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ChemicalBook > CAS DataBase List > Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)

Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)

Reaction
Product Name
Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)
CAS No.
387859-70-3
Chemical Name
Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)
Synonyms
Ir(Fppy)3;Ir(dFppy);Ir(4,6Fppy)3;Tris[2-(2,4-difL;)pyridine]iridium(III);Tris(2-(4,6-difuorophenyl)pyridine)iridium(III);TRIS[2-(2,4-DIFLUOROPHENYL)PYRIDINE]IRIDIUM(III),95%;Tris[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium;2-(2,4-difluorobenzene-6-id-1-yl)pyridine,iridium(3+);Tris[4,6-difluoro-2-(2-pyridyl)phenyl-C2,N]iridium(III)
CBNumber
CB92753471
Molecular Formula
C33H18F6IrN3
Formula Weight
762.74
MOL File
387859-70-3.mol
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Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Property

Melting point:
401 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Powder
color 
yellow
Sensitive 
air sensitive
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
900540
Product name
Ir(dFppy)3
Packaging
100mg
Price
$226
Updated
2024/03/01
Sigma-Aldrich
Product number
682594
Product name
Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)
Purity
96%
Packaging
250mg
Price
$456
Updated
2024/03/01
Strem Chemicals
Product number
77-7030
Product name
Tris[2-(2,4-difluorophenyl)pyridine]iridium(III), 95%
Packaging
50mg
Price
$104
Updated
2024/03/01
Strem Chemicals
Product number
77-7030
Product name
Tris[2-(2,4-difluorophenyl)pyridine]iridium(III), 95%
Packaging
250mg
Price
$413
Updated
2024/03/01
ChemSupplyAustralia
Product number
300896
Product name
fac-Tris[2-?(4,?6-?Difluorophenyl)?pyridinato]iridium(III), 95%
Packaging
50mg
Price
$65
Updated
2021/12/16
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Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Chemical Properties,Usage,Production

Reaction

  1. Photoredox catalysis for trifluoromethylation of arenes and heteroarenes.
  2. Photocatalyst for C–F alkenylation coupling reactions between perfluoroarenes and alkynes.

Uses

Ir(dFppy)3 is a photocatalyst that readily facilitates the decarboxylative arylation of α amino acids using visible light.

Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Suppliers

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View Lastest Price from Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
Fac-Ir (dfppy)3 387859-70-3
Price
US $0.00/g
Min. Order
1g
Purity
99.90%
Supply Ability
100kgs
Release date
2021-09-16
Career Henan Chemical Co
Product
Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) 387859-70-3
Price
US $0.10/KG
Min. Order
1KG
Purity
95%-99%
Supply Ability
1kg; 100kg
Release date
2019-12-25