Tricyclohexyl phosphine

ChemicalBook > CAS DataBase List > Tricyclohexyl phosphine

Tricyclohexyl phosphine

Description

Product Name: Tricyclohexyl phosphine
CAS No.: 2622-14-2
Chemical Name: Tricyclohexyl phosphine
Synonyms: PCY3;TRICYCLOHEXYLPHOSPHINE;Cy3P;TCHP;TricycL;Phosphine, tricyclohexyl-;NSC 158657;Protein TCHP;Tricyclohexyl phosph;tricyclohexylphospine
CBNumber: CB9251553
Molecular Formula: C18H33P
Formula Weight: 280.43
MOL File: 2622-14-2.mol

Less

Tricyclohexyl phosphine Property

Melting point:: 81-83 °C (lit.)
Boiling point:: 383.4±9.0 °C | Condition: Press: 760 Torr
Density: 0.909 g/mL at 25 °C
Flash point:: 48 °F
storage temp.: Inert atmosphere,2-8°C
solubility: Chloroform (Slightly), DMSO (Slightly, Heated, Sonicaetd), Ethyl Acetate (Slightly)
form: Solution
Specific Gravity: 0.9
color: White to off-white
Water Solubility: Soluble in most organic solvents. Insoluble in water.
Sensitive: Air Sensitive
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
BRN: 957171
Stability:: Air Sensitive, Moisture Sensitive
InChIKey: WLPUWLXVBWGYMZ-UHFFFAOYSA-N
CAS DataBase Reference: 2622-14-2(CAS DataBase Reference)
NIST Chemistry Reference: Phosphine, tricyclohexyl-(2622-14-2)
EPA Substance Registry System: Phosphine, tricyclohexyl- (2622-14-2)

Less

Safety

Hazard Codes: Xi,Xn,F
Risk Statements: 36/37/38-22-37/38-36-19-11-67-65-63-48/20-40
Safety Statements: 26-36/37-62-37/39-36-33-29-16
RIDADR: UN 2056 3/PG 2
WGK Germany: 3
TSCA: Yes
HazardClass: 3
PackingGroup: III
HS Code: 29319090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

H373May cause damage to organs through prolonged or repeated exposure

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P331Do NOT induce vomiting.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 261971
Product name: Tricyclohexylphosphine
Packaging: 1g
Price: $73.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 261971
Product name: Tricyclohexylphosphine
Purity: 97%
Packaging: 5g
Price: $83.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: SAB1302957
Product name: ANTI-TCHP (CENTER) antibody produced in rabbit
Purity: IgG fraction of antiserum, buffered aqueous solution
Packaging: 400μL
Price: $461
Updated: 2023/01/07

Alfa Aesar

Product number: 030386
Product name: Tricyclohexylphosphine
Purity: 96%
Packaging: 1g
Price: $23.65
Updated: 2024/03/01

Alfa Aesar

Product number: 030386
Product name: Tricyclohexylphosphine
Purity: 96%
Packaging: 5g
Price: $79.7
Updated: 2024/03/01

Less

Tricyclohexyl phosphine Chemical Properties,Usage,Production

Description

Tricyclohexyl phosphine is the tertiary phosphine with the formula P( C 6H11) 3. Commonly used as a ligand in organometallic chemistry, it is often abbreviated to PCy 3, where Cy stands for cyclohexyl. It is characterized by both high basicity (pK a = 9.7) and a large ligand cone angle (170°). Tricyclohexyl-phosphine is more basic (and so a better c-donor) than tribu tyiphosphine, which in turn is more basic than triphenyl phosphIne.

Chemical Properties

clear colorless to pale yellow solution

Uses

Tricyclohexylphosphine is used as a ligand in organometallic chemistry. As a reagent, it is used for a range of metal-catalyzed organic transformations. Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions. Grubbs?catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.

