
[2] Patent: WO2018/1973, 2018, A1. Location in patent: Page/Page column 196
[3] Journal of the Chemical Society, 1927, p. 2218
[4] Journal of the Chemical Society, 1928, p. 331
[5] Journal of the Chemical Society, 1927, p. 2218

4-METHOXY-2-CHLOROANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-METHOXY-2-CHLOROANILINE Suppliers

China 87 India 5 Switzerland 1 United Kingdom 3 United States 6 Global 102
Biokemix
Tel
--
Fax
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Email
biokemix@yes-boss.com
Country
India
ProdList
486
Advantage
50
A.J Chemicals
Tel
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Fax
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Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
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View Lastest Price from 4-METHOXY-2-CHLOROANILINE manufacturers

Career Henan Chemical Co
Product
4-METHOXY-2-CHLOROANILINE 29242-84-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-11

29242-84-0, 4-METHOXY-2-CHLOROANILINERelated Search:

2'-CHLORO-4'-(TRIFLUOROMETHOXY)ACETANILIDE 2,6-DICHLORO-4-(TRIFLUOROMETHOXY)ANILINE 2-CHLORO-4-(TRIFLUOROMETHOXY)ANILINE Lufenuron 4-METHOXY-2-CHLOROANILINE 6-CHLORO-2,2-DIFLUORO-BENZO[1,3]DIOXOL-5-YLAMINE N-(2,6-DICHLORO-4-METHOXYPHENYL)ACETAMIDE 5-amino-2-(2,6-dichloro-4-methoxyphenyl)-2,4-dihydro-3H-pyrazol-3-one 2-CHLORO-4-METHOXYNITROBENZENE 2,6-DICHLORO-4-METHOXYANILINE (2-Chloro-4,6-dimethoxyphenyl)amine N-(7-CHLORO-2,3-DIHYDRO-1,4-BENZODIOXIN-6-YL)ACETAMIDE 6-CHLORO-2,2,3,3-TETRAFLUORO-7-NITRO-1,4-BENZODIOXENE 2-CHLORO-6-NITRO-4-(TRIFLUOROMETHOXY)ACETANILIDE 3,6-Dichloro-2,4-dinitrophenyl methacrylate 5-Amino-4-chloro-N-ethyl-2-(2-propenyloxy)benzamide N'1-[2-(PYRIDO[3,2-D][1,3]THIAZOL-2-YLTHIO)ACETYL]-3,5-DICHLORO-4-(3-CHLORO-4-NITROPHENOXY)BENZENE-1-SULFONOHYDRAZIDE 2,3,5,6-Tetrachloro-4-nitroanisole.

  • 4-METHOXY-2-CHLOROANILINE
  • 5 graMs
  • 4-AMino-3-chloroanisole[2-Chloro-4-Methoxyaniline]
  • BenzenaMine,2-chloro-4-Methoxy-
  • 2-chloro-4-methoxybenzenamine
  • 2-Chloro-4-Methoxy-phenylaMine
  • 2-Chloro-4-methoxyaniline 97+%
  • 2-Chloro-4-methoxyan
  • 4-Amino-3-chloroanisole
  • 29242-84-0