ChemicalBook > CAS DataBase List > Ethyl benzoate

Ethyl benzoate

Product Name
Ethyl benzoate
CAS No.
93-89-0
Chemical Name
Ethyl benzoate
Synonyms
BENZOIC ACID ETHYL ESTER;Manufacture;Ethylbenzoat;Nat.Ethyl benzoate;BENZOIC ETHER;Benzoic acid ethyl;Benxoicacidethylester;ETHYL BENZOATE FOR SYNTHESIS 1 L;FEMA 2422;Large Stock
CBNumber
CB9318180
Molecular Formula
C9H10O2
Formula Weight
150.17
MOL File
93-89-0.mol
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Ethyl benzoate Property

Melting point:
-34 °C
Boiling point:
212 °C(lit.)
Density 
1.045 g/mL at 25 °C(lit.)
vapor density 
5.17 (vs air)
vapor pressure 
1 mm Hg ( 44 °C)
refractive index 
n20/D 1.504(lit.)
FEMA 
2422 | ETHYL BENZOATE
Flash point:
184 °F
storage temp. 
Store below +30°C.
solubility 
0.5g/l
form 
Liquid
color 
Clear colorless to pale yellow
Odor
at 100.00 %. fruity dry musty sweet wintergreen
Relative polarity
0.228
Odor Type
minty
explosive limit
1%(V)
Water Solubility 
INSOLUBLE
Merck 
14,3766
JECFA Number
852
BRN 
1908172
Dielectric constant
6.0（20℃）
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
LogP
2.59 at 23℃
CAS DataBase Reference
93-89-0(CAS DataBase Reference)
NIST Chemistry Reference
Benzoic acid, ethyl ester(93-89-0)
EPA Substance Registry System
Benzoic acid, ethyl ester (93-89-0)
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Safety

Hazard Codes 
N
Risk Statements 
51/53
Safety Statements 
24/25-61
RIDADR 
UN 3082 9 / PGIII
WGK Germany 
1
RTECS 
DH0200000
Autoignition Temperature
914 °F
TSCA 
Yes
HS Code 
29163100
Toxicity
LD50 orally in rats: 6.48 g/kg, Smyth et al., Arch. Ind. Hyg. Occup. Med. 10, 61 (1954)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W242217
Product name
Ethyl benzoate
Purity
natural, ≥99%, FCC, FG
Packaging
100g
Price
$79.9
Updated
2024/03/01
Sigma-Aldrich
Product number
W242217
Product name
Ethyl benzoate
Purity
natural, ≥99%, FCC, FG
Packaging
1kg
Price
$1040
Updated
2024/03/01
Sigma-Aldrich
Product number
W242209
Product name
Ethyl benzoate
Purity
≥99%, FCC, FG
Packaging
1kg
Price
$76.5
Updated
2024/03/01
Sigma-Aldrich
Product number
W242209
Product name
Ethyl benzoate
Purity
≥99%, FCC, FG
Packaging
25kg
Price
$562
Updated
2024/03/01
Sigma-Aldrich
Product number
E12907
Product name
Ethyl benzoate
Purity
≥99%
Packaging
5g
Price
$29.1
Updated
2024/03/01
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Ethyl benzoate Chemical Properties,Usage,Production

Description

Ethyl benzoate, C9H10O2, is the ester formed by the condensation of benzoic acid and ethanol. It is a colorless liquid that is almost insoluble in water, but miscible with most organic solvents.
As with many volatile esters, ethyl benzoate has a pleasant odor which could be described similar to wintergreen mint. It is a component of some artificial fruit flavors.

Chemical Properties

Ethyl benzoate is a colourless liquid that has a somewhat fruity odor similar to ylang-ylang, but milder than methyl benzoate. Soluble in ethanol, ethyl ether, petroleum ether, propylene glycol, mineral oil and most non-volatile oils, insoluble in water and glycerin.

Occurrence

Reported found in volatiles from hard, mature peaches, pineapple and currant. Also reported found in apple juice, banana, guava, cranberry, raspberry, sweet cherry, Parmesan cheese, butter, milk, white wine, red wine, cider, whiskies, cocoa, black tea, fresh plum, apple brandy, cherry brandy, Bourbon vanilla, naranjilla fruit, ceriman or pinanona, pimento berry, olive and passion fruit.

Uses

Ethyl Benzoate acts as an aroma and flavour compound due to the volatile ester group in its structure. In perfumery under the name Essence de Niobe; in manufacture of Peau d'Espagne; artificial fruit essence.

Uses

Ethyl benzoate is used as a perfume scent. It acts as a food flavoring agent. It is an active component of artificial fruit flavors. Further, it is used in cosmetics and personal care products as fragrance ingredients and preservatives.

Preparation

By esterification of ethyl alcohol and benzoic acid in the presence of anhydrous aluminum sulfate and a trace of sulfuric acid; by transesterification of methyl benzoate with ethanol in the presence of potassium ethylate

Definition

ChEBI: Ethyl benzoate is a benzoate ester obtained by condensation of benzoic acid and ethanol. It is a volatile oil component found in ripe kiwifruit, cranberry juice, and palm kernel oil. It has a role as a flavouring agent, a fragrance and a volatile oil component. It is a benzoate ester and an ethyl ester.

Aroma threshold values

Detection: 100 ppb; recognition: 150 ppb

Taste threshold values

Taste characteristics at 30 ppm: sweet, medicinal, green, minty, fruity, birch beer and wintergreen-like.

Synthesis Reference(s)

The Journal of Organic Chemistry, 25, p. 1703, 1960 DOI: 10.1021/jo01080a004
Synthetic Communications, 20, p. 2267, 1990 DOI: 10.1080/00397919008053167
Tetrahedron Letters, 22, p. 1509, 1981 DOI: 10.1016/S0040-4039(01)90363-6

General Description

Natural occurrence: Feijoa, guava, plum, raspberry, rum, strawberry, Virginia tobacco.

Flammability and Explosibility

Not classified

Biochem/physiol Actions

Taste at 10 ppm

Safety Profile

Moderately toxic by ingestion. Mildly toxic by skin contact. A skin and eye irritant. Combustible liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS

Ethyl benzoate Preparation Products And Raw materials

Raw materials

Trap Aluminum sulfate

Preparation Products

Alibendol 2-PHENYL-2-PROPANOL Benoxinate Hydrochloride Ethyl benzoylacetate Benzohydroxamic acid Benzoylacetonitrile Benzyl benzoate
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Ethyl benzoate Suppliers

Americas 1 Australia 2 Belgium 2 Brazil 1 Canada 4 China 387 Czech Republic 1 Europe 5 France 3 Germany 12 India 53 Italy 2 Japan 7 Mexico 1 Russia 1 Singapore 2 Slovakia 1 Spain 2 Switzerland 2 United Kingdom 13 United States 85 Global 587
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View Lastest Price from Ethyl benzoate manufacturers

Jinan Finer Chemical Co., Ltd
Product
Ethyl benzoate 93-89-0
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
99%
Supply Ability
500mt/year
Release date
2021-07-08
Dorne Chemical Technology co. LTD
Product
Ethyl benzoate 93-89-0
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
1000kg
Release date
2024-03-26
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Ethyl benzoate 93-89-0
Price
US $30.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000kg/Month
Release date
2024-04-29

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