ChemicalBook > CAS DataBase List > Tetrabutylammonium Difluorotriphenylsilicate

Tetrabutylammonium Difluorotriphenylsilicate

Product Name
Tetrabutylammonium Difluorotriphenylsilicate
CAS No.
163931-61-1
Chemical Name
Tetrabutylammonium Difluorotriphenylsilicate
Synonyms
TBAT;TETRABUTYLAMMONIUM TRIPHENYLDIFLUOROSILICATE;TETRA-N-BUTYLAMMONIUM;TETRA-N-BUTYLAMMONIUM DIFLUOROTRIPHENYLSILICATE;TetrabutylaMMoniuM difluorotriphenylsilicate(IV);DK570;DKFELEX0140;Bardac(R) 205 M;Alkyl Dimethyl Be;TETRABUTYLAMMONIUM TRIPHENYLDIFLUORO-SIL
CBNumber
CB9296666
Molecular Formula
C34H51F2NSi
Formula Weight
539.86
MOL File
163931-61-1.mol
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Tetrabutylammonium Difluorotriphenylsilicate Property

Melting point:
157-163 °C(lit.)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
soluble in most organic solvents.
form 
powder to crystal
color 
White to Almost white
Stability:
Hygroscopic, Moisture sensitive
InChI
InChI=1S/C18H15F2Si.C16H36N/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4/h1-15H;5-16H2,1-4H3/q-1;+1
InChIKey
RQBKGJOQACIQDG-UHFFFAOYSA-N
SMILES
[Si-](F)(F)(C1=CC=CC=C1)(C1C=CC=CC=1)C1C=CC=CC=1.[N+](CCCC)(CCCC)(CCCC)CCCC
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Safety

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
22-26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
441457
Product name
Tetrabutylammonium difluorotriphenylsilicate
Purity
97%
Packaging
5g
Price
$110
Updated
2024/03/01
Sigma-Aldrich
Product number
441457
Product name
Tetrabutylammonium difluorotriphenylsilicate
Purity
97%
Packaging
25g
Price
$375
Updated
2024/03/01
TCI Chemical
Product number
T1909
Product name
Tetrabutylammonium Difluorotriphenylsilicate
Purity
>97.0%(T)
Packaging
5g
Price
$93
Updated
2024/03/01
TCI Chemical
Product number
T1909
Product name
Tetrabutylammonium Difluorotriphenylsilicate
Purity
>97.0%(T)
Packaging
25g
Price
$295
Updated
2024/03/01
TRC
Product number
T291240
Product name
Tetrabutylammonium difluorotriphenylsilicate
Packaging
1g
Price
$65
Updated
2021/12/16
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Tetrabutylammonium Difluorotriphenylsilicate Chemical Properties,Usage,Production

Description

Tetrabutylammonium difluorotriphenylsilicate, also known as Tetrabutylammonium difluorotriphenylsilicate(IV) (TBADFTPS), is a fluoride source for nucleophilic fluorination. Tetrabutylammonium difluorotriphenylsilicate is an anion-exchange resin utilized in laboratory experiments for various scientific purposes. Its distinct characteristics render it useful for researchers in chromatography, catalysis, and electrochemistry. Tetrabutylammonium difluorotriphenylsilicate consists of two functional groups: a positively charged ammonium group and a negatively charged difluorotriphenylsilicate group. This resin allows for the exchange of anions within solutions. In chromatography and catalysis, Tetrabutylammonium difluorotriphenylsilicate effectively separates and purifies diverse compounds, including proteins, peptides, and organic molecules. Moreover, it catalyzes organic reactions and contributes to the synthesis of organic compounds. Additionally, Tetrabutylammonium difluorotriphenylsilicate plays a significant role in electrochemical experiments, aiding the study of electrochemical reactions and the measurement of electrochemical potentials.

Chemical Properties

Liquid

Physical properties

mp 155–156°C(EtOAc).

Uses

Tetrabutylammonium Difluorotriphenylsilicate is non-hygroscopic, organic-soluble reagent used as a nucleophilic fluoride source in Nucleophilic Fluorination and Allylation Reactions.

Uses

A fluoride source for nucleophilic fluorination.

Uses

Tetrabutylammonium Difluorotriphenylsilicate (Bardac(R) 208M) is a quaternary ammonium based antimicrobial used as a bacteriostat, deodorant, disinfectant and(or) a microbiocide.

Preparation

Tetrabutylammonium Difluorotriphenylsilicate is prepared by treatment of triphenylsilyl fluoride with tetrabutylammonium fluoride (TBAF), or by reaction of triphenylsilane with tetrabutylammonium hydrogen difluoride.

Tetrabutylammonium Difluorotriphenylsilicate Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetrabutylammonium Difluorotriphenylsilicate Suppliers

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View Lastest Price from Tetrabutylammonium Difluorotriphenylsilicate manufacturers

Shanghai Daken Advanced Materials Co.,Ltd
Product
Tetrabutylammonium triphenyldifluorosilicate 163931-61-1
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1000KG /month
Release date
2021-11-19
Henan Aochuang Chemical Co.,Ltd.
Product
Tetrabutylammonium Difluorotriphenylsilicate 163931-61-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-09
Career Henan Chemical Co
Product
Tetrabutylammonium Difluorotriphenylsilicate 163931-61-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000KGS
Release date
2019-12-23

163931-61-1, Tetrabutylammonium DifluorotriphenylsilicateRelated Search:


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  • CH3CH2CH2CH24NC6H53SiF2
  • C18H15F2SiC16H36N
  • C34H51F2NSi
  • Ammonium Salts
  • Halogenation
  • Fluorination
  • Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds
  • Quaternary Ammonium Compounds
  • Phase Transfer Catalysts
  • Synthetic Reagents
  • Si (Classes of Silicon Compounds)
  • Ammonium Polyhalides, etc. (Quaternary)
  • Fluorinating Reagents
  • Si-X (F, Br, I) Compounds
  • Nucleophilic Fluorinating Reagents
  • Ammonium Polyhalides, etc. (Quaternary)
  • Fluorinating Reagents
  • Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds
  • Fluorination
  • Halogenation
  • Nucleophilic Fluorinating Reagents
  • Quaternary Ammonium Compounds
  • Si (Classes of Silicon Compounds)
  • Si-X (F, Br, I) Compounds
  • Synthetic Organic Chemistry