Uses

Tricyclohexyl Phosphine is a ligand catalyst used primarily in organometallic chemistry.
Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides.
suzuki reaction: Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides.
This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.
As a reagent, Tricyclohexylphosphine is used for a range of metal-catalyzed organic transformations.
Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions.
Grubbs' catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.

reaction suitability

reaction type: Cross Couplings
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Hiyama Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

Purification Methods

It recrystallises from EtOH [Boert et al. J Am Chem Soc 109 7781 1987]. [Beilstein 16 IV 947.]

Tricyclohexyl phosphine Preparation Products And Raw materials

Raw materials

Bromocyclohexane Phosphorus trichloride Diethyl ether Ammonium chloride Magnesium

Preparation Products

Bis(tricyclohexylphosphine)palladium(II) Dichloride

Less

Tricyclohexyl phosphine Suppliers

Belgium 4 Canada 1 China 372 Europe 1 Germany 7 India 16 Japan 7 Russia 1 Slovakia 1 South Korea 2 Switzerland 3 Ukraine 1 United Kingdom 14 United States 38 Global 468

Sinocompound Catalysts Co., Ltd.

Tel: 0512-67216630 67216634
Fax: 0512-56316689
Email: sales@sinocompound.com
Country: China
ProdList: 281
Advantage: 64

Wuhan Ying Yuan Bei Biological Limited

Tel: 13349903920 13349903920
Email: 1540154086@qq.com
Country: China
ProdList: 2996
Advantage: 58

Wuhan WinYuanBei Trading Company

Tel: 86-13349903920 13349903920
Fax: -
Email: 869523959@qq.com
Country: China
ProdList: 9959
Advantage: 58

Aikon International Limited

Tel: 025-66028182 18112977050
Fax: (3)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 15818
Advantage: 58

BeiJing Greenchem Technology Co.,Ltd.

Tel: 131-21959385 15640741633
Fax: 010-62925455
Email: chemrocking@bjgreenchem.com
Country: China
ProdList: 269
Advantage: 58

Hubei Zhonglong Kangsheng fine chemical Co.,Ltd

Tel: 027-83850381 18171045381
Email: 2533797015@qq.com
Country: China
ProdList: 186
Advantage: 58

Nanjin Cynthia chemicals Technology Co.,Ltd

Tel: 0550-5618439 15951861180
Fax: 0550-5610690
Email: cynthiachem@163.com
Country: China
ProdList: 291
Advantage: 62

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 9371
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18207
Advantage: 66

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12387
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9510
Advantage: 66

Beijing VSciChem Technology Co., Ltd.

Tel: 13811761079
Email: vscichem@163.com
Country: China
ProdList: 251
Advantage: 64

Puyang Huicheng Electronic Material Co. Ltd.

Tel: 0393-0393-0393-8910800 15039333257
Fax: 0393-8912775
Email: info@huichengchem.com
Country: China
ProdList: 565
Advantage: 64

Hangzhou Minsuo Technology Co., Ltd.

Tel: 0571-0571-88199336 13355710209
Fax: 0571-88190523
Email: sales@luckysagechem.com
Country: China
ProdList: 56
Advantage: 64

Shanghai Longsheng chemical Co.,Ltd.

Tel: 021-58099652-8005 13585536065
Fax: 021-58099609
Email: bin.wu@shlschem.com
Country: China
ProdList: 9810
Advantage: 59

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32321
Advantage: 50

Shijiazhuang Kenuo Da Technology Co., Ltd.

Tel: 0311-85461665 13784393231
Fax: 0311-85461665
Email: leichemist@126.com
Country: China
ProdList: 25
Advantage: 64

China DongFan Chemical Co.,LTD

Tel: 86-0571-85151182
Fax: 86-0571-85151182
Country: China
ProdList: 5691
Advantage: 66

XiaoGan ShenYuan ChemPharm co,ltd

Tel: 15527768850
Email: 1791901229@qq.com
Country: China
ProdList: 8835
Advantage: 52

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18738
Advantage: 57

Tangshan Moneide Trading Co., Ltd.

