ChemicalBook > CAS DataBase List > 2-Hydroxypropyl methacrylate

2-Hydroxypropyl methacrylate

Product Name
2-Hydroxypropyl methacrylate
CAS No.
27813-02-1
Chemical Name
2-Hydroxypropyl methacrylate
Synonyms
HYDROXYPROPYL METHACRYLATE;METHACRYLIC ACID 2-HYDROXYPROPYL ESTER;methacrylic acid, monoester with propane-1,2-diol;2HPMA;L-61040;rocryl410;Photomer 2317;2-Hydroxypropyl meth;Dimethicone 9006-65-9;Hydroxy propyl ethacrylate
CBNumber
CB9299748
Molecular Formula
C7H12O3
Formula Weight
144.17
MOL File
27813-02-1.mol
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2-Hydroxypropyl methacrylate Property

Melting point:
-58°C
Boiling point:
57 °C/0.5 mmHg (lit.)
Density 
1.066 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
vapor pressure 
0.05 mm Hg ( 20 °C)
refractive index 
n20/D 1.447(lit.)
Flash point:
206 °F
storage temp. 
2-8°C
solubility 
107g/l
form 
Liquid
Specific Gravity
1.066
color 
Clear
PH
6 (50g/l, H2O, 20℃)
Water Solubility 
Soluble in water.
BRN 
1752228
InChIKey
GNSFRPWPOGYVLO-UHFFFAOYSA-N
LogP
0.97 at 20℃
CAS DataBase Reference
27813-02-1(CAS DataBase Reference)
EPA Substance Registry System
Hydroxypropyl methacrylate (27813-02-1)
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Safety

Hazard Codes 
Xi,T
Risk Statements 
36/37/38-43-36-46-45
Safety Statements 
26-36/37-37/39-24/25-45-53
WGK Germany 
1
RTECS 
UD3442500
TSCA 
Yes
HS Code 
29161490
Hazardous Substances Data
27813-02-1(Hazardous Substances Data)
Toxicity
rat,LD50,oral,11200mg/kg (11200mg/kg),LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMAGASTROINTESTINAL: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: DYSPNEA,National Technical Information Service. Vol. OTS0544834,
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

H340May cause genetic defects

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
268542
Product name
Hydroxypropyl methacrylate
Purity
Mixture of hydroxypropyl and hydroxyisopropyl methacrylates, 97%, contains 180-220 ppm monomethyl ether hydroquinone as inhibitor
Packaging
1l
Price
$206
Updated
2024/03/01
Sigma-Aldrich
Product number
268542
Product name
Hydroxypropyl methacrylate
Purity
Mixture of hydroxypropyl and hydroxyisopropyl methacrylates, 97%, contains 180-220 ppm monomethyl ether hydroquinone as inhibitor
Packaging
18l
Price
$739
Updated
2024/03/01
TCI Chemical
Product number
M0512
Product name
Hydroxypropyl Methacrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Methacrylate) (stabilized with MEHQ)
Purity
>97.0%(GC)
Packaging
25mL
Price
$19
Updated
2024/03/01
TCI Chemical
Product number
M0512
Product name
Hydroxypropyl Methacrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Methacrylate) (stabilized with MEHQ)
Purity
>97.0%(GC)
Packaging
500mL
Price
$55
Updated
2024/03/01
Alfa Aesar
Product number
A17951
Product name
Hydroxypropyl methacrylate, mixture of isomers, 98%, stab. with ca 0.02% 4-methoxyphenol
Packaging
250ml
Price
$41.65
Updated
2024/03/01
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2-Hydroxypropyl methacrylate Chemical Properties,Usage,Production

Description

Hydroxypropyl methacrylate(HPMA) is a clear, colorless liquid with a pungent, sweet odor. The product contains low levels of a polymerization inhibitor along with small amounts of methacrylic acid, and propylene oxide. HPMA is used in the manufacture of acrylic polymers for adhesives, inks, and coatings for automotive, appliance and metal applications. The added hydroxyl groups improve adhesion to surfaces, incorporate cross-link sites, and impart corrosion, fogging, and abrasion resistance.

Chemical Properties

Clear colorless liquid

Uses

Monomer for acrylic resins, nonwoven fabric binders, detergent lubricating-oil additives.

Uses

Hydroxypropyl methacrylate is a functional monomer for the preparation of hot solid acrylic coatings, styrene-butadiene latex modifiers, acrylic modified polyurethane coating ,water-soluble plating coatings , adhesives ,textile finishing agent ,paper coating , photosensitive paint and polyurethane vinyl resin modified agent. Mainly used in the manufacture are active groups of hydroxyl acrylic resin. Used in reactive diluent and cross-linking agent in the UV curing system.

Definition

ChEBI: 2-hydroxypropyl methacrylate is an enoate ester that is the 1-methacryloyl derivative of propane-1,2-diol. It has a role as a polymerisation monomer. It is functionally related to a propane-1,2-diol and a methacrylic acid.

Application

2-Hydroxypropyl Methacrylate (HPMA) used in the preparation of solid and emulsion polymers, acrylic dispersions in combination with other (meth) acrylates, which are used in various industries, especially for textile coatings and dressings. HPMA is widely used in the production of acrylic polyols for automotive components, refurbishment coatings, and industrial coatings. HPMA is also used as a comonomer in styrene-based unsaturated polyesters, PMMA-based acrylic resins, and vinyl ester formulations in anchor bolts and chemical anchors.HPMA is particularly useful as a hydrophobic hydroxy monomer in the manufacture of sealants for vacuum impregnation of cast aluminum components. HPMA is also widely used in the production of flexible UV-curable photopolymer printing plates.

General Description

White liquid with a light unpleasant odor. May float or sink in water.

Reactivity Profile

2-Hydroxypropyl methacrylate polymerization: May polymerize when hot or when exposed to ultraviolet light and free-radical catalysts [USCG, 1999].

Health Hazard

Inhalation causes coughing and irritation of nose and throat; lung injury may occur. Ingestion causes irritation and burning of mouth and stomach. Contact of vapor with eyes causes irritation. Liquid may cause severe eye burns and irritation of skin.

Fire Hazard

Behavior in Fire: Compound may polymerize when hot and burst container.

Safety

2-Hydroxypropyl Methacrylate (2-HPMA) is a combustible substance. With intense healing, it forms explosive vapors with air. Vapors are heavier than air and may spread along with floors. In the case of fire, the formation of harmful gaseous products is possible. Contact with skin may cause an allergic reaction. When working with 2-Hydroxypropyl Methacrylate (2-HPMA), sanitary rules for organizing technological processes and hygienic requirements for production equipment must be strictly observed.

2-Hydroxypropyl methacrylate Preparation Products And Raw materials

Raw materials

Methacrylic acid Propylene oxide

Preparation Products

CC-2SH adhesive composite used in anterior teeth
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2-Hydroxypropyl methacrylate Suppliers

Americas 1 Belgium 1 Canada 1 China 341 Europe 1 France 1 Germany 8 India 14 Italy 1 Japan 6 Spain 1 Switzerland 1 The Netherlands 2 United Kingdom 5 United States 43 Global 427
Esstech Inc.
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+1 (610) 521-3800
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Alfa Chemistry
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KOWA American Corporation (part of Kowa Group)
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Scientific Polymer Products Inc
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Maroon Group (formerly D.B. Becker Co., Inc.)
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THE DOW CHEMICAL COMPANY
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MD Chemicals
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Charkit Chemical Corporation
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Alfa Aesar
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View Lastest Price from 2-Hydroxypropyl methacrylate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
2-Hydroxypropyl methacrylate 27813-02-1
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000
Release date
2024-05-11
WUHAN FORTUNA CHEMICAL CO., LTD
Product
2-Hydroxypropyl methacrylate 27813-02-1
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-13
Yancheng Green Chemicals Co.,Ltd
Product
2-Hydroxypropyl methacrylate；HPMA 27813-02-1
Price
US $0.00/Kg/Drum
Min. Order
200ASSAYS
Purity
98
Supply Ability
1mt
Release date
2020-12-28

27813-02-1, 2-Hydroxypropyl methacrylate Related Search:

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