Tel: 0315-8309571 15633399667
Fax: +86-315-7726572
Email: sales@moneidechem.com
Country: China
ProdList: 704
Advantage: 57

Sichuan Kulinan Technology Co., Ltd

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11707
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

Sinopharm Chemical Reagent Co,Ltd.

Tel: 86-21-63210123
Fax: 86-21-63290778 86-21-63218885
Email: sj_scrc@sinopharm.com
Country: China
ProdList: 9815
Advantage: 79

Shanghai Sunway Pharmaceutical Technology Co., Ltd

Tel: 021-51613915-820 13611835272
Fax: 021 51613951
Email: mmwang@sunwaypharm.cn
Country: China
ProdList: 9734
Advantage: 57

Nanjing Vital Chemical Co., Ltd.

Tel: Please Send Email 18652950785
Fax: 025-87193546
Email: chemweiao@163.com
Country: China
ProdList: 4378
Advantage: 65

Aemon Chemical

Tel: 0086-755-86198205
Email: acinfo@aemonchem.com
Country: China
ProdList: 1931
Advantage: 57

Springchem New Material Technology Co.,Limited

Tel: +86-021-62885108 +8613917661608
Email: info@spring-chem.com
Country: China
ProdList: 2068
Advantage: 57

ZhengZhou HuaWen Chemical Co.Ltd

Tel: 0370-2785118 17550508557
Fax: QQ：3470079902
Email: 675141927@qq.com
Country: China
ProdList: 3203
Advantage: 55

WuHan Taiyukaishang Chemical Co., Ltd.

Tel: 027-027-87680032 18963957250
Fax: 027-87680032 -8016
Email: taiyuchem@163.com
Country: China
ProdList: 108
Advantage: 55

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9718
Advantage: 55

T&W GROUP

Tel: 021-61551611 13296011611
Fax: ＋86 21-50676805
Email: contact@trustwe.com
Country: China
ProdList: 9895
Advantage: 58

Suzhou Sibian Chemical Technology Co.,Ltd.

Tel: 0512-65617459 18915409046
Fax: 0512-65617459
Email: sales@sibian-chem.com
Country: China
ProdList: 1922
Advantage: 55

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6134
Advantage: 55

Accendatech Co., LTD.

Tel: 13132578992
Fax: 022-83718543-802
Email: sales@accendatech.com
Country: China
ProdList: 332
Advantage: 58

Shanghai Topbiochem Technology Co., Ltd

Tel: +86-21-60341587
Fax: +86-21-61294319
Email: sales@topbiochem.com
Country: China
ProdList: 6175
Advantage: 58

Yurui (Shanghai) Chemical Co., Ltd.

Tel: 02150456736 18602143071
Fax: 021-50761379
Email: Jenny@riyngroup.com
Country: China
ProdList: 889
Advantage: 30

Shanghai T&W Pharmaceutical Co., Ltd.

Tel: +86 21 61551611
Fax: +86 21 50676805
Country: China
ProdList: 9891
Advantage: 58

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 18017383231 18017383231
Fax: qq：2817624287
Email: lyh_antaeus@163.com
Country: China
ProdList: 9347
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22514
Advantage: 55

UHN Shanghai Research & Development Co., Ltd.

Tel: 021-58958002 18930822973
Fax: +86 (21) 5895-8628
Email: sales@uhnshanghai.com
Country: China
ProdList: 997
Advantage: 58

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-6206333 18021050169
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Less

View Lastest Price from Tricyclohexyl phosphine manufacturers

Wuhan Circle Star Chem-medical Technology Co.,Ltd

Product: Tricyclohexyl phosphine 2622-14-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98
Supply Ability: 1000
Release date: 2025-01-09

XINXIANG RUNYU MATERIAL CO., LTD.

Product: Tricyclohexyl phosphine 2622-14-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 0.99
Supply Ability: 500kg
Release date: 2021-12-02

Hebei Yanxi Chemical Co., Ltd.

Product: Tricyclohexyl phosphine 2622-14-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100tons
Release date: 2023-09-27

2622-14-2, Tricyclohexyl phosphineRelated Search:

DICYCLOHEXYLPHOSPHINE TRICYCLOHEXYLPHOSPHINE OXIDE TRICYCLOHEXYLPHOSPHONIUM TETRAFLUOROBORATE TRICYCLOPENTYLPHOSPHINE TRIHEXYLPHOSPHINE O-(2,2,2-Trifluoroethyl)hydroxylamine hydrochloride Trimethylsilyl 2-(fluorosulfonyl)difluoroacetate BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium (3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)rutheniuM(IV) Dichloride Phosphine Bis(tricyclohexylphosphine)palladium(0) Bis(tricyclohexylphosphine)palladium(II) Dichloride TRICYCLOHEXYL-D33-PHOSPHINE CARBON DISULFIDE COMPLEX GRUBBS CATALYST 2ND GENERATION Dichlorobis(tricyclohexylphosphine) palladium CYCLOHEXYLPHOSPHINE (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

PHOSPHORUS TRICYCLOHEXYL

TCHP

TRICYCLOHEXYL-PHOSPHANE

TRICYCLOHEXYLPHOSPHINE

NSC 158657

ANTI-TCHP (CENTER) antibody produced in rabbit

Protein TCHP

Trichoplein keratin filament-binding protein

Tumor suppressor protein

Tricyclohexylphosphine, min. 98%

TRICYCLOHEXYLPHOSPHINE: (20% IN TOLUENE)

Tricyclohexylphosphine, technical grade

Tricyclohexylphosphine (contains Tricyclohexylphosphine Oxide) (ca. 18% in Toluene, ca. 0.60mol/L)

TRICYCLOHEXYLPHOSPHINE, DISSOLVED IN TOLUENE (20% CONCENTRATION)

TRICYCLOHEXYL PHOSPHINE (TCHP)

Phosphine, tricyclohexyl-

Tricyclohexylphosphine (20% in toluene), min. 88%

Tris(cyclohexyl)phosphine

Triscyclohexylphosphine

Tricyclohexylphosphine (ca. 18% in Toluene, ca. 0.60mol/L)(contains Tricyclohexylphosphine Oxide)

Tricyclohexylphosphine,1M solution in THF

Tricyclohexylphosphine,1M solution in toluene

Tricyclohexylphosphine, 97% 1mol toluene

tricyclohexyl-phosphin

TRICYCLOHEXYLPHOSPHINE, 20 WT. % SOLUTI&

TRICYCLOHEXYLPHOSPHINE, 1M IN TOLUENE

TRICYCLOHEXYLPHOSPHINE, 1M IN TETRAHYDR&

Tricyclohexylphosphine, 20% Toluene Solution

Tricyclohexylphosphine,97%

Tricyclohexylphosphine(20%intoluene),min.88%

tricyclohexylphosphine solution

PCY3

tricyclohexylphospine

Tricyclohexylphosphine,Cy3P

Tricyclohexyl Phosphine (90%)

Tricyclohexylphosphine solution 20 wt. % in toluene

Tricyclohexyphosphine

Tricyclohexylphosphine, 1.0 M solution in THF, SpcSeal

Tricyclohexylphosphine,97% Cy3P

Tricyclohexylphosphine,96%

Tricyclohexyl phosph

Tricyclohexylphosphine, 1M solution in toluene, AcroSeal

Tricyclohexylphosphine, 1M solution in THF, AcroSeal

Tricyclohexylphosphene

Tricyclohexylphosphine, 97% 5GR

TricycL

TRICYCLOHEXYLPHOSPHINE, 20-22% in toluene

Tricyclohexylphosphine, 97% 1mol THF

Cy3P

Tricyclohexylphosphine (Cy3P) extrapure, 97%

Tricyclohexylphosphine, 1M solution in toluene, AcroSeal&trade

2-Propenoicacid,2-methyl-,2-(6-hydroxyethoxy)ethylester

ricyclohexylphosphane

Tricyclohexylphosphine(TCP)

Tricyclohexylphosphine,95%

2622-14-2

3622-14-2

622-14-2